Carbonylchlorohydrotris(triphenylphosphine)ruthenium
Reaction- Product Name
- Carbonylchlorohydrotris(triphenylphosphine)ruthenium
- CAS No.
- 16971-33-8
- Chemical Name
- Carbonylchlorohydrotris(triphenylphosphine)ruthenium
- Synonyms
- RuHCl(CO)(PPh3)3;Carbonylchlorohydridotris(triphenylphosphine)ruthenium;Ru(CO)ClH(PPh3)3;mer-RuH(PPh3)3(CO)Cl;Carbonylchlorohydridotris;carbonylchlorohydridotris(triphenyl-phosphine)rut;Carbonylchlorohydrido tris (triphenylphosphine) ru;carbonylchlorohydrotris(triphenylphosphine)ruthenium;Carbonylchlorohydrotris(triphen-ylphosphineruthenium(Ⅱ);Hydridochlorocarbonyltris-(triphenylphosphino)-ruthenium
- CBNumber
- CB8487823
- Molecular Formula
- C55H45ClOP3Ru
- Formula Weight
- 951.39
- MOL File
- 16971-33-8.mol
Carbonylchlorohydrotris(triphenylphosphine)ruthenium Property
- Melting point:
- 204-206 °C (dec.)(lit.)
- Boiling point:
- approximate 360℃
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- form
- Powder
- color
- Cream to tan
- Water Solubility
- insoluble
- Sensitive
- Air stable, light sensitive
Safety
- Hazard Codes
- Xn,T
- Risk Statements
- 20/21/22-36/37/38
- Safety Statements
- 26-37/39-36/37/39-22
- WGK Germany
- 3
- HS Code
- 29310099
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 334995
- Product name
- Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II)
- Packaging
- 1g
- Price
- $133
- Updated
- 2024/03/01
- Product number
- 334995
- Product name
- Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II)
- Packaging
- 5g
- Price
- $383
- Updated
- 2024/03/01
- Product number
- 044955
- Product name
- Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II)
- Packaging
- 1g
- Price
- $93.65
- Updated
- 2024/03/01
- Product number
- 044955
- Product name
- Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II)
- Packaging
- 5g
- Price
- $417
- Updated
- 2024/03/01
- Product number
- 44-0085
- Product name
- Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II), 99%
- Packaging
- 1g
- Price
- $82
- Updated
- 2024/03/01
Carbonylchlorohydrotris(triphenylphosphine)ruthenium Chemical Properties,Usage,Production
Reaction
- Catalyst for alcohol α-allylation with dienes or allenes under transfer hydrogenation conditions.
- Catalyst for tandem isomerization (to imine), followed by Friedel Crafts alkylation.
- Catalyst for amination of alcohols with ammonia.
Chemical Properties
pale yellow crystals
Uses
Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II) is used as a raw material to synthesize other ru-hydride catalysts. It is involved in the hydrogenation of ring-opening metathesis polymers such as norbornene and other cyclic olefin ROMP polymers used as plastics, resins and optical materials. It can act as an alternative catalyst to rhodium hydrogenation catalyst. It also serves as a catalyst in the hydrogenation of conjugated diene copolymers like acrylonitrile-butadiene rubber (NBR).
Carbonylchlorohydrotris(triphenylphosphine)ruthenium Preparation Products And Raw materials
Raw materials
Preparation Products
Carbonylchlorohydrotris(triphenylphosphine)ruthenium Suppliers
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View Lastest Price from Carbonylchlorohydrotris(triphenylphosphine)ruthenium manufacturers
- Product
- Carbonylchlorohydrotris(triphenylphosphine)ruthenium 16971-33-8
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 200kg
- Release date
- 2019-07-03