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Carbonylchlorohydrotris(triphenylphosphine)ruthenium

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Product Name
Carbonylchlorohydrotris(triphenylphosphine)ruthenium
CAS No.
16971-33-8
Chemical Name
Carbonylchlorohydrotris(triphenylphosphine)ruthenium
Synonyms
RuHCl(CO)(PPh3)3;Carbonylchlorohydridotris(triphenylphosphine)ruthenium;Ru(CO)ClH(PPh3)3;mer-RuH(PPh3)3(CO)Cl;Carbonylchlorohydridotris;carbonylchlorohydridotris(triphenyl-phosphine)rut;Carbonylchlorohydrido tris (triphenylphosphine) ru;carbonylchlorohydrotris(triphenylphosphine)ruthenium;Carbonylchlorohydrotris(triphen-ylphosphineruthenium(Ⅱ);Hydridochlorocarbonyltris-(triphenylphosphino)-ruthenium
CBNumber
CB8487823
Molecular Formula
C55H45ClOP3Ru
Formula Weight
951.39
MOL File
16971-33-8.mol
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Carbonylchlorohydrotris(triphenylphosphine)ruthenium Property

Melting point:
204-206 °C (dec.)(lit.)
Boiling point:
approximate 360℃
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
form 
Powder
color 
Cream to tan
Water Solubility 
insoluble
Sensitive 
Air stable, light sensitive
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Safety

Hazard Codes 
Xn,T
Risk Statements 
20/21/22-36/37/38
Safety Statements 
26-37/39-36/37/39-22
WGK Germany 
3
HS Code 
29310099
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
334995
Product name
Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II)
Packaging
1g
Price
$133
Updated
2024/03/01
Sigma-Aldrich
Product number
334995
Product name
Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II)
Packaging
5g
Price
$383
Updated
2024/03/01
Alfa Aesar
Product number
044955
Product name
Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II)
Packaging
1g
Price
$93.65
Updated
2024/03/01
Alfa Aesar
Product number
044955
Product name
Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II)
Packaging
5g
Price
$417
Updated
2024/03/01
Strem Chemicals
Product number
44-0085
Product name
Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II), 99%
Packaging
1g
Price
$82
Updated
2024/03/01
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Carbonylchlorohydrotris(triphenylphosphine)ruthenium Chemical Properties,Usage,Production

Reaction

  1. Catalyst for alcohol α-allylation with dienes or allenes under transfer hydrogenation conditions.
  2. Catalyst for tandem isomerization (to imine), followed by Friedel Crafts alkylation.
  3. Catalyst for amination of alcohols with ammonia.

Chemical Properties

pale yellow crystals

Uses

Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II) is used as a raw material to synthesize other ru-hydride catalysts. It is involved in the hydrogenation of ring-opening metathesis polymers such as norbornene and other cyclic olefin ROMP polymers used as plastics, resins and optical materials. It can act as an alternative catalyst to rhodium hydrogenation catalyst. It also serves as a catalyst in the hydrogenation of conjugated diene copolymers like acrylonitrile-butadiene rubber (NBR).

Carbonylchlorohydrotris(triphenylphosphine)ruthenium Preparation Products And Raw materials

Raw materials

Preparation Products

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Carbonylchlorohydrotris(triphenylphosphine)ruthenium Suppliers

Shanghai Incat Chemtech Co.,Ltd.
Tel
021-57603038 13601791340
Fax
021-57603057
Email
307593986@qq.com
Country
China
ProdList
475
Advantage
58
Shaanxi Rock New Materials Co., Ltd.
Tel
917-917-8888777 18691746767
Email
zhaoting@bjrock.com
Country
China
ProdList
302
Advantage
62
Beijing Guofang Dingsheng Technology Co., Ltd.
Tel
18610472091 18610472091
Fax
010-59092859
Email
gfdskj@163.com
Country
China
ProdList
494
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40241
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30132
Advantage
84
Ark Pharm, Inc.
Tel
847-367-3680
Fax
847-367-3681
Email
sales@arkpharminc.com
Country
United States
ProdList
1670
Advantage
56
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44751
Advantage
61
JinYan Chemicals(ShangHai) Co.,Ltd.
Tel
13817811078
Fax
86-021-50426522,50426273
Email
sales@jingyan-chemical.com
Country
China
ProdList
9984
Advantage
60
Jia Xing Isenchem Co.,Ltd
Tel
0573-85285100 18627885956
Fax
0573-85285100
Email
isenchem@163.com
Country
China
ProdList
9551
Advantage
66
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View Lastest Price from Carbonylchlorohydrotris(triphenylphosphine)ruthenium manufacturers

Career Henan Chemical Co
Product
Carbonylchlorohydrotris(triphenylphosphine)ruthenium 16971-33-8
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
200kg
Release date
2019-07-03

16971-33-8, Carbonylchlorohydrotris(triphenylphosphine)rutheniumRelated Search:


  • CARBONYLCHLOROHYDRIDOTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II)
  • carbonylchlorohydridotris(triphenyl-phosphine)rut
  • carbonylchlorohydrotris(triphenylphosphine)ruthenium
  • Hydridochlorocarbonyltris-(triphenylphosphino)-ruthenium
  • Carbonylchlorohydridotris(triphenylphosphine)ruthenium
  • Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II),99%
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  • Carbonylchlorohydridotris(triphenylphosphine)rutheniuM(II),98% (PPh3)3(CO)HRuCl
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  • Carbonylchlorohydrotris(triphenylphosphine)ruthenium(II)
  • Carbonylchlorohydrotris(triphenylphosphine)ruthenium ISO 9001:2015 REACH
  • 16971-33-8 Carbonylchlorohydrotris(triphenylphosphine)ruthenium
  • Carbonylchlorohydridotris(triphenylphosphine)ruthenium(Il)
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  • Catalysis and Inorganic Chemistry