Uses
ChemicalBook > CAS DataBase List > [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)

Uses
Product Name
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
CAS No.
72287-26-4
Chemical Name
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
Synonyms
PDCL2(DPPF);(dppf)2PdCl2;dichloropalladiuM;1,1-BIS(DIPHENYLPHOSPHINO)FERROCENEDICHLOROPALLADIUM(II);Palladium(II) chloride-1,1’-bis(diphenylphosphino)ferrocene,complex with CH2Cl2;CX93;oropaL;Pd（dppf）;pddppfcl2;[1,1&prime
CBNumber
CB3276259
Molecular Formula
C34H28Cl2FeP2Pd
Formula Weight
731.7
MOL File
72287-26-4.mol
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[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Property

Melting point:
275-280 °C(lit.)
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
solubility 
Soluble in dichloromethane.
form 
powder
color 
red to very dark red
Stability:
Hygroscopic
InChI
InChI=1S/2C17H11P.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*1-6,9-12,18H;2*1H;;/q;;;;+2;/p-2
InChIKey
LMSWLYFMTLONFK-UHFFFAOYSA-L
SMILES
[Cl-][Pd+2]1(P(C2C=CC=CC=2)(C2C=CC=CC=2)[C-]23C4=C5C6=C2[Fe+2]27893456C3C2=C7[C-]8(C9=3)P1(C1C=CC=CC=1)C1C=CC=CC=1)[Cl-]
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Safety

Hazard Codes 
Xn,Xi
Risk Statements 
20/21/22-36/37/38-40
Safety Statements 
23-24/25-26-36/37
WGK Germany 
3
TSCA 
No
HazardClass 
IRRITANT
HS Code 
28439000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
697230
Product name
[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
Packaging
1g
Price
$76.6
Updated
2025/07/31
Sigma-Aldrich
Product number
697230
Product name
[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
Packaging
5g
Price
$234
Updated
2025/07/31
Sigma-Aldrich
Product number
697230
Product name
[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
Packaging
1 unit
Price
$981
Updated
2025/07/31
Sigma-Aldrich
Product number
697230
Product name
[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
Packaging
1 unit
Price
$981
Updated
2025/07/31
Sigma-Aldrich
Product number
697230
Product name
[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
Packaging
250g
Price
$9880
Updated
2025/07/31
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[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Chemical Properties,Usage,Production

Uses

[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), is a palladium catalyst used in chemical synthesis of various compounds. Is used in preparation of Nucleosides as Ectonucleotidase inhibitors.

Chemical Properties

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) is Red solid

Uses

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) is used as a catalyst for Suzuki and Stile couplings.

Uses

suzuki reaction

Uses

Catalyst for C-C and C-N coupling reaction.

Application

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) may be used as an effective palladium catalyst in the following reactions:
Cross-coupling of sec-alkyl and n-alkyl Grignard reagents with high yield and selectivity.
Suzuki coupling of aryl boronic esters with [11C]methyl iodide to form functionalized [11C]toluene derivatives.
Kumada cross-coupling of 1,3,5-tribromobenzene with Grignard reagents to form star-shaped oligothiophenes.

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

Mechanism of action

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) (pd(dppf)cl2) catalysis has gained widespread use in industrial and academic synthetic chemistry laboratories as a powerful methodology for the formation of C-C and C-Heteroatom bonds.

R = usually sp2 hybridised carbon
X = usually I, Br, Cl or OTf
The nature of R' and M are dependant upon
the specic coupling being performed

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Preparation Products And Raw materials

Raw materials

Acetonitrile Ethanol 1,1'-Bis(diphenylphosphino)ferrocene Toluene Palladium chloride Dichloromethane Methanol Lithium chloride

Preparation Products

Vanadyl acetylacetonate 4-AMINO-3-METHOXYPHENYLBORONIC ACID, PINACOL ESTER 4-Nitrophenylboronic acid 3-MORPHOLINOPHENYLBORONIC ACID PINACOL ESTER 2-Ethoxycarbonylphenylboronic acid pinacol ester
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[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Suppliers

Australia 1 Belgium 1 Canada 1 China 471 Europe 4 Germany 7 India 13 Japan 1 Russia 1 South Korea 1 Switzerland 2 United Kingdom 8 United States 28 Global 539
Wuhan Taiyu New Materials Co., Ltd.
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18627786697
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tyxcchem@163.com
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China
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Wuhan Tuochuangda Technology Co., LTD
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18627850571
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tuochuangda@163.com
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China
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Shaanxi Rock New Materials Co., Ltd.
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0917-8888777, 3380777,18691786767; 15619786767
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xuya@bjrock.com
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China
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WuHan Taiyukaishang Chemical Co., Ltd.
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027-027-87680032 18963957250
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Beijing Guofang Dingsheng Technology Co., Ltd.
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18610472091
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010-59092859
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Wuhan Huahan Dingcheng New Material Technology Co., Ltd
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027-81388558 18963961905
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Tianjin heowns Biochemical Technology Co., Ltd.
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400-6387771-6039 18920764717
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sales@heowns.com
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China
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Wuhan Jiade Ruifeng New Materials Co., Ltd
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18271874579 / 18971104330 18971104330
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Xiaowei@JDchem.com.cn
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China
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Wuhan Houshuang Technology Co., Ltd
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13080686708; 13080686708
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houshuangchem@163.com
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China
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Luoyang Heyi New Materials Co., Ltd
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13674998441 18203623319
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12409005@qq.com
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China
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View Lastest Price from [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) manufacturers

Shaanxi Dideu New Materials Co. Ltd
Product
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) 72287-26-4
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98
Supply Ability
10000KGS
Release date
2025-11-20
Hebei Chuanghai Biotechnology Co., Ltd
Product
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) 72287-26-4
Price
US $10.00/KG
Min. Order
100KG
Purity
99%
Supply Ability
100 mt
Release date
2024-11-29
Hebei Chuanghai Biotechnology Co., Ltd
Product
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) 72287-26-4
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2023-02-09

72287-26-4, [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)Related Search:

Diphenylphosphine oxide Dicyclohexylchlorophosphine Chlorodiphenylphosphine ETHYNYLFERROCENE Tricyclohexyl phosphine Acetylferrocene Ferrocene Palladium chloride Tetrakis(triphenylphosphine)platinum [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) Dichloro(1,5-cyclooctadien)ruthenium(II) polymer 1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride, DICHLORO[1,3-BIS(DIPHENYLPHOSPHINO)PROPANE]PALLADIUM(II) ISOPROPYLDIPHENYLPHOSPHINE 1,1'-Bis(diphenylphosphino)ferrocene Dichloro(1,1-bis(diphenylphosphino)ferrocene)palladium(II) acetone adduct Palladium 1,3-Cyclopentadiene

  • 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENEDICHLOROPALLADIUM(II)
  • 1,1-BIS(DIPHENYLPHOSPHINO)FERROCENEDICHLOROPALLADIUM(II)
  • 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE PALLADIUM DICHLORIDE
  • 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENEPALLADIUM(II) DICHLORIDE
  • PDCL2(DPPF)
  • Dichloro(1,1'-bis(diphenylphosphino)ferrocene)palladium (II) dichloromethane add
  • 1,1'-Bis(diphenylphosphino)ferroceneüpalladium(II) chloride, 1:1 complex with dichloromethane
  • [bis(diphenylphosphino)ferrocene]PdCl2/ dichloromethane
  • 1,1'-Bis(diphenylphosphino)ferrocene palladium dichloride ,99%
  • [1,1'-Bis(diphenylphosphino)ferrocene]dichloropall
  • 1,1'-Bis(diphenylphosphino)ferrocene-palladium dichloride,98%
  • 1,1'-Bis(diphenylphosphino)ferrocene palladium(II)dichloride [Pd(dppf)Cl2]
  • Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II)
  • (dppf)2PdCl2
  • 1'-Bis(diphenylphosphino)ferrocene-palladiuM(II) dichloride
  • 1,1'-Bis(diphenylphosphino)ferrocene palladium dichloride ,99.9%
  • [1,1′-Bis(diphenylph
  • JACS-72287-26-4
  • [1,1'-Bis(Diphenylphosphino)Ferrocene]Dichloropalladium
  • dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(ii) dichloromethane complex (1:1)
  • -Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
  • 1,1-BIS(DIPHENYLPHOSPHINO)FERROCENEDICHLOROPALLADIUM(II): 99.9%
  • (II)dichloromethane adduct
  • 1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) complex with dichloromethane
  • Palladium, 1,1-bis(diphenylphosphino-.kappa.P)ferrocenedichloro-, (SP-4-2)-
  • [1,1'-bis(diphenylphosphino)ferrocene]dichloropalladium(ii) dichloromethane complex (1:1)
  • [1,1'-bis(diphenylphosphino)ferrocene]palladium(ii) dichloride dichloromethane complex (1:1)
  • (1,1'-Bis(diphenylphosphimoferrocene)dichloropalladium (II)-CH2CL2
  • [1,1-BIS(DIPHENYLPHOSPHINO)FERROCENE]DICHLOROPALLADI
  • Palladium(II) chloride-1,1’-bis(diphenylphosphino)ferrocene,complex with CH2Cl2
  • [1,1''-Bis-(diphenylphosphino)-ferrocene]-palladous dichloride
  • [1,1''-Bis(diphenyphosphino)ferrocene]dichloropalladium(II)
  • [1,1’-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) PdCl2(dppf)
  • 1,1''-BIS(DIPHENYLPHOSPHINO)FERROCENE]DICHLOROPALLADIUM() COMPLEX WITH DICHLOROMETHANE
  • (1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE)-P ALLADIUM(II) CHLORIDE CH2CL2 COMPL
  • DICHLORO-((BIS-DIPHENYLPHOSPHINO)FERROCENYL)-PALLADIUM(II)
  • 1,1'-Bis(diphenylphosphino)ferrocenepalladiuM( II) dichloride Pd
  • DICHLORO-((BIS-DIPHENYLPHOSPHINO)FERROCENYL)-PALLADIUM(II) DICHLOROMETHANE ADDUCT
  • [1,1'-Bis(diphenylphosphino)ferrocen]dichloropalladiuM(II), coMplex with dichloroMethane
  • -Bis(diphenylphosphino)ferrocene-palladiuM(II)dichloride dichloroMethane coMplex
  • dichloropalladiuM
  • 1,1'-Bis(diphenylphosphiNA)ferrocene palladiuM(II)dichloride
  • Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladiuM(II), (DPPF)PdCl2
  • [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(Ⅱ)
  • [1,1'-Bis(diphenylphosphino)ferrocene]Pd(II)Cl2
  • CHEMWISH IC30255
  • 1,1'-Bis(diphenylphosphino)ferrocene palladiuM(II)dichlorid
  • (Diphenylphosphino)Ferrocene PalladiuM Dichlorid
  • 1,1'-BIS(DIPHENYLPHOSPHINO)
  • 1,1'-BIS(DIPHENYLPHOSP
  • [1,1&prime
  • 1'1-Bis(diphenylphosphino)fewocene palladium(Ⅱ)chloride
  • [1,1’-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) (Pd(dppf)Cl2)
  • [1,1'-Bis(diphenyL
  • oropaL
  • phosphino)ferrocene]dichL
  • 1,1 '- bis (diphenylphosphino) ferrocene palladium dichloride (II)
  • 1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)，Pd 14.5%