[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)
- Product Name
- [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)
- CAS No.
- 19978-61-1
- Chemical Name
- [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)
- Synonyms
- 1,2-Bis;Dichloro(1;PdCl2(dppe);1,2-[BIS(DIPHENYLPHOSPHINO)ETHAN;2-bis(diphenylphosphino)ethane)palladium(II);Bis(diphenylphosphino)ethane]dichloropalladium;TIANFU-CHEM Bis(benzonitrile)palladium chloride-;Dichloro[1,2-bis(diphenylphosphino)ethanepalladiu;[1,2-Bis(diphenylphosphino)ethane]dichloropalladiu;1,2-bis(diphenylphosphino)ethane palladium dichloride
- CBNumber
- CB5309560
- Molecular Formula
- C26H24Cl2P2Pd
- Formula Weight
- 575.74
- MOL File
- 19978-61-1.mol
[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) Property
- Melting point:
- 360 °C
- storage temp.
- Inert atmosphere,Room Temperature
- form
- Powder
- color
- off-white
- Water Solubility
- insoluble
- Sensitive
- Moisture sensitive
- InChI
- InChI=1S/C26H24P2.2ClH.Pd/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;2*1H;/q;;;+2/p-2
- InChIKey
- LDJXFZUGZASGIW-UHFFFAOYSA-L
- SMILES
- C(P(C1=CC=CC=C1)C1=CC=CC=C1)CP(C1=CC=CC=C1)C1=CC=CC=C1.[Pd](Cl)Cl
- CAS DataBase Reference
- 19978-61-1(CAS DataBase Reference)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 345237
- Product name
- [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)
- Purity
- 98%
- Packaging
- 1g
- Price
- $146
- Updated
- 2026/03/19
- Product number
- B2016
- Product name
- [1,2-Bis(diphenylphosphino)ethane]palladium(II) Dichloride
- Purity
- >98.0%(T)
- Packaging
- 1g
- Price
- $57
- Updated
- 2026/03/19
- Product number
- B2016
- Product name
- [1,2-Bis(diphenylphosphino)ethane]palladium(II) Dichloride
- Purity
- >98.0%(T)
- Packaging
- 5g
- Price
- $169
- Updated
- 2026/03/19
- Product number
- 46-0800
- Product name
- Dichloro(1,2-bis(diphenylphosphino)ethane)palladium(II), 98%
- Packaging
- 1g
- Price
- $98
- Updated
- 2024/03/01
- Product number
- 46-0800
- Product name
- Dichloro(1,2-bis(diphenylphosphino)ethane)palladium(II), 98%
- Packaging
- 5g
- Price
- $337
- Updated
- 2024/03/01
[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) Chemical Properties,Usage,Production
Chemical Properties
orange powder
Uses
[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) is a precatalyst used in the production of acrylic acid sodium salt via coupling of CO2 with ethene.
suzuki reaction.
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
core: palladium
Synthesis
Add acetonitrile 3L in the reaction kettle, heat, add palladium chloride 177g (1.0mol) in 3 batches, add acetonitrile 2L, reflux reaction for 2~3h. When the reaction solution becomes brown-red clarified liquid, filter it while it is still hot, filter out a small amount of insoluble matter, add dppe 398g (1.0mol) in the filtrate, stir the reaction for 0.5h. Cool down to room temperature, filtrate, and wash the cake with cold tetrahydrofuran and water for 3~4 times in turn, vacuum drying for 7h to obtain 1,2-bis(diphenylphosphino)ethane palladium(II) 552g. The filter cake was washed with cold tetrahydrofuran and water for 3~4 times, and then dried under vacuum for 7h to obtain 1,2-bis(diphenylphosphino)ethane palladium(II) dichloride 552g, with 96% yield. The solvent slow evaporation method was used to cultivate single crystal, appropriate amount of solid product was dissolved in CHCl3, sealed with plastic wrap, left to stand, and naturally evaporated for 30d to obtain white flaky crystals.
Precautions
This palladium catalyst, also known as [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II), presents as a very pale yellow to yellow crystalline powder. Store under inert gas, at ambient temperatures and protected from moisture. This substance is moisture sensitive. [1,2-Bis(diphenylphosphino)ethane]palladium(II) Dichloride is incompatible with oxidizing agents. This chemical is harmful if swallowed, in contact with skin or if inhaled. It causes skin irritation as well as serious eye irritation.
[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) manufacturers
- Product
- [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) 19978-61-1
- Price
- US $2.00-5.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 100kg
- Release date
- 2025-06-23
- Product
- [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) 19978-61-1
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-07-11
- Product
- [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) 19978-61-1
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-07-09