1,1μ-Bis(di-cyclohexylphosphino)ferrocene palladium dichloride
Uses- Product Name
- 1,1μ-Bis(di-cyclohexylphosphino)ferrocene palladium dichloride
- CAS No.
- 917511-90-1
- Chemical Name
- 1,1μ-Bis(di-cyclohexylphosphino)ferrocene palladium dichloride
- Synonyms
- PdCl2(dcypf);Nickel(II)broMide,diMethoxyethaneadduct;1,1''-Bis(di;Dichloro [1,1'-bis(dicyclohexy;Dichloro [1,1'-bis(dicyclohexylphosphino)ferrocene]palladium;Dichloro[1,1'-bis(dicyclohexylphosphino)ferrocene]palladium(II);1,1'-Bis(di-cyclohexylphosphino)ferrocene]dichloropalladium(II);Dichloro[1,1'-bis(dicyclohexylphosphino)ferrocene]palladium (II);[1,1′-Bis(di-cyclohexylphosphino)ferrocene]dichloropalladiuM(II);Dichloro[1,1'-bis(dicyclohexylphosphiNA)ferrocene]palladiuM (II)
- CBNumber
- CB02101420
- Molecular Formula
- 2C17H26P.Cl2Pd.Fe
- Formula Weight
- 755.904
- MOL File
- 917511-90-1.mol
1,1μ-Bis(di-cyclohexylphosphino)ferrocene palladium dichloride Property
- Melting point:
- 294-300 °C
- storage temp.
- -20°C
- form
- Crystalline solid
- color
- red-orange microcrystal
- InChI
- InChI=1S/2C17H26P.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*7-8,13-16H,1-6,9-12H2;2*1H;;/q;;;;;+2/p-2
- InChIKey
- HRAMBTUEZQOQRK-UHFFFAOYSA-L
- SMILES
- [CH]1[CH][CH][CH][C]1P(C1CCCCC1)C1CCCCC1.[CH]1[CH][CH][CH][C]1P(C1CCCCC1)C1CCCCC1.[Pd](Cl)Cl.[Fe] |^1:0,1,2,3,4,18,19,20,21,22|
- CAS DataBase Reference
- 917511-90-1
Safety
- WGK Germany
- 3
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 701998
- Product name
- [1,1′-Bis(di-cyclohexylphosphino)ferrocene]dichloropalladium(II)
- Purity
- 98%
- Packaging
- 250mg
- Price
- $57.2
- Updated
- 2024/03/01
- Product number
- 701998
- Product name
- [1,1′-Bis(di-cyclohexylphosphino)ferrocene]dichloropalladium(II)
- Purity
- 98%
- Packaging
- 1g
- Price
- $217
- Updated
- 2024/03/01
- Product number
- 046383
- Product name
- Dichloro[1,1'-bis(dicyclohexylphosphino)ferrocene]palladium(II), Pd 14.1%
- Packaging
- 1g
- Price
- $324
- Updated
- 2023/06/20
- Product number
- 46-0455
- Product name
- Dichloro[1,1'-bis(dicyclohexylphosphino)ferrocene]palladium(II), dichloromethane adduct, 99%
- Packaging
- 250mg
- Price
- $109
- Updated
- 2024/03/01
- Product number
- 46-0455
- Product name
- Dichloro[1,1'-bis(dicyclohexylphosphino)ferrocene]palladium(II), dichloromethane adduct, 99%
- Packaging
- 1g
- Price
- $316
- Updated
- 2024/03/01
1,1μ-Bis(di-cyclohexylphosphino)ferrocene palladium dichloride Chemical Properties,Usage,Production
Uses
1,1'-Bis(di-cyclohexylphosphino)ferrocene palladium dichloride is an air-stable catalyst useful in the arylation of various ketones with aryl chlorides and aryl bromides.
Uses
1,1′-Bis(di-cyclohexylphosphino)ferrocene]dichloropalladium(II) or (Pd(dcpf)Cl2) can be used as a catalyst in the synthesis of:
- α, β-unsaturated amides by hydroaminocarbonylation of alkynes with tertiary amines.
- Quinazoline derivatives via Suzuki-Miyaura coupling reaction between of quinazolines containing unprotected NH2 group and arylboronic acids.
- α-aryl carbonyl compounds by α-arylation of ketones with aryl chlorides and aryl bromides.
reaction suitability
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
1,1μ-Bis(di-cyclohexylphosphino)ferrocene palladium dichloride Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 1,1μ-Bis(di-cyclohexylphosphino)ferrocene palladium dichloride manufacturers
- Product
- 1,1μ-Bis(di-cyclohexylphosphino)ferrocene palladium dichloride 917511-90-1
- Price
- US $20.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10000KG
- Release date
- 2020-11-11
- Product
- 1,1μ-Bis(di-cyclohexylphosphino)ferrocene palladium dichloride 917511-90-1
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100
- Release date
- 2019-06-28