1,1μ-Bis(di-cyclohexylphosphino)ferrocene palladium dichloride

Uses

Product Name: 1,1μ-Bis(di-cyclohexylphosphino)ferrocene palladium dichloride
CAS No.: 917511-90-1
Chemical Name: 1,1μ-Bis(di-cyclohexylphosphino)ferrocene palladium dichloride
Synonyms: PdCl2(dcypf);Nickel(II)broMide,diMethoxyethaneadduct;1,1''-Bis(di;1,1''-Bis(di;Dichloro [1,1'-bis(dicyclohexy;Dichloro [1,1'-bis(dicyclohexylphosphino)ferrocene]palladium;Dichloro[1,1'-bis(dicyclohexylphosphino)ferrocene]palladium(II);1,1'-Bis(di-cyclohexylphosphino)ferrocene]dichloropalladium(II);Dichloro[1,1'-bis(dicyclohexylphosphino)ferrocene]palladium (II);[1,1′-Bis(di-cyclohexylphosphino)ferrocene]dichloropalladiuM(II)
CBNumber: CB02101420
Molecular Formula: 2C17H26P.Cl2Pd.Fe
Formula Weight: 755.904
MOL File: 917511-90-1.mol

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1,1μ-Bis(di-cyclohexylphosphino)ferrocene palladium dichloride Property

Melting point:: 294-300 °C
storage temp.: -20°C
form: Crystalline solid
color: red-orange microcrystal
InChI: InChI=1S/2C17H26P.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*7-8,13-16H,1-6,9-12H2;2*1H;;/q;;;;;+2/p-2
InChIKey: HRAMBTUEZQOQRK-UHFFFAOYSA-L
SMILES: [CH]1[CH][CH][CH][C]1P(C1CCCCC1)C1CCCCC1.[CH]1[CH][CH][CH][C]1P(C1CCCCC1)C1CCCCC1.[Pd](Cl)Cl.[Fe] |^1:0,1,2,3,4,18,19,20,21,22|
CAS DataBase Reference: 917511-90-1

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Safety

WGK Germany: 3
Storage Class: 11 - Combustible Solids

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 701998
Product name: [1,1′-Bis(di-cyclohexylphosphino)ferrocene]dichloropalladium(II)
Purity: 98%
Packaging: 250mg
Price: $47.02
Updated: 2025/07/31

Sigma-Aldrich

Product number: 701998
Product name: [1,1′-Bis(di-cyclohexylphosphino)ferrocene]dichloropalladium(II)
Purity: 98%
Packaging: 1g
Price: $224
Updated: 2025/07/31

Strem Chemicals

Product number: 46-0455
Product name: Dichloro[1,1'-bis(dicyclohexylphosphino)ferrocene]palladium(II), dichloromethane adduct, 99%
Packaging: 250mg
Price: $109
Updated: 2024/03/01

Strem Chemicals

Product number: 46-0455
Product name: Dichloro[1,1'-bis(dicyclohexylphosphino)ferrocene]palladium(II), dichloromethane adduct, 99%
Packaging: 1g
Price: $316
Updated: 2024/03/01

ChemScene

Product number: CS-0031984
Product name: [1,1'-Bis(di-cyclohexylphosphino)ferrocene]dichloropalladium(II)
Purity: ≥98.0%
Packaging: 1g
Price: $140
Updated: 2021/12/16

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1,1μ-Bis(di-cyclohexylphosphino)ferrocene palladium dichloride Chemical Properties,Usage,Production

Uses

1,1'-Bis(di-cyclohexylphosphino)ferrocene palladium dichloride is an air-stable catalyst useful in the arylation of various ketones with aryl chlorides and aryl bromides.

Uses

1,1′-Bis(di-cyclohexylphosphino)ferrocene]dichloropalladium(II) or (Pd(dcpf)Cl₂) can be used as a catalyst in the synthesis of:

α, β-unsaturated amides by hydroaminocarbonylation of alkynes with tertiary amines.
Quinazoline derivatives via Suzuki-Miyaura coupling reaction between of quinazolines containing unprotected NH₂ group and arylboronic acids.
α-aryl carbonyl compounds by α-arylation of ketones with aryl chlorides and aryl bromides.

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

Synthesis

The thimble of a 250 mL Soxhlet apparatus was charged with 10 g of anhydrous NiBr2. The air in the apparatus was replaced with nitrogen, and 150 mL of ethylene glycol dimethyl ether was added to the flask with a condenser attached. The solid was heated to

1,1μ-Bis(di-cyclohexylphosphino)ferrocene palladium dichloride Preparation Products And Raw materials

Raw materials

Preparation Products

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1,1μ-Bis(di-cyclohexylphosphino)ferrocene palladium dichloride Suppliers

China 130 India 3 Switzerland 1 United States 5 Global 139

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View Lastest Price from 1,1μ-Bis(di-cyclohexylphosphino)ferrocene palladium dichloride manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

Product: 1,1'-bis-(di-Cyclohexylphosphino)ferrocene palladium dichloride 917511-90-1
Price: US $2.00-6.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 100kg
Release date: 2025-07-29

Longyan Tianhua Biological Technology Co., Ltd

Product: 1,1μ-Bis(di-cyclohexylphosphino)ferrocene palladium dichloride 917511-90-1
Price: US $20.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10000KG
Release date: 2020-11-11

Career Henan Chemical Co

Product: 1,1μ-Bis(di-cyclohexylphosphino)ferrocene palladium dichloride 917511-90-1
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100
Release date: 2019-06-28

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1,1′-Bis(di-cyclohexylphosphino)ferrocene palladium dichloride, CAS 917511-90-1

1,1''-Bis(di

917511-90-1

2C17H26PCl2PdFe

C34H52Cl2FeP2Pd

Pd