[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
Uses- Product Name
- [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
- CAS No.
- 72287-26-4
- Chemical Name
- [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
- Synonyms
- PDCL2(DPPF);(dppf)2PdCl2;dichloropalladiuM;1,1-BIS(DIPHENYLPHOSPHINO)FERROCENEDICHLOROPALLADIUM(II);Palladium(II) chloride-1,1’-bis(diphenylphosphino)ferrocene,complex with CH2Cl2;oropaL;[1,1′JACS-72287-26-4;CHEMWISH IC30255;[1,1'-Bis(diphenyL
- CBNumber
- CB3276259
- Molecular Formula
- C34H28Cl2FeP2Pd
- Formula Weight
- 731.7
- MOL File
- 72287-26-4.mol
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Property
- Melting point:
- 275-280 °C(lit.)
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- solubility
- Soluble in dichloromethane.
- form
- powder
- color
- red to very dark red
- Stability:
- Hygroscopic
Safety
- Hazard Codes
- Xn,Xi
- Risk Statements
- 20/21/22-36/37/38-40
- Safety Statements
- 23-24/25-26-36/37
- WGK Germany
- 3
- TSCA
- No
- HazardClass
- IRRITANT
- HS Code
- 28439000
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- 697230
- Product name
- [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
- Packaging
- 1g
- Price
- $74.3
- Updated
- 2024/03/01
- Product number
- 697230
- Product name
- [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
- Packaging
- 5g
- Price
- $227
- Updated
- 2024/03/01
- Product number
- 046503
- Product name
- Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II), Pd 13.5-15.5%
- Packaging
- 1g
- Price
- $72.5
- Updated
- 2023/06/20
- Product number
- 697230
- Product name
- [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
- Packaging
- 250g
- Price
- $9580
- Updated
- 2024/03/01
- Product number
- B430465
- Product name
- [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
- Packaging
- 1g
- Price
- $100
- Updated
- 2021/12/16
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Chemical Properties,Usage,Production
Uses
[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), is a palladium catalyst used in chemical synthesis of various compounds.Is used in preparation of Nucleosides as Ectonucleotidase inhibitors.
Chemical Properties
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) is Red solid
Uses
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) is used as a catalyst for Suzuki and Stile couplings.
Uses
suzuki reaction
Uses
Catalyst for C-C and C-N coupling reaction.
Application
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) may be used as an effective palladium catalyst in the following reactions:
Cross-coupling of sec-alkyl and n-alkyl Grignard reagents with high yield and selectivity.
Suzuki coupling of aryl boronic esters with [11C]methyl iodide to form functionalized [11C]toluene derivatives.
Kumada cross-coupling of 1,3,5-tribromobenzene with Grignard reagents to form star-shaped oligothiophenes.
Mechanism of action
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) (pd(dppf)cl2) catalysis has gained widespread use in industrial and academic synthetic chemistry laboratories as a powerful methodology for the formation of C-C and C-Heteroatom bonds.
R = usually sp2
hybridised carbon
X = usually I, Br, Cl or OTf
The nature of R' and M are dependant upon
the specic coupling being performed
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) manufacturers
- Product
- [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) 72287-26-4
- Price
- US $80.00/kilograms
- Min. Order
- 10kilograms
- Purity
- 99
- Supply Ability
- 10
- Release date
- 2023-03-01
- Product
- [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) 72287-26-4
- Price
- US $100.00-1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2023-12-25
- Product
- [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) 72287-26-4
- Price
- US $30.00-9.00/kg
- Min. Order
- 1kg
- Purity
- 0.99
- Supply Ability
- 15 tons
- Release date
- 2023-11-15