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Dicyclohexylchlorophosphine

Product Name
Dicyclohexylchlorophosphine
CAS No.
16523-54-9
Chemical Name
Dicyclohexylchlorophosphine
Synonyms
chlorodicyclohexylphosphane;CHLORODICYCLOHEXYLPHOSPHINE;Cy2PCl;orodicycL;98% (C6H11)2PCl;DICYCLOHEXYLCHLOROPHOSPHINE;Dicyclohexylphosphine chloride;Chlorodicyclohexylphosphine 97%;Chlorodicyclohexylphosphine,97%;Chlorodicyclohexylphosphine >
CBNumber
CB3345601
Molecular Formula
C12H22ClP
Formula Weight
232.73
MOL File
16523-54-9.mol
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Dicyclohexylchlorophosphine Property

Melting point:
126-128 °C
Boiling point:
165 °C/12 mmHg (lit.)
Density 
1.054 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.533(lit.)
Flash point:
>230 °F
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
Liquid
Specific Gravity
1.054
color 
Colorless to pale yellow
Water Solubility 
reacts violently
Sensitive 
Air & Moisture Sensitive
InChIKey
AKJFBIZAEPTXIL-UHFFFAOYSA-N
CAS DataBase Reference
16523-54-9(CAS DataBase Reference)
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Safety

Hazard Codes 
C
Risk Statements 
14-34
Safety Statements 
26-27-36/37/39-45-8
RIDADR 
UN 3265 8/PG 2
WGK Germany 
3
TSCA 
No
HazardClass 
8
PackingGroup 
II
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
481408
Product name
Chlorodicyclohexylphosphine
Purity
97%
Packaging
1g
Price
$83.5
Updated
2024/03/01
Sigma-Aldrich
Product number
481408
Product name
Chlorodicyclohexylphosphine
Purity
97%
Packaging
5g
Price
$283
Updated
2024/03/01
TCI Chemical
Product number
C1658
Product name
Chlorodicyclohexylphosphine
Purity
>97.0%(T)
Packaging
1g
Price
$52
Updated
2024/03/01
TCI Chemical
Product number
C1658
Product name
Chlorodicyclohexylphosphine
Purity
>97.0%(T)
Packaging
5g
Price
$226
Updated
2024/03/01
Alfa Aesar
Product number
033571
Product name
Dicyclohexylchlorophosphine, 98+%
Packaging
1g
Price
$128.65
Updated
2024/03/01
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Dicyclohexylchlorophosphine Chemical Properties,Usage,Production

Chemical Properties

clear colorless liquid

Uses

Dicyclohexylchlorophosphine is used as pharmaceutical intermediate. It is also used in the synthesis of various phosphines.

Uses

Chlorodicyclohexylphosphine can be used as a reactant in the synthesis of:

  • 1,2-Bis(dicyclohexylphosphinoxy)ethane ligand by reacting with ethylene glycol in the presence of triethylamine via Michaelis?Arbuzov type rearrangements.
  • 1,1,2,2-tetracyclohexyldiphosphine monosulfide ligand by treating with LiS.

It can be also used as a starting material for the preparation of some other ligands such as dicyclohexylphosphine oxide , phosphino substituted N-aryl pyrroles , di-tert-butyl((dicyclohexylphosphino)methyl)phosphine , dicyclohexylcyclopentylphosphine. These ligands are used in Pd-catalyzed cross-coupling reactions.

Application

Chlorodicyclohexylphosphine can be used as a reactant in the synthesis of:
1,2-Bis(dicyclohexylphosphinoxy)ethane ligand by reacting with ethylene glycol in the presence of triethylamine via Michaelis?Arbuzov type rearrangements.
1,1,2,2-tetracyclohexyldiphosphine monosulfide ligand by treating with LiS.
It can be also used as a starting material for the preparation of some other ligands such as dicyclohexylphosphine oxide , phosphino substituted N-aryl pyrroles , di-tert-butyl((dicyclohexylphosphino)methyl)phosphine , dicyclohexylcyclopentylphosphine. These ligands are used in Pd-catalyzed cross-coupling reactions.

Precautions

Store in cool, dry conditions in well sealed containers. Protect from humidity and water. Store under dry inert gas. It is sensitive to air and moisture. Incompatible with strong oxidizing agents.

Dicyclohexylchlorophosphine Preparation Products And Raw materials

Raw materials

Preparation Products

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Dicyclohexylchlorophosphine Suppliers

He' nan ruisiqi new material co., ltd
Tel
18903931628
Email
researchvip@163.com
Country
China
ProdList
215
Advantage
58
Puyang Huicheng Electronic Material Co. Ltd.
Tel
0393-0393-8910800 18236056670
Fax
0393-8912775
Email
info@huichengchem.com
Country
China
ProdList
549
Advantage
64
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40241
Advantage
62
INTATRADE GmbH
Tel
+49 3493/605464
Fax
+49 3493/605470
Email
sales@intatrade.de
Country
Germany
ProdList
3576
Advantage
66
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30132
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24539
Advantage
81
BeiJing Hwrk Chemicals Limted
Tel
0757-86329057 18501085097
Fax
010-89508210
Email
sales3.gd@hwrkchemical.com
Country
China
ProdList
7583
Advantage
55
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44751
Advantage
61
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028 13552068683
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12426
Advantage
60
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View Lastest Price from Dicyclohexylchlorophosphine manufacturers

Shanghai UCHEM Inc.
Product
Dicyclohexylchlorophosphine 16523-54-9
Price
US $59.00-485.00/g
Min. Order
25g
Purity
0.98
Supply Ability
25kg
Release date
2023-12-21
XINXIANG RUNYU MATERIAL CO., LTD.
Product
Dicyclohexylchlorophosphine 16523-54-9
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
97%
Supply Ability
500kg
Release date
2023-12-15
Hangzhou ICH Biofarm Co., Ltd
Product
Dicyclohexylchlorophosphine 16523-54-9
Price
US $0.00-0.00/kg
Min. Order
0.1kg
Purity
99.0%min
Supply Ability
200kg
Release date
2023-06-09

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