Dicyclohexylchlorophosphine
- Product Name
- Dicyclohexylchlorophosphine
- CAS No.
- 16523-54-9
- Chemical Name
- Dicyclohexylchlorophosphine
- Synonyms
- chlorodicyclohexylphosphane;CHLORODICYCLOHEXYLPHOSPHINE;Cy2PCl;orodicycL;98% (C6H11)2PCl;DICYCLOHEXYLCHLOROPHOSPHINE;Dicyclohexylphosphine chloride;Chlorodicyclohexylphosphine 97%;Chlorodicyclohexylphosphine,97%;Chlorodicyclohexylphosphine >
- CBNumber
- CB3345601
- Molecular Formula
- C12H22ClP
- Formula Weight
- 232.73
- MOL File
- 16523-54-9.mol
Dicyclohexylchlorophosphine Property
- Melting point:
- 126-128 °C
- Boiling point:
- 165 °C/12 mmHg (lit.)
- Density
- 1.054 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.533(lit.)
- Flash point:
- >230 °F
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- Liquid
- Specific Gravity
- 1.054
- color
- Colorless to pale yellow
- Water Solubility
- reacts violently
- Sensitive
- Air & Moisture Sensitive
- InChI
- InChI=1S/C12H22ClP/c13-14(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h11-12H,1-10H2
- InChIKey
- AKJFBIZAEPTXIL-UHFFFAOYSA-N
- SMILES
- P(C1CCCCC1)(C1CCCCC1)Cl
- CAS DataBase Reference
- 16523-54-9(CAS DataBase Reference)
Safety
- Hazard Codes
- C
- Risk Statements
- 14-34
- Safety Statements
- 26-27-36/37/39-45-8
- RIDADR
- UN 3265 8/PG 2
- WGK Germany
- 3
- TSCA
- No
- HazardClass
- 8
- PackingGroup
- II
- HS Code
- 29319090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P363Wash contaminated clothing before reuse.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- 481408
- Product name
- Chlorodicyclohexylphosphine
- Purity
- 97%
- Packaging
- 1g
- Price
- $83.5
- Updated
- 2024/03/01
- Product number
- 481408
- Product name
- Chlorodicyclohexylphosphine
- Purity
- 97%
- Packaging
- 5g
- Price
- $283
- Updated
- 2024/03/01
- Product number
- C1658
- Product name
- Chlorodicyclohexylphosphine
- Purity
- >97.0%(T)
- Packaging
- 1g
- Price
- $52
- Updated
- 2024/03/01
- Product number
- C1658
- Product name
- Chlorodicyclohexylphosphine
- Purity
- >97.0%(T)
- Packaging
- 5g
- Price
- $226
- Updated
- 2024/03/01
- Product number
- 033571
- Product name
- Dicyclohexylchlorophosphine, 98+%
- Packaging
- 1g
- Price
- $128.65
- Updated
- 2024/03/01
Dicyclohexylchlorophosphine Chemical Properties,Usage,Production
Chemical Properties
clear colorless liquid
Uses
Dicyclohexylchlorophosphine is used as pharmaceutical intermediate. It is also used in the synthesis of various phosphines.
Uses
Chlorodicyclohexylphosphine can be used as a reactant in the synthesis of:
- 1,2-Bis(dicyclohexylphosphinoxy)ethane ligand by reacting with ethylene glycol in the presence of triethylamine via Michaelis?Arbuzov type rearrangements.
- 1,1,2,2-tetracyclohexyldiphosphine monosulfide ligand by treating with LiS.
It can be also used as a starting material for the preparation of some other ligands such as dicyclohexylphosphine oxide , phosphino substituted N-aryl pyrroles , di-tert-butyl((dicyclohexylphosphino)methyl)phosphine , dicyclohexylcyclopentylphosphine. These ligands are used in Pd-catalyzed cross-coupling reactions.
Application
Chlorodicyclohexylphosphine can be used as a reactant in the synthesis of:
1,2-Bis(dicyclohexylphosphinoxy)ethane ligand by reacting with ethylene glycol in the presence of triethylamine via Michaelis?Arbuzov type rearrangements.
1,1,2,2-tetracyclohexyldiphosphine monosulfide ligand by treating with LiS.
It can be also used as a starting material for the preparation of some other ligands such as dicyclohexylphosphine oxide , phosphino substituted N-aryl pyrroles , di-tert-butyl((dicyclohexylphosphino)methyl)phosphine , dicyclohexylcyclopentylphosphine. These ligands are used in Pd-catalyzed cross-coupling reactions.
Precautions
Store in cool, dry conditions in well sealed containers. Protect from humidity and water. Store under dry inert gas. It is sensitive to air and moisture. Incompatible with strong oxidizing agents.
Dicyclohexylchlorophosphine Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Dicyclohexylchlorophosphine manufacturers
- Product
- Dicyclohexylchlorophosphine 16523-54-9
- Price
- US $0.00-0.00/Kg
- Min. Order
- 1Kg
- Purity
- 99％
- Supply Ability
- 100kg
- Release date
- 2024-07-26
- Product
- Dicyclohexylchlorophosphine 16523-54-9
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20 mt
- Release date
- 2024-11-14
- Product
- Dicyclohexylchlorophosphine 16523-54-9
- Price
- US $59.00-485.00/g
- Min. Order
- 25g
- Purity
- 0.98
- Supply Ability
- 25kg
- Release date
- 2023-12-21