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Trimethylamine hydrochloride

Product Name
Trimethylamine hydrochloride
CAS No.
593-81-7
Chemical Name
Trimethylamine hydrochloride
Synonyms
TRIMETHYLAMMONIUM CHLORIDE;TRIMETHYLAMINE HCL;FEMA 3241;Trimthylamine bydrochloride;N, N-DIMETHYLMETHYLAMINE HCL;Trimethylamine monohydrochloride;Trimethylammonium monohydrochloride;Methanamine,N,N-dimethyl-,hydrochloride;HJ 1042-2019);TrimethylamineHcl99%
CBNumber
CB8770378
Molecular Formula
C3H10ClN
Formula Weight
95.57
MOL File
593-81-7.mol
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Trimethylamine hydrochloride Property

Melting point:
283-284 °C (dec.)(lit.)
Boiling point:
132.32°C (rough estimate)
Density 
0.9337 (rough estimate)
vapor pressure 
0Pa at 25℃
refractive index 
1.4413 (estimate)
storage temp. 
Store below +30°C.
solubility 
SOLUBLE
form 
Crystalline Powder
color 
White to slightly cream
PH
5 (100g/l, H2O, 20℃)
Water Solubility 
SOLUBLE
Sensitive 
Hygroscopic
Merck 
14,9710
BRN 
3905063
Stability:
Hygroscopic
InChIKey
SZYJELPVAFJOGJ-UHFFFAOYSA-N
LogP
-2.25 at 25℃
CAS DataBase Reference
593-81-7(CAS DataBase Reference)
NIST Chemistry Reference
Methanamine,n,n-dimethyl-,hydrochloride(593-81-7)
EPA Substance Registry System
Trimethylamine hydrochloride (593-81-7)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38-38-36
Safety Statements 
26-36-37/39
WGK Germany 
1
RTECS 
YH2700000
3-10
TSCA 
Yes
HS Code 
29211190
Hazardous Substances Data
593-81-7(Hazardous Substances Data)
Toxicity
LD50 orally in Rabbit: 3090 mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
T72761
Product name
Trimethylamine hydrochloride
Purity
98%
Packaging
25g
Price
$23.3
Updated
2024/03/01
Sigma-Aldrich
Product number
8.21178
Product name
Trimethylammonium chloride
Purity
for synthesis
Packaging
5G
Price
$35.5
Updated
2024/03/01
Sigma-Aldrich
Product number
8.21178
Product name
Trimethylammonium chloride
Purity
for synthesis
Packaging
250g
Price
$117
Updated
2024/03/01
Sigma-Aldrich
Product number
41284
Product name
Trimethylamine hydrochloride
Purity
analytical standard
Packaging
100mg
Price
$86.3
Updated
2024/03/01
TCI Chemical
Product number
T0465
Product name
Trimethylamine Hydrochloride
Purity
>98.0%(N)
Packaging
100g
Price
$25
Updated
2024/03/01
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Trimethylamine hydrochloride Chemical Properties,Usage,Production

Chemical Properties

white to slightly cream crystalline powder

Uses

Trimethylamine hydrochloride is used in the manufacture of quaternary ammonium compounds, as insect attractant. It is also used as a raw material for the synthesis of choline chloride and ion exchange resins. Additionally, It acts as a cationic starch reagent, phase transfer catalyst, oil field chemicals, warning agent for natural gas and flotation agent.

Application

Trimethylamine hydrochloride(593-81-7) is a precursor to prepare aluminium chloride- trimethylamine hydrochloride ionic liquid, which is commonly used in electrodeposition of aluminum wires. It is also used in the synthesis of trimethylamine gallane, trimethylamine-borane and azido-bridged perovskite-type metal-organic frameworks (MOFs).

Definition

ChEBI: Trimethylamine hydrochloride is a hydrochloride salt formed by reaction of equimolar amounts of trimethylamine and hydrogen chloride. It contains a trimethylammonium.

Preparation

Trimethylamine hydrochloride can be synthesized through the reaction of trimethylamine (TMA) and hydrochloric acid (HCl). The synthesis reaction can be written as follows:
C3H9N+ HCl → C3H10ClN
The following steps are involved in obtaining trimethylamine hydrochloride:
Step 1: Evaporation of hydrochloric acid solution The hydrochloric acid solution is evaporated, first over a free flame, and later on a steam bath. This process results in concentration of the solution, which aids in the formation of trimethylamine hydrochloride crystals.
Step 2: Crystal formation and filtration As the solution becomes more and more concentrated, the trimethylamine hydrochloride crystals begin to form. The crystals are filtered periodically to remove them from the solution.
Step 3: Drying The filtered crystals are dried in an air bath for a few minutes, with a temperature range of 100-110°.
Step 4: Storage The air-dried crystals are then stored in a tightly closed bottle.
Step 5: Centrifugation (optional) If the trimethylamine hydrochloride crystals are centrifuged, the product is obtained pure and dry.
Overall, four runs yield an average of 710 g of pure trimethylamine hydrochloride and 82 g of slightly yellow-tinted product. This yield is equivalent to 89% of the theoretical amount based on ammonium chloride. The slight yellow coloration results from the evaporation of the last traces of solution.
DOI: 10.15227/orgsyn.001.0079

Flammability and Explosibility

Non flammable

Purification Methods

The salt crystallises from CHCl3, EtOH or n-propanol, and is dried under vacuum. It also crystallises from *benzene/MeOH, MeOH/diethyl ether and is dried under vacuum over paraffin wax and H2SO4. It is kept over P2O5 as it is hygroscopic.[Beilstein 4 H 262, 4 I 419, 4 IV 138.]

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Trimethylamine hydrochloride Suppliers

Hebei Guanlang Biotechnology Co., Ltd.
Tel
19930505208
Email
515253120@qq.com
Country
China
ProdList
306
Advantage
58
Jinan Wald Chemical Co., Ltd.
Tel
0531-88773586 13210588999
Fax
053188773586
Email
304264064@qq.com
Country
China
ProdList
195
Advantage
58
Shenyang Snota Biotech Co.,Ltd
Tel
+86-024-31174117 +86-18002429090
Fax
024-31174117
Email
2193387905@qq.com
Country
China
ProdList
103
Advantage
58
Hebei Clavier Biotechnology Co., LTD
Tel
19930508148
Email
1350255213@qq.com
Country
China
ProdList
912
Advantage
58
Hebei Guanlang Biotechnology Co., Ltd.
Tel
13383116422
Email
3381425553@qq.com
Country
China
ProdList
997
Advantage
58
Liaocheng Lebote Biopharmaceutical Technology Co., Ltd
Tel
0635-893290 18663513896;
Email
28698871@qq.com
Country
China
ProdList
8531
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94838
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40241
Advantage
62
future industrial shanghai co., ltd
Tel
400-0066400 13621662912
Fax
021-55660885
Email
sales@jonln.com
Country
China
ProdList
1998
Advantage
65
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30132
Advantage
84
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View Lastest Price from Trimethylamine hydrochloride manufacturers

Shandong Hanjiang Chemical Co., Ltd
Product
Trimethylamine hydrochloride 593-81-7
Price
US $0.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
10T
Release date
2024-01-19
Dorne Chemical Technology co. LTD
Product
Trimethylamine hydrochloride 593-81-7
Price
US $10.00/ASSAYS
Min. Order
1ASSAYS
Purity
99%
Supply Ability
10 ton
Release date
2024-03-26
Nanjing Deda New Material Technology Co., Ltd
Product
Trimethylamine Hydrochlorate 593-81-7
Price
US $15.00-10.00/kg
Min. Order
1kg
Purity
99.5
Supply Ability
10 ton per month
Release date
2023-11-23

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