Carbonylchlorohydrotris(triphenylphosphine)ruthenium

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Carbonylchlorohydrotris(triphenylphosphine)ruthenium

Reaction

Product Name: Carbonylchlorohydrotris(triphenylphosphine)ruthenium
CAS No.: 16971-33-8
Chemical Name: Carbonylchlorohydrotris(triphenylphosphine)ruthenium
Synonyms: RuHCl(CO)(PPh3)3;Carbonylchlorohydridotris(triphenylphosphine)ruthenium;Ru(CO)ClH(PPh3)3;mer-RuH(PPh3)3(CO)Cl;Carbonylchlorohydridotris;carbonylchlorohydridotris(triphenyl-phosphine)rut;Carbonylchlorohydrido tris (triphenylphosphine) ru;carbonylchlorohydrotris(triphenylphosphine)ruthenium;Carbonylchlorohydrotris(triphen-ylphosphineruthenium(Ⅱ);Hydridochlorocarbonyltris-(triphenylphosphino)-ruthenium
CBNumber: CB8487823
Molecular Formula: C55H45ClOP3Ru
Formula Weight: 951.39
MOL File: 16971-33-8.mol

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Carbonylchlorohydrotris(triphenylphosphine)ruthenium Property

Melting point:: 204-206 °C (dec.)(lit.)
Boiling point:: approximate 360℃
storage temp.: Keep in dark place,Inert atmosphere,Room temperature
form: Powder
color: Cream to tan
Water Solubility: insoluble
Sensitive: Air stable, light sensitive

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Safety

Hazard Codes: Xn,T
Risk Statements: 20/21/22-36/37/38
Safety Statements: 26-37/39-36/37/39-22
WGK Germany: 3
HS Code: 29310099

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 334995
Product name: Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II)
Packaging: 1g
Price: $133
Updated: 2024/03/01

Sigma-Aldrich

Product number: 334995
Product name: Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II)
Packaging: 5g
Price: $383
Updated: 2024/03/01

Alfa Aesar

Product number: 044955
Product name: Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II)
Packaging: 1g
Price: $93.65
Updated: 2024/03/01

Alfa Aesar

Product number: 044955
Product name: Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II)
Packaging: 5g
Price: $417
Updated: 2024/03/01

Strem Chemicals

Product number: 44-0085
Product name: Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II), 99%
Packaging: 1g
Price: $82
Updated: 2024/03/01

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Carbonylchlorohydrotris(triphenylphosphine)ruthenium Chemical Properties,Usage,Production

Reaction

Catalyst for alcohol α-allylation with dienes or allenes under transfer hydrogenation conditions.
Catalyst for tandem isomerization (to imine), followed by Friedel Crafts alkylation.
Catalyst for amination of alcohols with ammonia.

Chemical Properties

pale yellow crystals

Uses

Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II) is used as a raw material to synthesize other ru-hydride catalysts. It is involved in the hydrogenation of ring-opening metathesis polymers such as norbornene and other cyclic olefin ROMP polymers used as plastics, resins and optical materials. It can act as an alternative catalyst to rhodium hydrogenation catalyst. It also serves as a catalyst in the hydrogenation of conjugated diene copolymers like acrylonitrile-butadiene rubber (NBR).

Carbonylchlorohydrotris(triphenylphosphine)ruthenium Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Carbonylchlorohydrotris(triphenylphosphine)ruthenium manufacturers

Career Henan Chemical Co

Product: Carbonylchlorohydrotris(triphenylphosphine)ruthenium 16971-33-8
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 200kg
Release date: 2019-07-03

16971-33-8, Carbonylchlorohydrotris(triphenylphosphine)rutheniumRelated Search:

METHOXYCARBONYLSULFENYL CHLORIDE Ruthenium Tris(triphenylphosphine)rhodiu Ruthenium(III) chloride Triphenylphosphine Tris(dibenzylideneacetone)dipalladium Tris(dibenzylideneacetone)dipalladium Hexachloroiridic acid hexahydrate Tris(triphenylphosphine)ruthenium(II) chloride Rhodium (triphenylphosphine)carbonylacetylacetonate Iridium(III) acetylacetonate [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Chloroplantinic acid Platinum dioxide Palladium (II) Acetate DICHLORODICARBONYLBIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II) Carbonyldihydrotris(triphenylphosphine)ruthenium CHLOROHYDRIDOTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II)

CARBONYLCHLOROHYDRIDOTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II)

carbonylchlorohydridotris(triphenyl-phosphine)rut

carbonylchlorohydrotris(triphenylphosphine)ruthenium

Hydridochlorocarbonyltris-(triphenylphosphino)-ruthenium

Carbonylchlorohydridotris(triphenylphosphine)ruthenium

Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II),99%

Ru(CO)ClH(PPh3)3

RuHCl(CO)(PPh3)3

mer-RuH(PPh3)3(CO)Cl

Carbonylchlorohydrido tris (triphenylphosphine) ru

Carbonylchlorohydridotris(triphenylphosphine)rutheniuM(II),98% (PPh3)3(CO)HRuCl

Carbonylchlorohydridotris(triphenylphosphine)ruthenium(Ⅱ)

Carbonylchlorohydrotris(triphenylphosphine)ruthenium(II)

Carbonylchlorohydrotris(triphenylphosphine)ruthenium ISO 9001：2015 REACH

16971-33-8 Carbonylchlorohydrotris(triphenylphosphine)ruthenium

Carbonylchlorohydridotris(triphenylphosphine)ruthenium(Il)

Carbonylchlorohydrotris(triphen-ylphosphineruthenium(Ⅱ)

[carbonylchlorohydridotris(triphenylphosphane)ruthenium(II)]

Carbonylchlorohydridotris

Chlorocarbonylhydridotris(triphenylphosphine)ruthenium(II)

16971-33-8

C55H47ClOP3Ru

C55H45ClOP3Ru

RuCOClHPC6H533

C6H53P3RuCOClH

C55H46ClOP3Ru

Ru Catalysts

Catalysis and Inorganic Chemistry

metal carbonyl complex

Ru Catalysts

Ruthenium

Catalysis and Inorganic Chemistry