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Carbonylchlorohydrotris(triphenylphosphine)ruthenium

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Product Name
Carbonylchlorohydrotris(triphenylphosphine)ruthenium
CAS No.
16971-33-8
Chemical Name
Carbonylchlorohydrotris(triphenylphosphine)ruthenium
Synonyms
RuHCl(CO)(PPh3)3;Carbonylchlorohydridotris(triphenylphosphine)ruthenium;Ru(CO)ClH(PPh3)3;mer-RuH(PPh3)3(CO)Cl;Carbonylchlorohydridotris;carbonylchlorohydridotris(triphenyl-phosphine)rut;Carbonylchlorohydrido tris (triphenylphosphine) ru;carbonylchlorohydrotris(triphenylphosphine)ruthenium;Carbonylchlorohydrotris(triphen-ylphosphineruthenium(Ⅱ);Hydridochlorocarbonyltris-(triphenylphosphino)-ruthenium
CBNumber
CB8487823
Molecular Formula
C55H45ClOP3Ru
Formula Weight
951.39
MOL File
16971-33-8.mol
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Carbonylchlorohydrotris(triphenylphosphine)ruthenium Property

Melting point:
204-206 °C (dec.)(lit.)
Boiling point:
approximate 360℃
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
form 
Powder
color 
Cream to tan
Water Solubility 
insoluble
Sensitive 
Air stable, light sensitive
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Safety

Hazard Codes 
Xn,T
Risk Statements 
20/21/22-36/37/38
Safety Statements 
26-37/39-36/37/39-22
WGK Germany 
3
HS Code 
29310099
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
334995
Product name
Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II)
Packaging
1g
Price
$133
Updated
2024/03/01
Sigma-Aldrich
Product number
334995
Product name
Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II)
Packaging
5g
Price
$383
Updated
2024/03/01
Alfa Aesar
Product number
044955
Product name
Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II)
Packaging
1g
Price
$93.65
Updated
2024/03/01
Alfa Aesar
Product number
044955
Product name
Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II)
Packaging
5g
Price
$417
Updated
2024/03/01
Strem Chemicals
Product number
44-0085
Product name
Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II), 99%
Packaging
1g
Price
$82
Updated
2024/03/01
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Carbonylchlorohydrotris(triphenylphosphine)ruthenium Chemical Properties,Usage,Production

Reaction

  1. Catalyst for alcohol α-allylation with dienes or allenes under transfer hydrogenation conditions.
  2. Catalyst for tandem isomerization (to imine), followed by Friedel Crafts alkylation.
  3. Catalyst for amination of alcohols with ammonia.

Chemical Properties

pale yellow crystals

Uses

Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II) is used as a raw material to synthesize other ru-hydride catalysts. It is involved in the hydrogenation of ring-opening metathesis polymers such as norbornene and other cyclic olefin ROMP polymers used as plastics, resins and optical materials. It can act as an alternative catalyst to rhodium hydrogenation catalyst. It also serves as a catalyst in the hydrogenation of conjugated diene copolymers like acrylonitrile-butadiene rubber (NBR).

Carbonylchlorohydrotris(triphenylphosphine)ruthenium Preparation Products And Raw materials

Raw materials

Preparation Products

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Carbonylchlorohydrotris(triphenylphosphine)ruthenium Suppliers

Acros Organics
Tel
--
Fax
--
Email
info@acros.com
Country
Belgium
ProdList
6772
Advantage
81
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View Lastest Price from Carbonylchlorohydrotris(triphenylphosphine)ruthenium manufacturers

Career Henan Chemical Co
Product
Carbonylchlorohydrotris(triphenylphosphine)ruthenium 16971-33-8
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
200kg
Release date
2019-07-03

16971-33-8, Carbonylchlorohydrotris(triphenylphosphine)rutheniumRelated Search:


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  • Carbonylchlorohydrotris(triphenylphosphine)ruthenium(II)
  • Carbonylchlorohydrotris(triphenylphosphine)ruthenium ISO 9001:2015 REACH
  • 16971-33-8 Carbonylchlorohydrotris(triphenylphosphine)ruthenium
  • Carbonylchlorohydridotris(triphenylphosphine)ruthenium(Il)
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  • C55H47ClOP3Ru
  • C55H45ClOP3Ru
  • RuCOClHPC6H533
  • C6H53P3RuCOClH
  • C55H46ClOP3Ru
  • Ru Catalysts
  • Catalysis and Inorganic Chemistry
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  • metal carbonyl complex
  • Ru Catalysts
  • Ruthenium
  • Catalysis and Inorganic Chemistry