Dichloro(1,5-cyclooctadiene)platinum(II)

Product Name: Dichloro(1,5-cyclooctadiene)platinum(II)
CAS No.: 12080-32-9
Chemical Name: Dichloro(1,5-cyclooctadiene)platinum(II)
Synonyms: pt(cod)cl2;Dichloro(1,5-cyclooctadiene)platinum;NSC 239486;ooctadiene)pL;Platinum(COD)dichloride;Dichloro(1,5-cyclooctadiene);5-cyclooctadiene)platinum(II);1,5-Cyclooctadienedichloroplatinum;Dichloro(1,5-cyclooctadiene)platin(II);Dichloro(1,5-cyclooctadiene)platinum(Ⅱ)
CBNumber: CB8338684
Molecular Formula: C8H12Cl2Pt
Formula Weight: 374.16
MOL File: 12080-32-9.mol

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Dichloro(1,5-cyclooctadiene)platinum(II) Property

Melting point:: 285 °C (dec.) (lit.)
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
solubility: Soluble in dichloromethane
form: Crystals or Crystalline Powder
color: White to pale yellow
Water Solubility: insoluble
Sensitive: Hygroscopic
InChI: InChI=1S/C8H12.2ClH.Pt/c1-2-4-6-8-7-5-3-1;;;/h1-2,7-8H,3-6H2;2*1H;/q;;;+2/p-2/b2-1-,8-7-;;;
InChIKey: VVAOPCKKNIUEEU-PHFPKPIQSA-L
SMILES: C1CC=CCCC=C1.[Pt](Cl)Cl |c:2,6|
CAS DataBase Reference: 12080-32-9(CAS DataBase Reference)
NIST Chemistry Reference: (Cyclocta-1,5-diene)platinum(ii)chloride(12080-32-9)
EPA Substance Registry System: Platinum, dichloro[(1,2,5,6-.eta.)-1,5-cyclooctadiene]- (12080-32-9)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-37/39
WGK Germany: 3
TSCA: TSCA listed
HS Code: 28439000
Storage Class: 11 - Combustible Solids
Hazard Classifications: Eye Irrit. 2
Skin Irrit. 2
STOT SE 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 244937
Product name: Dichloro(1,5-cyclooctadiene)platinum(II)
Packaging: 250mg
Price: $43.42
Updated: 2025/07/31

Sigma-Aldrich

Product number: 244937
Product name: Dichloro(1,5-cyclooctadiene)platinum(II)
Packaging: 1g
Price: $179
Updated: 2025/07/31

TCI Chemical

Product number: D3592
Product name: Dichloro(1,5-cyclooctadiene)platinum(II)
Packaging: 1g
Price: $337
Updated: 2025/07/31

TCI Chemical

Product number: D3592
Product name: Dichloro(1,5-cyclooctadiene)platinum(II)
Packaging: 200mg
Price: $115
Updated: 2025/07/31

Strem Chemicals

Product number: 78-0430
Product name: Dichloro(1,5-cyclooctadiene)platinum(II), 99%
Packaging: 250mg
Price: $53
Updated: 2024/03/01

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Dichloro(1,5-cyclooctadiene)platinum(II) Chemical Properties,Usage,Production

Chemical Properties

white to pale yellow

Uses

it is used in Hydrosilyation reactions.

Uses

Catalyst for:

Hydrogenative cyclization of allenynes
Stereoselective tandem hydrosilylation-Hiyama coupling reactions
Amino alkene cyclohydroamination
Hydrative cyclization reactions
Direct amination of allylic alcohols under mild conditions

Potential anticancer agent

reaction suitability

core: platinum
reagent type: catalyst

Synthesis

10025-99-7

5259-72-3

12080-32-9

2.1.4.1 Synthesis of cis-dichloro(1,5-cyclooctadiene)platinum(II), [Pt(cod)Cl2] (0014): K2PtCl4 (1.000 g, 2.4 mmol) was dissolved in water (16 mL) and the resulting solution was filtered. Acetic acid (24 mL) and 1,5-cyclooctadiene (cod) (1.00 mL, 8.1 mmol) were sequentially added to the filtrate under light protection. The reaction mixture was stirred and heated in a water bath at about 100°C. Within 30 minutes, the dark red solution gradually changed to a pale yellow color with the formation of a precipitate. After about 2 h, the solution was concentrated to a volume of 10 mL by distillation under reduced pressure, after which the resulting precipitate was separated by centrifugation and washed sequentially with water, ethanol and ether. Product yield: 703 mg (80%).1H NMR (CDCl3) δ: 5.60 (4H, t, CH), 2.70 (2H, m, CH2-CH), 2.30-2.16 (2H, m, CH2-CH) ppm; 13C{1H} NMR (CDCl3) δ: 100.0 (CH), 30.0 (CH2) ppm. 195Pt NMR (CDCl3) δ: -3340 ppm.

References

[1] Chemistry - An Asian Journal, 2018, vol. 13, # 8, p. 1053 - 1059
[2] Dalton Transactions, 2008, # 47, p. 6724 - 6731
[3] Organometallics, 2014, vol. 33, # 15, p. 4027 - 4034
[4] Journal of the American Chemical Society, 2015, vol. 137, # 42, p. 13464 - 13467
[5] Journal of Inorganic Biochemistry, 2016, vol. 160, p. 275 - 286

Dichloro(1,5-cyclooctadiene)platinum(II) Preparation Products And Raw materials

Raw materials

Stannous chloride dihydrate Potassium tetrachloroplatinate(II) 1,5-Cyclooctadiene 1-Propanol

Preparation Products

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Dichloro(1,5-cyclooctadiene)platinum(II) Suppliers

Americas 1 Belgium 2 China 185 Europe 1 Germany 3 India 4 Japan 2 South Korea 1 Switzerland 1 United Kingdom 5 United States 24 Global 229

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View Lastest Price from Dichloro(1,5-cyclooctadiene)platinum(II) manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

Product: Dichloro(1,5-cyclooctadiene)platinum(II) 12080-32-9
Price: US $2.00-5.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 100kg
Release date: 2025-06-17

Hebei Chuanghai Biotechnology Co., Ltd

Product: Dichloro(1,5-cyclooctadiene)platinum(II) 12080-32-9
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100 MT
Release date: 2024-11-14

Zhuozhou Wenxi import and Export Co., Ltd

Product: Dichloro(1,5-cyclooctadiene)platinum(II) 12080-32-9
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-06-27

12080-32-9, Dichloro(1,5-cyclooctadiene)platinum(II)Related Search:

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pt(cod)cl2

Dichloro(1,5-cyclooctadiene)platinum(II) 250 dec.

Dichloro(1,5-cyclooctadiene)platinum(II),98%

Dichloro(1,5-cyclooctadiene)platinum(II), Pt 51.6-52.6%

Dichloro(1,5-cyclooctadiene)platinum(II),99%

5-cyclooctadiene)platinum(II)

Dichloro(cycloocta-1,5-diene)platinum(II),Pt52.1%

Dichloro(1,5-cyclooctadiene)platinum(II) ,98% [C%:24.15-27.15%]

Dichloro(1,5-cyclooctadiene)platinum(II),Pt(COD)Cl2

Dichloro(1,5-cyclooctadiene)platin(II)

Dichloro(1,5-cyclooctadiene)platinum(Ⅱ)

Dichloro(1,5-cyclooctadiene)platinum(II) (1,5-Cyclooctadiene)platinum(II) dichloride

(1,5-Cyclooctadiene)platinum dichloride

NSC 239486

Dichloro(1,5-cyclooctadiene)

(1,5-CYCLOOCTADIENE)PLATINUM(II) DICHLORIDE

1,5-Cyclooctadienedichloroplatinum

Dichloro(1,5-cyclooctadiene)platinum

dichloro[(1,2,5,6-eta)-1,5-cyclooctadiene]-platinu

Platinum, dichloro(1,5-cyclooctadiene)-

Platinum, dichloro[(1,2,5,6-eta)-1,5-cyclooctadiene]-

DICHLORO(1,5-CYCLOOCTADIENE)PLATINATE (II)

DICHLORO(1,5-CYCLOOCTADIENE)PLATINUM(II)

DICHLORO(CYCLOOCTA-1,5-DIENE)PLATINUM(II)

DICHLORO(ETA-CYCLOOCTA-1,5-DIENE)PLATINUM (II)

dichloro[(1,2,5,6-eta)-cycloocta-1,5-diene]platinum

Platinum(COD)dichloride

ooctadiene)pL

Dichloro(1,5-cyclooctadiene)platinum(II) ISO 9001：2015 REACH

Dichloro[(1,2,5,6-η)-1,5-cyclooctadiene]-platinum

Dichloro(1,5-cyclooctadiene) platinium(II)

(1Z,5Z)-cycloocta-1,5-diene dichloroplatinum

ichloro(1,5-cyclooctadiene)platinum(II)

Dichloro(1,5-cyclooctadiene)platinum (Ⅱ)

12080-32-9

PtCl2C8H12

C8H12Cl2Pt

PtCl215C8H12

Catalysis and Inorganic Chemistry

Catalysts for Organic Synthesis

Classes of Metal Compounds

Homogeneous Catalysts

Metal Complexes

Pt (Platinum) Compounds

Synthetic Organic Chemistry

Transition Metal Compounds

chemical reaction,pharm,electronic,materials

organometallic complexes

Pt