Dichloro(1,5-cyclooctadiene)palladium(II)
- Product Name
- Dichloro(1,5-cyclooctadiene)palladium(II)
- CAS No.
- 12107-56-1
- Chemical Name
- Dichloro(1,5-cyclooctadiene)palladium(II)
- Synonyms
- PdCl2(cod);1,5-CYCLOOCTADIENEPALLADIUM(II) DICHLORIDE;adium(Ⅱ);NSC 169973;ooctadiene)paL;Dichloro(1,5-cyclooctadience;DICHLORO(CYCLOOCTA-1,5-DIENE)PAL;Dichloro-(1,5-cyclooctadiene)-palladium;Dichloro(1,5-cyclooctadiene)palladium(Ⅱ);Dichloro(1,5-cyclooctadiene)palladium(Ⅱ)
- CBNumber
- CB5488849
- Molecular Formula
- C8H12Cl2Pd
- Formula Weight
- 285.51
- MOL File
- 12107-56-1.mol
Dichloro(1,5-cyclooctadiene)palladium(II) Property
- Melting point:
- 210 °C (dec.) (lit.)
- storage temp.
- Inert atmosphere,Room Temperature
- solubility
- Soluble in dichloromethane
- form
- crystal
- color
- yellow
- Water Solubility
- insoluble
- Sensitive
- Hygroscopic
- InChI
- InChI=1S/C8H12.2ClH.Pd/c1-2-4-6-8-7-5-3-1;;;/h1-2,7-8H,3-6H2;2*1H;/q;;;+2/p-2/b2-1-,8-7-;;;
- InChIKey
- NEKYMUKEOUDFPP-XRGHXPOKSA-L
- SMILES
- C1CC=CCCC=C1.[Pd](Cl)Cl |c:2,6|
- CAS DataBase Reference
- 12107-56-1(CAS DataBase Reference)
- EPA Substance Registry System
- Palladium, dichloro[(1,2,5,6-.eta.)-1,5-cyclooctadiene]- (12107-56-1)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 275891
- Product name
- Dichloro(1,5-cyclooctadiene)palladium(II)
- Purity
- 99%
- Packaging
- 2g
- Price
- $238.28
- Updated
- 2025/07/31
- Product number
- D2604
- Product name
- Dichloro(1,5-cyclooctadiene)palladium(II)
- Purity
- >98.0%(T)
- Packaging
- 1g
- Price
- $346
- Updated
- 2025/07/31
- Product number
- D2604
- Product name
- Dichloro(1,5-cyclooctadiene)palladium(II)
- Purity
- >98.0%(T)
- Packaging
- 5g
- Price
- $1261
- Updated
- 2025/07/31
- Product number
- 46-0650
- Product name
- Dichloro(1,5-cyclooctadiene)palladium(II), 99%
- Packaging
- 250mg
- Price
- $42
- Updated
- 2024/03/01
- Product number
- 46-0650
- Product name
- Dichloro(1,5-cyclooctadiene)palladium(II), 99%
- Packaging
- 1g
- Price
- $99
- Updated
- 2024/03/01
Dichloro(1,5-cyclooctadiene)palladium(II) Chemical Properties,Usage,Production
Chemical Properties
yellow
Uses
Dichloro(1,5-cyclooctadiene)palladium(II) is used as catalyst for C-C bond and C-N formation, used in Heck coupling of alkynes with alkenes, Suzuki cross-coupling of aryl bromides , allylic substitution of oximes with allylic acetate and methoxycarbonylation of iodobenzene.
Uses
Dichloro(1,5-cyclooctadiene)palladium(II) is a commonly used catalyst to protect alcohols as acetals by treating with 2-benzyloxy-1-propene; to synthesize bicyclooctanes from diethyl malonate and in alkene carbonylation. It can also be used to catalyze the Heck coupling of nonactivated vinyl phosphates with electron deficient alkenes; the synthesis of benzo[b]thiophenes from thioenols and to prepare an active catalyst for Mizoroki-Heck and Suzuki-Miyaura cross-coupling reactions.
Application
Used in alcohol protection; synthesis of carbamates, bicyclooctanes and alkene carbonylation.
reaction suitability
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
Synthesis
Dichloro(1,5-cyclooctadiene)palladium(II) is prepared in 96% yield by treating Palladium(II) Chloride with 1,5-cyclooctadiene in concentrated hydrochloric acid.
Dichloro(1,5-cyclooctadiene)palladium(II) Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Dichloro(1,5-cyclooctadiene)palladium(II) manufacturers
- Product
- Dichloro(1,5-cyclooctadiene)palladium(II) 12107-56-1
- Price
- US $2.00-5.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 100kg
- Release date
- 2025-06-17
- Product
- Dichloro(1,5-cyclooctadiene)palladium(II) 12107-56-1
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 1000kg
- Release date
- 2022-09-23
- Product
- Dichloro(1,5-cyclooctadiene)palladium(II) 12107-56-1
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- Customized
- Release date
- 2019-07-02