Diphenylacetylene
- Product Name
- Diphenylacetylene
- CAS No.
- 501-65-5
- Chemical Name
- Diphenylacetylene
- Synonyms
- Tolane;Diphenylethyne;1,2-Diphenylacetylene;TOLAN;Diphenilethyne;ethyne,diphenyl-;DIPHENYLACETYLENE;biphenylacetylene;Ethyne, diphenyl-;1,2-DIPHENYL ETHYNE
- CBNumber
- CB6198660
- Molecular Formula
- C14H10
- Formula Weight
- 178.23
- MOL File
- 501-65-5.mol
Diphenylacetylene Property
- Melting point:
- 59-61 °C (lit.)
- Boiling point:
- 170 °C/19 mmHg (lit.)
- Density
- 0.99 g/mL at 25 °C (lit.)
- refractive index
- 1.6415 (estimate)
- Flash point:
- 170°C/19mm
- storage temp.
- Sealed in dry,2-8°C
- form
- Crystalline Powder and Chunks
- color
- Light yellow to brownish
- Specific Gravity
- 0.99
- Water Solubility
- Miscible with ether and hot alcohol. Immiscible with water.
- Merck
- 14,9504
- BRN
- 606478
- Stability:
- Stable. Combustible. Incompatible with strong oxidizing agents.
- InChIKey
- JRXXLCKWQFKACW-UHFFFAOYSA-N
- CAS DataBase Reference
- 501-65-5(CAS DataBase Reference)
- NIST Chemistry Reference
- Diphenylethyne(501-65-5)
- EPA Substance Registry System
- Benzene, 1,1'-(1,2-ethynediyl)bis- (501-65-5)
Safety
- Safety Statements
- 24/25-22
- WGK Germany
- 3
- TSCA
- Yes
- HS Code
- 29029090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321Specific treatment (see … on this label).
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P362Take off contaminated clothing and wash before reuse.
N-Bromosuccinimide Price
- Product number
- D204803
- Product name
- Diphenylacetylene
- Purity
- 98%
- Packaging
- 5g
- Price
- $61.7
- Updated
- 2024/03/01
- Product number
- D204803
- Product name
- Diphenylacetylene
- Purity
- 98%
- Packaging
- 25g
- Price
- $249
- Updated
- 2024/03/01
- Product number
- D0871
- Product name
- Diphenylacetylene
- Purity
- >98.0%(GC)
- Packaging
- 25g
- Price
- $157
- Updated
- 2024/03/01
- Product number
- A13979
- Product name
- Diphenylacetylene, 99%
- Packaging
- 5g
- Price
- $32.9
- Updated
- 2024/03/01
- Product number
- A13979
- Product name
- Diphenylacetylene, 99%
- Packaging
- 25g
- Price
- $71.2
- Updated
- 2024/03/01
Diphenylacetylene Chemical Properties,Usage,Production
Chemical Properties
white crystals
Uses
Organic synthesis, purified grade, primary fluor or wavelength shifter in soluble scintillators.
Uses
Diphenylacetylene is often used as a building block in organic and organometallic chemistry. It acts as dienophile and under goes Diels-Alder reaction with tetraphenylcyclopentadienone to prepare hexaphenylbenzene. It acts as a precursor in the preparation of 3-alkoxycyclopropene by reacting with benzal chloride in the presence of potassium t-butoxide.
Definition
ChEBI: An arylacetylene that is acetylene in which the hydrogens are replaced by phenyl groups.
Synthesis Reference(s)
Canadian Journal of Chemistry, 61, p. 86, 1983 DOI: 10.1139/v83-015
Journal of the American Chemical Society, 87, p. 863, 1965 DOI: 10.1021/ja01082a029
The Journal of Organic Chemistry, 51, p. 3830, 1986 DOI: 10.1021/jo00370a016
Purification Methods
Crystallise tolan from EtOH. [Beilstein 5 H 656, 5 IV 2276.]
Diphenylacetylene Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Diphenylacetylene manufacturers
- Product
- Diphenylacetylene 501-65-5
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 95%-99%
- Supply Ability
- 1000kg
- Release date
- 2018-12-24