Diphenylacetylene

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Diphenylacetylene

Product Name: Diphenylacetylene
CAS No.: 501-65-5
Chemical Name: Diphenylacetylene
Synonyms: Tolane;Diphenylethyne;1,2-Diphenylacetylene;TOLAN;Diphenilethyne;ethyne,diphenyl-;DIPHENYLACETYLENE;biphenylacetylene;Ethyne, diphenyl-;1,2-DIPHENYL ETHYNE
CBNumber: CB6198660
Molecular Formula: C14H10
Formula Weight: 178.23
MOL File: 501-65-5.mol

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Diphenylacetylene Property

Melting point:: 59-61 °C (lit.)
Boiling point:: 170 °C/19 mmHg (lit.)
Density: 0.99 g/mL at 25 °C (lit.)
refractive index: 1.6415 (estimate)
Flash point:: 170°C/19mm
storage temp.: Sealed in dry,2-8°C
form: Crystalline Powder and Chunks
color: Light yellow to brownish
Specific Gravity: 0.99
Water Solubility: Miscible with ether and hot alcohol. Immiscible with water.
Merck: 14,9504
BRN: 606478
Stability:: Stable. Combustible. Incompatible with strong oxidizing agents.
InChIKey: JRXXLCKWQFKACW-UHFFFAOYSA-N
CAS DataBase Reference: 501-65-5(CAS DataBase Reference)
NIST Chemistry Reference: Diphenylethyne(501-65-5)
EPA Substance Registry System: Benzene, 1,1'-(1,2-ethynediyl)bis- (501-65-5)

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Safety

Safety Statements: 24/25-22
WGK Germany: 3
TSCA: Yes
HS Code: 29029090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: D204803
Product name: Diphenylacetylene
Purity: 98%
Packaging: 5g
Price: $61.7
Updated: 2024/03/01

Sigma-Aldrich

Product number: D204803
Product name: Diphenylacetylene
Purity: 98%
Packaging: 25g
Price: $249
Updated: 2024/03/01

TCI Chemical

Product number: D0871
Product name: Diphenylacetylene
Purity: >98.0%(GC)
Packaging: 25g
Price: $157
Updated: 2024/03/01

Alfa Aesar

Product number: A13979
Product name: Diphenylacetylene, 99%
Packaging: 5g
Price: $32.9
Updated: 2024/03/01

Alfa Aesar

Product number: A13979
Product name: Diphenylacetylene, 99%
Packaging: 25g
Price: $71.2
Updated: 2024/03/01

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Diphenylacetylene Chemical Properties,Usage,Production

Chemical Properties

white crystals

Uses

Organic synthesis, purified grade, primary fluor or wavelength shifter in soluble scintillators.

Uses

Diphenylacetylene is often used as a building block in organic and organometallic chemistry. It acts as dienophile and under goes Diels-Alder reaction with tetraphenylcyclopentadienone to prepare hexaphenylbenzene. It acts as a precursor in the preparation of 3-alkoxycyclopropene by reacting with benzal chloride in the presence of potassium t-butoxide.

Definition

ChEBI: An arylacetylene that is acetylene in which the hydrogens are replaced by phenyl groups.

Synthesis Reference(s)

Canadian Journal of Chemistry, 61, p. 86, 1983 DOI: 10.1139/v83-015
Journal of the American Chemical Society, 87, p. 863, 1965 DOI: 10.1021/ja01082a029
The Journal of Organic Chemistry, 51, p. 3830, 1986 DOI: 10.1021/jo00370a016

Purification Methods

Crystallise tolan from EtOH. [Beilstein 5 H 656, 5 IV 2276.]

Diphenylacetylene Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Diphenylacetylene manufacturers

Career Henan Chemical Co

Product: Diphenylacetylene 501-65-5
Price: US $1.00/KG
Min. Order: 1KG
Purity: 95%-99%
Supply Ability: 1000kg
Release date: 2018-12-24

501-65-5, DiphenylacetyleneRelated Search:

o-Phenylenediamine p-Phenylenediamine tert-Butylchlorodiphenylsilane ETHYNYLFERROCENE Benzophenone 1,3-Diphenyl-2-thiourea Diphenyl ether Diphenylmethane polyphenylacetylene Dichlorodiphenylsilane Diphenylsilane Chlorodiphenylphosphine Diphenylphosphine Bis(2-ethylhexyl) phthalate Diphenyldimethoxysilane Phthalic acid Phenylacetylene Isophthalic acid

DIPHENYLACETYLENE

1,2-DIPHENYL ETHYNE

1,2-Ethynediylbisbenzene

Diphenylacetylene ,98.5%

Diphenylacetylene 1g [501-65-5]

DIPHENYLACETYLENE 98%

TOLAN

(Phenylethynyl)benzene

1,1'-(1,2-Ethanediyl)bisbenzene

1,1’-(1,2-ethynediyl)bis-benzen

Diphenylacetylene,99%

Diphenilethyne

Diphenylacetylene, 99% 25GR

Diphenylacetylene, 99% 5GR

DIPHENYLACETYLENE, 98%DIPHENYLACETYLENE, 98%DIPHENYLACETYLENE, 98%DIPHENYLACETYLENE, 98%

1,1’-(1,2-Ethynediyl)bisbenzene

1,2-Diphenylacetylene

Acetylene, diphenyl-

acetylene,diphenyl-

Benzene, 1,1'-(1,2-ethynediyl)bis-

biphenylacetylene

Diphenylethyne

Ethyne, diphenyl-

ethyne,diphenyl-

Tolane

SYM-DIPHENYLACETYLENE

DIPHENYLACETYLENE, FOR SCINTILLATION

Diphenylacetylene&gt

Diphenylacetylene, 99%, for synthesis

(2-phenylethynyl)benzene

TIANFU-CHEM - Diphenylacetylene

501-65-5

C6H5C

C6H5CCC6H5

C6H5C8801CC6H5

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Acetylenes

Acetylenic Hydrocarbons having Benzene Ring

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Acetylenes

Acetylenic Hydrocarbons having Benzene Ring