ChemicalBook > CAS DataBase List > Methyl 2-(4-bromo-2-nitrophenyl)acetate

Methyl 2-(4-bromo-2-nitrophenyl)acetate

Product Name
Methyl 2-(4-bromo-2-nitrophenyl)acetate
CAS No.
100487-82-9
Chemical Name
Methyl 2-(4-bromo-2-nitrophenyl)acetate
Synonyms
Methyl 4-Bromo-2-nitrophenylacetae;Methyl4-bromo-2-nitrophenylacetate98%;4-Bromo-2-nitrobenzeneacetic acid methyl ester;(4-BroMo-2-nitro-phenyl)-acetic acid Methyl ester;Benzeneacetic acid, 4-broMo-2-nitro-, Methyl ester;4-Bromo-2-nitrophenylacetic acid methyl ester, 5-Bromo-2-(2-methoxy-2-oxoethyl)nitrobenzene
CBNumber
CB51457611
Molecular Formula
C9H8BrNO4
Formula Weight
274.07
MOL File
100487-82-9.mol
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Methyl 2-(4-bromo-2-nitrophenyl)acetate Property

Boiling point:
331.7±27.0 °C(Predicted)
Density 
1.609±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
Appearance
Off-white to yellow Solid
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Safety

HS Code 
2916391000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P309+P311IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician.

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N-Bromosuccinimide Price

TRC
Product number
M296385
Product name
Methyl2-(4-bromo-2-nitrophenyl)acetate
Packaging
100mg
Price
$45
Updated
2021/12/16
Apolloscientific
Product number
OR7152
Product name
Methyl 4-bromo-2-nitrophenylacetate
Purity
97%
Packaging
1g
Price
$156
Updated
2021/12/16
SynQuest Laboratories
Product number
4754-9-08
Product name
Methyl 4-bromo-2-nitrophenylacetate
Purity
98%
Packaging
1g
Price
$184
Updated
2021/12/16
AK Scientific
Product number
Z6282
Product name
Methyl2-(4-bromo-2-nitrophenyl)acetate
Packaging
10g
Price
$419
Updated
2021/12/16
Apolloscientific
Product number
OR7152
Product name
Methyl 4-bromo-2-nitrophenylacetate
Purity
97%
Packaging
5g
Price
$486
Updated
2021/12/16
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Methyl 2-(4-bromo-2-nitrophenyl)acetate Chemical Properties,Usage,Production

Synthesis

100487-81-8

100487-82-9

GENERAL STEPS: To a stirred solution of 1,3-dimethyl 2-(4-bromo-2-nitrophenyl) malonate (20 g, 60.2 mmol) in dimethyl sulfoxide (DMSO, 200 mL) was added lithium chloride (5.11 g, 2 eq.) followed by water (1.1 mL, 1 eq.). The reaction mixture was stirred at 100°C for 2 days and then continued at room temperature for 4 days. Upon completion of the reaction, the mixture was poured into water and extracted with ethyl acetate (2 x 200 mL). The organic phases were combined, washed with saturated brine (2 x 200 mL) and dried over anhydrous sodium sulfate. After concentration under reduced pressure, the residue was purified by Combi-Flash column chromatography (eluent: ethyl acetate/hexane) to afford methyl 2-(4-bromo-2-nitrophenyl)acetate (12 g, 73% yield) as a light yellow solid.1H NMR (400 MHz, DMSO-d6) δ 8.30 (d, J = 2.1 Hz, 1H), 7.98 (dd, J = 8.2, 2.1 Hz, 1H), 7.56 (d, J = 8.2 Hz, 1H), 4.08 (s, 2H), 3.63 (s, 3H).LCMS-ESI (POS), m/z, [M + H]+: measured values 274.0 and 276.0.

References

[1] Synthesis, 1993, # 1, p. 51 - 53
[2] Journal of the American Chemical Society, 2013, vol. 135, # 2, p. 620 - 623
[3] Patent: WO2009/158011, 2009, A1. Location in patent: Page/Page column 59-60
[4] Patent: WO2009/85040, 2009, A1. Location in patent: Page/Page column 25-26
[5] Patent: US6350747, 2002, B1. Location in patent: Page column 48

Methyl 2-(4-bromo-2-nitrophenyl)acetate Preparation Products And Raw materials

Raw materials

Preparation Products

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100487-82-9, Methyl 2-(4-bromo-2-nitrophenyl)acetateRelated Search:

(4-BROMO-2-NITRO-PHENYL)-ACETIC ACID Methyl 2-(4-bromo-2-nitrophenyl)acetate

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