N-(TRIMETHYLSILYL)BIS(TRIFLUOROMETHANESULFONYL)IMIDE

Product Name: N-(TRIMETHYLSILYL)BIS(TRIFLUOROMETHANESULFONYL)IMIDE
CAS No.: 82113-66-4
Chemical Name: N-(TRIMETHYLSILYL)BIS(TRIFLUOROMETHANESULFONYL)IMIDE
Synonyms: TMS Triflimide;[Bis(trifluoromethanesulfonyl)amino]trimethylsilane;N-(TRIMETHYLSILYL)BIS(TRIFLUOROMETHANESULFONYL)IMIDE;N-(Trimethylsilyl)bis(trifluoromethanesulfonyl)amine;N-(Trimethylsilyl)bis(trifluoromethanesulfonyl)imide;[Bis(trifluoromethanesulfonyl)amino]trimethylsilane TMS Triflimide;1,1,1-trifluoro-N-(trifluoroMethylsulfonyl)-N-(triMethylsilyl)MethanesulfonaMide;Methanesulfonamide,1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]-N-(trimethylsilyl)-
CBNumber: CB51479303
Molecular Formula: C5H9F6NO4S2Si
Formula Weight: 353.34
MOL File: 82113-66-4.mol

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N-(TRIMETHYLSILYL)BIS(TRIFLUOROMETHANESULFONYL)IMIDE Property

Boiling point:: 115 °C / 2mmHg
Density: 1.543±0.06 g/cm3(Predicted)
storage temp.: Freezer
solubility: soluble in most common organic solvents, commonly used in dichloromethane, toluene, diethyl ether.
form: clear liquid
pka: -26.49±0.70(Predicted)
color: Colorless to Red to Green

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Safety

HS Code: 2931.90.9010

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

TCI Chemical

Product number: T2392
Product name: N-(Trimethylsilyl)bis(trifluoromethanesulfonyl)imide
Purity: >97.0%(T)
Packaging: 1g
Price: $97
Updated: 2024/03/01

TCI Chemical

Product number: T2392
Product name: N-(Trimethylsilyl)bis(trifluoromethanesulfonyl)imide
Purity: >97.0%(T)
Packaging: 5g
Price: $297
Updated: 2024/03/01

AK Scientific

Product number: 8368AL
Product name: N-(Trimethylsilyl)bis(trifluoromethanesulfonyl)imide
Packaging: 1g
Price: $183
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: ORS0001405
Product name: N-(TRIMETHYLSILYL)BIS(TRIFLUOROMETHANESULFONYL)IMIDE
Purity: 95.00%
Packaging: 1G
Price: $185.85
Updated: 2021/12/16

Ambeed

Product number: A752811
Product name: N-(TRimethylsilyl)bis(trifluoromethanesulfonyl)imide
Purity: 95%
Packaging: 250mg
Price: $37
Updated: 2021/12/16

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N-(TRIMETHYLSILYL)BIS(TRIFLUOROMETHANESULFONYL)IMIDE Chemical Properties,Usage,Production

Physical properties

colorless liquid, bp: 115°C(2 Torr).

Uses

Methanesulfonamide, 1,1,1-Trifluoro- N[(trifluoromethyl)sulfonyl]- N(trimethylsilyl)-? can be used as Lewis acid catalyst for a variety of organic transformations.

Preparation

It is easily prepared in situ through protodesilation by mixing commercially available allyltrimethylsilane (or any TMS enol ether) and Tf2NH. Originally prepared by mixing Tf2NH with trimethylsilane at low temperature or mixing AgNTf2 with TMSCl.

N-(TRIMETHYLSILYL)BIS(TRIFLUOROMETHANESULFONYL)IMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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N-(TRIMETHYLSILYL)BIS(TRIFLUOROMETHANESULFONYL)IMIDE Suppliers

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82113-66-4, N-(TRIMETHYLSILYL)BIS(TRIFLUOROMETHANESULFONYL)IMIDERelated Search:

Triethylamine trihydrofluoride Diethyl azodicarboxylate Chlorosulfonyl isocyanate TRIMETHYLSILANE N-(TRIMETHYLSILYL)BIS(TRIFLUOROMETHANESULFONYL)IMIDE

N-(TRIMETHYLSILYL)BIS(TRIFLUOROMETHANESULFONYL)IMIDE

[Bis(trifluoromethanesulfonyl)amino]trimethylsilane

TMS Triflimide

[Bis(trifluoromethanesulfonyl)amino]trimethylsilane TMS Triflimide

1,1,1-trifluoro-N-(trifluoroMethylsulfonyl)-N-(triMethylsilyl)MethanesulfonaMide

Methanesulfonamide,1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]-N-(trimethylsilyl)-

<i>N</i>-(Trimethylsilyl)bis(trifluoromethanesulfonyl)imide

N-(Trimethylsilyl)bis(trifluoromethanesulfonyl)amine

82113-66-4

C5H9F6NO4S2Si

Si (Classes of Silicon Compounds)

Si-N Compounds

Trimethylsilylazide, etc.