FMOC-L-VALINOL

Product Name: FMOC-L-VALINOL
CAS No.: 160885-98-3
Chemical Name: FMOC-L-VALINOL
Synonyms: FMOC-VAL-OL;FMOC-VALINOL;Fmoc-L-Val-ol;FMOC-L-VALINOL;CAS:160885-98-3;N-FMOC-L-VALINOL;N-Fmoc-L-valinol,98%;N-ALPHA-FMOC-L-VALINOL;REF DUPL: Fmoc-L-Val-OH;FMOC-L-VALINOL USP/EP/BP
CBNumber: CB5157477
Molecular Formula: C20H23NO3
Formula Weight: 325.4
MOL File: 160885-98-3.mol

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FMOC-L-VALINOL Property

Melting point:: 129-133 °C(lit.)
Boiling point:: 515.7±33.0 °C(Predicted)
Density: 1.166±0.06 g/cm3(Predicted)
storage temp.: Sealed in dry,Store in freezer, under -20°C
solubility: Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
form: Solid
pka: 11.40±0.46(Predicted)
Appearance: White to off-white Solid
optical activity: Consistent with structure
CAS DataBase Reference: 160885-98-3(CAS DataBase Reference)

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Safety

Safety Statements: 22-24/25
WGK Germany: 3

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

TRC

Product number: F679788
Product name: Fmoc-L-valinol
Packaging: 250mg
Price: $55
Updated: 2021/12/16

Usbiological

Product number: 276999
Product name: Fmoc-L-valinol
Packaging: 2g
Price: $375
Updated: 2021/12/16

Chem-Impex

Product number: 03239
Product name: Fmoc-L-valinol,98%(HPLC)
Purity: 98%(HPLC)
Packaging: 25G
Price: $614.88
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: AAA0002596
Product name: FMOC-L-VALINOL
Purity: 95.00%
Packaging: 1G
Price: $655
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: AAA0002596
Product name: FMOC-L-VALINOL
Purity: 95.00%
Packaging: 5G
Price: $1005.26
Updated: 2021/12/16

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FMOC-L-VALINOL Chemical Properties,Usage,Production

Chemical Properties

White powder

Synthesis

68858-20-8

160885-98-3

GENERAL METHOD: To a tetrahydrofuran (THF, 10 mL) solution of Fmoc-L-valine (10 mmol) was added N,N-diisopropylethylamine (DIPEA, 11 mmol, 1.42 mL) and 50% propylphosphonic anhydride (T3P) in ethyl acetate (EtOAc) solution (20 mmol, 6.36 mL) at 0 °C, and the reaction was stirred mixture for about 10 minutes. Subsequently, an aqueous solution (0.3 mL) of sodium borohydride (NaBH4, 10 mmol, 388 mg) was slowly added to the reaction mixture at the same temperature and stirring was continued until the reaction was shown to be complete by thin layer chromatography (TLC). After completion of the reaction, the solvent was removed under reduced pressure by rotary evaporator and the crude product was extracted with ethyl acetate (EtOAc). The organic phase was washed sequentially with 5% aqueous citric acid (10 mL × 2), 5% aqueous sodium carbonate (Na2CO3) (10 mL × 2), water and saturated saline. Finally, the organic phase was dried with anhydrous sodium sulfate (Na2SO4) and concentrated under reduced pressure to afford the target product (S)-(9H-fluoren-9-yl)methyl (1-hydroxy-3-methylbutan-2-yl)carbamate.

References

[1] Journal of Organic Chemistry, 2001, vol. 66, # 25, p. 8454 - 8462
[2] Tetrahedron Letters, 1999, vol. 40, # 23, p. 4395 - 4396
[3] Tetrahedron Letters, 2012, vol. 53, # 38, p. 5059 - 5063
[4] RSC Advances, 2014, vol. 4, # 87, p. 46947 - 46950
[5] Organic and Biomolecular Chemistry, 2011, vol. 9, # 11, p. 4182 - 4187

FMOC-L-VALINOL Preparation Products And Raw materials

Raw materials

Preparation Products

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FMOC-L-VALINOL Suppliers

China 74 Germany 2 India 3 Japan 2 Switzerland 3 United Kingdom 2 United States 16 Global 102

J & K SCIENTIFIC LTD.

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Shanghai Hanhong Scientific Co.,Ltd.

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Shandong Xiya Chemical Co., Ltd

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Sichuan Kulinan Technology Co., Ltd

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ChemPep, Inc.

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9ding chemical ( Shanghai) Limited

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ApexBio Technology LLC

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Bide Pharmatech Ltd.

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Wuxi Zhongkun Biochemical Technology Co., Ltd.

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View Lastest Price from FMOC-L-VALINOL manufacturers

Sichuan HongRi Pharma-Tech Co.,Ltd

Product: Fmoc-L-Valinol 160885-98-3
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 1T+
Release date: 2024-01-14

160885-98-3, FMOC-L-VALINOLRelated Search:

Fmoc-N-Me-Val-OH Fmoc-N-methyl-L-isoleucine FMOC-CHG-OH FMOC-L-Valine FMOC-[15N]VAL-OH Fmoc-L-tert-leucine Fmoc-Ile-OH FMOC-L-VALINOL (S)-(+)-2-Amino-3-methyl-1-butanol 3-Methyl-1-butanol FMOC-VAL-OPFP FMOC-ILE-OH-15N FMOC-ILE-OL FMOC-PEN(ACM)-OH FMOC-ILE-OPFP FMOC-L-VALINE N-CARBOXY ANHYDRIDE FMOC-VAL-OSU FMOC-ILE-N-CARBOXYANHYDRIDE

NALPHA-9-Fluorenylmethoxycarbonyl-(S)-2-amino-3-methyl-1-butanol

(S)-2-(9-Fluorenylmethyloxycarbonyl)amino-3-methyl-1-butanol, N-alpha-(9-Fluorenylmethyloxycarbonyl)-L-valinol

(S)-2-(Fmoc-amino)-3-methyl-1-butanol, N-(9-Fluorenylmethoxycarbonyl)-L-valinol

FMOC-L-VALINOL

FMOC-(S)-2-AMINO-3-METHYL-1-BUTANOL

FMOC-VALINOL

FMOC-VAL-OL

N-ALPHA-FMOC-L-VALINOL

N-(9-FLUORENYLMETHOXYCARBONYL)-L-VALINOL

N-FMOC-(S)-2-AMINO-3-METHYL-1-BUTANOL

N-FMOC-L-VALINOL

(S)-2-(FMOC-AMINO)-3-METHYL-1-BUTANOL

(S)-(9H-fluoren-9-yl)methyl 1-hydroxy-3-methylbutan-2-ylcarbamate

REF DUPL: Fmoc-L-Val-OH

CarbaMic acid,N-[(1S)-1-(hydroxyMethyl)-2-Methylpropyl]-, 9H-fluoren-9-ylMethyl ester

Fmoc-L-valinol≥ 98% (HPLC)

Fmoc-L-Val-ol

N-(1-hydroxy-3-methylbutan-2-yl)carbamic acid 9H-fluoren-9-ylmethyl ester

N-Fmoc-L-valinol,98%

FMOC-L-VALINOL USP/EP/BP

CAS:160885-98-3

160885-98-3

C20H23NO3

FM - FZ

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