ChemicalBook > CAS DataBase List > 2,6-DIMETHOXYANILINE

2,6-DIMETHOXYANILINE

Product Name
2,6-DIMETHOXYANILINE
CAS No.
2734-70-5
Chemical Name
2,6-DIMETHOXYANILINE
Synonyms
2,6-dimethoxybenzenamine;NSC 43758;BUTTPARK 33\04-69;2,6-DIMETHOXYANILINE;2,6-Dimethoxyaniline 98%;2,6-Dimethoxyaniline >2,6-Dimethoxyaniline, 97%;2,6-Dimethoxy-phenylamine;2,6-Dimethoxyaniline ,98%;BenzenaMine, 2,6-diMethoxy-
CBNumber
CB5164510
Molecular Formula
C8H11NO2
Formula Weight
153.18
MOL File
2734-70-5.mol
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2,6-DIMETHOXYANILINE Property

Melting point:
71-74
Boiling point:
254℃
Density 
1.096
refractive index 
1.4770 (estimate)
Flash point:
116℃
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
form 
powder to crystal
pka
4.48±0.10(Predicted)
color 
White to Gray to Brown
Water Solubility 
Slightly soluble in water.
InChI
InChI=1S/C8H11NO2/c1-10-6-4-3-5-7(11-2)8(6)9/h3-5H,9H2,1-2H3
InChIKey
HQBJSEKQNRSDAZ-UHFFFAOYSA-N
SMILES
C1(N)=C(OC)C=CC=C1OC
CAS DataBase Reference
2734-70-5(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi,T
Risk Statements 
20/21/22-36/37/38-36-33
Safety Statements 
26-36/37/39-36/37-28
RIDADR 
UN2811
Hazard Note 
Toxic/Irritant
TSCA 
N
HazardClass 
6.1
PackingGroup 
III
HS Code 
29214200
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H311Toxic in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H373May cause damage to organs through prolonged or repeated exposure

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P309IF exposed or if you feel unwell:

P310Immediately call a POISON CENTER or doctor/physician.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical
Product number
D4480
Product name
2,6-Dimethoxyaniline
Purity
>98.0%(GC)
Packaging
1g
Price
$52
Updated
2025/07/31
TCI Chemical
Product number
D4480
Product name
2,6-Dimethoxyaniline
Purity
>98.0%(GC)
Packaging
5g
Price
$203
Updated
2025/07/31
TRC
Product number
D451870
Product name
2,6-Dimethoxyaniline
Packaging
100mg
Price
$45
Updated
2021/12/16
TRC
Product number
D451870
Product name
2,6-Dimethoxyaniline
Packaging
500mg
Price
$65
Updated
2021/12/16
Oakwood
Product number
017336
Product name
2,6-Dimethoxyaniline
Packaging
1g
Price
$14
Updated
2021/12/16
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2,6-DIMETHOXYANILINE Chemical Properties,Usage,Production

Chemical Properties

Off-white solid

Uses

2,6-Dimethylaniline degradation by Fenton process has been studied in depth for the purpose of learning more about the reactions involved in the oxidation of 2,6-dimethylaniline under various reaction conditions. Using a previously developed gas chromatographic-mass spectrometric assay, hemoglobin adducts of 2,6-dimethylaniline were detected covalently bound to rat hemoglobin after administration of either 2,6-dimethylaniline or lidocaine.

Synthesis

51410-99-2

2734-70-5

N-hydroxy-2,6-dimethoxybenzamide (1a) (0.237 g, 1.2 mmol) was used as a raw material and it was mixed with K2CO3 (0.166 g, 1.2 mmol) and DMSO (0.5 mL). Acetic anhydride (1.1 mL, 0.012 mmol) was added to the mixture and the reaction system was heated to 50°C. After stirring the reaction at this temperature for 10 min, the reaction mixture was cooled to 0°C and subsequently treated with 2M HCl (~2 mL). After the mixture was transformed into a clarified solution, it was neutralized by the addition of 2M NaOH (ca. 2 mL) and subsequently extracted with ether (Et2O, 15 mL x 3). The organic layers were combined, dried with anhydrous Na2SO4, filtered and concentrated under reduced pressure. The residue was purified by silica gel column chromatography (eluent: hexane/ether, 1:1) to afford the target product 2,6-dimethoxyaniline (2a) (0.171 g, 93% yield) as a white crystalline solid.

References

[1] Chemical Communications, 2009, # 17, p. 2281 - 2283
[2] Organic and Biomolecular Chemistry, 2016, vol. 14, # 38, p. 9046 - 9054
[3] Tetrahedron Letters, 2015, vol. 56, # 5, p. 710 - 712

2,6-DIMETHOXYANILINE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 2,6-DIMETHOXYANILINE manufacturers

Hebei Chuanghai Biotechnology Co., Ltd
Product
2,6-DIMETHOXYANILINE 2734-70-5
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-11-12
Career Henan Chemical Co
Product
2,6-DIMETHOXYANILINE 2734-70-5
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100kg
Release date
2019-07-11

2734-70-5, 2,6-DIMETHOXYANILINERelated Search:

EPIROPRIM 2,6-DIMETHOXYPHENYL ISOCYANATE 2,6-Dimethoxynitrobenzene 98% 1,3,5-TRIMETHOXY-2-NITROBENZENE 2,6-DIMETHOXYANILINE N N-BIS-(2-HYDROXYETHYL)-3,5-DIMETHOXYANILINE 2,4-DIMETHOXYANILINE 5-Chloro-2,4-dimethoxyaniline 2,5-Dimethoxyaniline 4'-Chloro-2',5'-dimethoxyacetoacetanilide 4-Aminoveratrole 3,4-Dimethoxyaniline hydrochloride o-Dianisidine N-Methyl-N-(3-chloropropyl)-3,4-dimethoxyphenethylamine CI 37235 4-(2-PYRIDYLAZO)-N,N-DIMETHYLANILINE 3-Fluoro-2,4-dimethoxyaniline 2-(4-AMINO-2,5-DIMETHOXY-PHENYL-SULFONYL)ETHANOL SULFATE ESTER

  • 2,6-DIMETHOXYANILINE
  • BUTTPARK 33\04-69
  • 2,6-Dimethoxyaniline 98%
  • 2,6-Dimethoxyaniline ,98%
  • 2,6-Dimethoxy-phenylamine
  • 2,6-dimethoxybenzenamine
  • NSC 43758
  • BenzenaMine, 2,6-diMethoxy-
  • 2,6-Dimethoxyaniline &gt
  • 2,6-DIMETHOXYANILINE ISO 9001：2015 REACH
  • 2,6-Dimethoxyaniline, 97%
  • 2734-70-5
  • Anilines, Aromatic Amines and Nitro Compounds