2,6-DIMETHOXYANILINE
- Product Name
- 2,6-DIMETHOXYANILINE
- CAS No.
- 2734-70-5
- Chemical Name
- 2,6-DIMETHOXYANILINE
- Synonyms
- 2,6-dimethoxybenzenamine;NSC 43758;BUTTPARK 33\04-69;2,6-DIMETHOXYANILINE;2,6-Dimethoxyaniline 98%;2,6-Dimethoxyaniline >2,6-Dimethoxyaniline, 97%;2,6-Dimethoxy-phenylamine;2,6-Dimethoxyaniline ,98%;BenzenaMine, 2,6-diMethoxy-
- CBNumber
- CB5164510
- Molecular Formula
- C8H11NO2
- Formula Weight
- 153.18
- MOL File
- 2734-70-5.mol
2,6-DIMETHOXYANILINE Property
- Melting point:
- 71-74
- Boiling point:
- 254℃
- Density
- 1.096
- refractive index
- 1.4770 (estimate)
- Flash point:
- 116℃
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- form
- powder to crystal
- pka
- 4.48±0.10(Predicted)
- color
- White to Gray to Brown
- Water Solubility
- Slightly soluble in water.
- InChI
- InChI=1S/C8H11NO2/c1-10-6-4-3-5-7(11-2)8(6)9/h3-5H,9H2,1-2H3
- InChIKey
- HQBJSEKQNRSDAZ-UHFFFAOYSA-N
- SMILES
- C1(N)=C(OC)C=CC=C1OC
- CAS DataBase Reference
- 2734-70-5(CAS DataBase Reference)
Safety
- Hazard Codes
- Xi,T
- Risk Statements
- 20/21/22-36/37/38-36-33
- Safety Statements
- 26-36/37/39-36/37-28
- RIDADR
- UN2811
- Hazard Note
- Toxic/Irritant
- TSCA
- N
- HazardClass
- 6.1
- PackingGroup
- III
- HS Code
- 29214200
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H311Toxic in contact with skin
H315Causes skin irritation
H319Causes serious eye irritation
H332Harmful if inhaled
H373May cause damage to organs through prolonged or repeated exposure
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P309IF exposed or if you feel unwell:
P310Immediately call a POISON CENTER or doctor/physician.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- D4480
- Product name
- 2,6-Dimethoxyaniline
- Purity
- >98.0%(GC)
- Packaging
- 1g
- Price
- $52
- Updated
- 2025/07/31
- Product number
- D4480
- Product name
- 2,6-Dimethoxyaniline
- Purity
- >98.0%(GC)
- Packaging
- 5g
- Price
- $203
- Updated
- 2025/07/31
- Product number
- D451870
- Product name
- 2,6-Dimethoxyaniline
- Packaging
- 100mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- D451870
- Product name
- 2,6-Dimethoxyaniline
- Packaging
- 500mg
- Price
- $65
- Updated
- 2021/12/16
- Product number
- 4656-1-W0
- Product name
- 2,6-Dimethoxyaniline
- Purity
- 97%
- Packaging
- 5G
- Price
- $69
- Updated
- 2021/12/16
2,6-DIMETHOXYANILINE Chemical Properties,Usage,Production
Chemical Properties
Off-white solid
Uses
2,6-Dimethylaniline degradation by Fenton process has been studied in depth for the purpose of learning more about the reactions involved in the oxidation of 2,6-dimethylaniline under various reaction conditions. Using a previously developed gas chromatographic-mass spectrometric assay, hemoglobin adducts of 2,6-dimethylaniline were detected covalently bound to rat hemoglobin after administration of either 2,6-dimethylaniline or lidocaine.
Synthesis
51410-99-2
2734-70-5
N-hydroxy-2,6-dimethoxybenzamide (1a) (0.237 g, 1.2 mmol) was used as a raw material and it was mixed with K2CO3 (0.166 g, 1.2 mmol) and DMSO (0.5 mL). Acetic anhydride (1.1 mL, 0.012 mmol) was added to the mixture and the reaction system was heated to 50°C. After stirring the reaction at this temperature for 10 min, the reaction mixture was cooled to 0°C and subsequently treated with 2M HCl (~2 mL). After the mixture was transformed into a clarified solution, it was neutralized by the addition of 2M NaOH (ca. 2 mL) and subsequently extracted with ether (Et2O, 15 mL x 3). The organic layers were combined, dried with anhydrous Na2SO4, filtered and concentrated under reduced pressure. The residue was purified by silica gel column chromatography (eluent: hexane/ether, 1:1) to afford the target product 2,6-dimethoxyaniline (2a) (0.171 g, 93% yield) as a white crystalline solid.
References
[1] Chemical Communications, 2009, # 17, p. 2281 - 2283
[2] Organic and Biomolecular Chemistry, 2016, vol. 14, # 38, p. 9046 - 9054
[3] Tetrahedron Letters, 2015, vol. 56, # 5, p. 710 - 712
2,6-DIMETHOXYANILINE Preparation Products And Raw materials
Raw materials
Preparation Products
2,6-DIMETHOXYANILINE Suppliers
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View Lastest Price from 2,6-DIMETHOXYANILINE manufacturers
- Product
- 2,6-DIMETHOXYANILINE 2734-70-5
- Price
- US $10.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10 mt
- Release date
- 2024-11-12
- Product
- 2,6-DIMETHOXYANILINE 2734-70-5
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100kg
- Release date
- 2019-07-11