(+)-(4S)-PHENYL-ALPHA-[(4S)-PHENYLOXAZOLIDIN-2-YLIDENE]-2-OXAZOLINE-2-ACETONITRILE

Product Name: (+)-(4S)-PHENYL-ALPHA-[(4S)-PHENYLOXAZOLIDIN-2-YLIDENE]-2-OXAZOLINE-2-ACETONITRILE
CAS No.: 150639-33-1
Chemical Name: (+)-(4S)-PHENYL-ALPHA-[(4S)-PHENYLOXAZOLIDIN-2-YLIDENE]-2-OXAZOLINE-2-ACETONITRILE
Synonyms: (4S)-(+)-Phenyl-α2-((S)-4-Phenyl-4,5-dihydrooxazol-2-yl)-2-((S)-4-phenylox;(S,S)-4-phe-A-(4-phe.oxazolidin-ylidene) -oxazoline-acetonit.;-[(4S)-phenyloxazolidin-2-ylidene]-2-oxazoline-2-acetonitrile;(s,s)-4-phenyl-α-(4-phenyloxazolidin-2-ylidene)-2-oxazoline-2-acetonitrile;(s,s)-4-phenyl-α-(4-phenyloxazolidin-2-ylidene)-2-oxazoline-2-acetonitrile;(S,S)-4-PHENYL-ALPHA-(4-PHENYLOXAZOLIDIN-2-YLIDENE)-2-OXAZOLINE-2-ACETONITRILE;(4s)-(+)-phenyl-α-[(4s)-phenyloxazolidin-2-ylidene]-2-oxazoline-2-acetonitrile;(4S)-(+)-Phenyl-α-[(4S)-phenyloxazolidin-2-ylidene]-2-oxazoline-2-acetonitrile;(S,S)-(+)-4-PHENYL-ALPHA-(4-PHENYLOXAZOL IDIN-2 -YLIDENE)-2-OXAZOLINE-2-ACETONITR
CBNumber: CB5174902
Molecular Formula: C20H17N3O2
Formula Weight: 331.37
MOL File: 150639-33-1.mol

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(+)-(4S)-PHENYL-ALPHA-[(4S)-PHENYLOXAZOLIDIN-2-YLIDENE]-2-OXAZOLINE-2-ACETONITRILE Property

Melting point:: 146-148 °C(lit.)
Boiling point:: 457.5±45.0 °C(Predicted)
Density: 1.27±0.1 g/cm3(Predicted)
storage temp.: 2-8°C
pka: 3.30±0.70(Predicted)
optical activity: [α]20/D +364°, c = 1 in chloroform

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36
WGK Germany: 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 417068
Product name: (4S)-(+)-Phenyl-α-[(4S)-phenyloxazolidin-2-ylidene]-2-oxazoline-2-acetonitrile
Purity: 97%
Packaging: 1g
Price: $299.4
Updated: 2024/03/01

American Custom Chemicals Corporation

Product number: CCH0004926
Product name: (4S)-(+)-PHENYL-ALPHA-[(4S)-PHENYLOXAZOLIDIN-2-YLIDENE]-2-OXAZOLINE-2-ACETONITRILE
Purity: 97.00%
Packaging: 1G
Price: $833.76
Updated: 2021/12/16

Arctom

Product number: AS713045
Product name: 2-((S)-4-Phenyl-4,5-dihydrooxazol-2-yl)-2-((S)-4-phenyloxazolidin-2-ylidene)acetonitrile
Purity: 98%
Packaging: 100mg
Price: $57
Updated: 2021/12/16

Ambeed

Product number: A1355479
Product name: 2-((S)-4-Phenyl-4,5-dihydrooxazol-2-yl)-2-((S)-4-phenyloxazolidin-2-ylidene)acetonitrile
Purity: 98%
Packaging: 100mg
Price: $65
Updated: 2021/12/16

Arctom

Product number: AS713045
Product name: 2-((S)-4-Phenyl-4,5-dihydrooxazol-2-yl)-2-((S)-4-phenyloxazolidin-2-ylidene)acetonitrile
Purity: 98%
Packaging: 250mg
Price: $117
Updated: 2021/12/16

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(+)-(4S)-PHENYL-ALPHA-[(4S)-PHENYLOXAZOLIDIN-2-YLIDENE]-2-OXAZOLINE-2-ACETONITRILE Chemical Properties,Usage,Production

Uses

Ligand for enantioselective catalysis. Easily forms bidentate coordination complexes due to the strong affinity of the oxazoline nitrogen for various metals.

General Description

(4S)-(+)-Phenyl-α-[(4S)-phenyloxazolidin-2-ylidene]-2-oxazoline-2-acetonitrile is a C₂-symmetric chiral bisoxazoline (BOX) ligand.

(+)-(4S)-PHENYL-ALPHA-[(4S)-PHENYLOXAZOLIDIN-2-YLIDENE]-2-OXAZOLINE-2-ACETONITRILE Preparation Products And Raw materials

Raw materials

Preparation Products

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(+)-(4S)-PHENYL-ALPHA-[(4S)-PHENYLOXAZOLIDIN-2-YLIDENE]-2-OXAZOLINE-2-ACETONITRILE Suppliers

China 21 South Korea 1 Switzerland 1 United States 3 Global 26

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150639-33-1, (+)-(4S)-PHENYL-ALPHA-[(4S)-PHENYLOXAZOLIDIN-2-YLIDENE]-2-OXAZOLINE-2-ACETONITRILERelated Search:

Oxazoline (S)-(+)-1-AMINO-1-PHENYL-2-METHOXYETHANE MYCOLIDE 2-ISOPROPENYL-2-OXAZOLINE 99+% 2-Ethyl-2-oxazoline (+)-(4S)-PHENYL-ALPHA-[(4S)-PHENYLOXAZOLIDIN-2-YLIDENE]-2-OXAZOLINE-2-ACETONITRILE 3-ETHOXYACRYLONITRILE

(s,s)-4-phenyl-α-(4-phenyloxazolidin-2-ylidene)-2-oxazoline-2-acetonitrile

(4S)-(+)-Phenyl-alpha-[(4S)-phenyloxazolidin-2-ylidene]-2-oxazoline-2-acetonitrile 97%

(+)-(4S)-PHENYL-ALPHA-[(4S)-PHENYLOXAZOLIDIN-2-YLIDENE]-2-OXAZOLINE-2-ACETONITRILE

(S,S)-4-PHENYL-ALPHA-(4-PHENYLOXAZOLIDIN-2-YLIDENE)-2-OXAZOLINE-2-ACETONITRILE

(S,S)-4-phe-A-(4-phe.oxazolidin-ylidene) -oxazoline-acetonit.

(S,S)-(+)-4-PHENYL-ALPHA-(4-PHENYLOXAZOL IDIN-2 -YLIDENE)-2-OXAZOLINE-2-ACETONITR

(4s)-(+)-phenyl-α-[(4s)-phenyloxazolidin-2-ylidene]-2-oxazoline-2-acetonitrile

(2Z)-2-[(4S)-4-phenyl-4,5-dihydro-1,3-oxazol-2-yl]-2-[(4S)-4-phenyl-1,3-oxazolidin-2-ylidene]acetonitrile

2-Oxazoleacetonitrile, 4,5-dihydro-4-phenyl-α-[(4S)-4-phenyl-2-oxazolidinylidene]-, (4S)-

2-((S)-4-Phenyl-4,5-dihydrooxazol-2-yl)-2-((S)-4-phenyloxazolidin-2-ylidene)acetonitrile

(+)-(4S)-PHENYL-ALPHA-[(4S)-PHENYLOXAZOLIDIN-2-YLIDENE]-2-OXAZOLINE-2-ACETONITRILE

(4S)-(+)-Phenyl-α-[(4S)-phenyloxazolidin-2-ylidene]-2-oxazoline-2-acetonitrile

2-((S)-4-Phenyl-4,5-dihydrooxazol-2-yl)-2-((S)-4-phenylox

(s,s)-4-phenyl-α-(4-phenyloxazolidin-2-ylidene)-2-oxazoline-2-acetonitrile

2-Oxazoleacetonitrile, 4,5-dihydro-4-phenyl-α-[(4S)-4-phenyl-2-oxazolidinylidene]-, (4S)-

(4S)-(+)-Phenyl-&#945

-[(4S)-phenyloxazolidin-2-ylidene]-2-oxazoline-2-acetonitrile

150639-33-1

BOX

Asymmetric Synthesis

Chiral Catalysts, Ligands, and Reagents

Privileged Ligands