ChemicalBook > CAS DataBase List > (+)-(4S)-PHENYL-ALPHA-[(4S)-PHENYLOXAZOLIDIN-2-YLIDENE]-2-OXAZOLINE-2-ACETONITRILE

(+)-(4S)-PHENYL-ALPHA-[(4S)-PHENYLOXAZOLIDIN-2-YLIDENE]-2-OXAZOLINE-2-ACETONITRILE

Product Name
(+)-(4S)-PHENYL-ALPHA-[(4S)-PHENYLOXAZOLIDIN-2-YLIDENE]-2-OXAZOLINE-2-ACETONITRILE
CAS No.
150639-33-1
Chemical Name
(+)-(4S)-PHENYL-ALPHA-[(4S)-PHENYLOXAZOLIDIN-2-YLIDENE]-2-OXAZOLINE-2-ACETONITRILE
Synonyms
(4S)-(+)-Phenyl-α2-((S)-4-Phenyl-4,5-dihydrooxazol-2-yl)-2-((S)-4-phenylox;(S,S)-4-phe-A-(4-phe.oxazolidin-ylidene) -oxazoline-acetonit.;-[(4S)-phenyloxazolidin-2-ylidene]-2-oxazoline-2-acetonitrile;(s,s)-4-phenyl-α-(4-phenyloxazolidin-2-ylidene)-2-oxazoline-2-acetonitrile;(s,s)-4-phenyl-α-(4-phenyloxazolidin-2-ylidene)-2-oxazoline-2-acetonitrile;(S,S)-4-PHENYL-ALPHA-(4-PHENYLOXAZOLIDIN-2-YLIDENE)-2-OXAZOLINE-2-ACETONITRILE;(4s)-(+)-phenyl-α-[(4s)-phenyloxazolidin-2-ylidene]-2-oxazoline-2-acetonitrile;(4S)-(+)-Phenyl-α-[(4S)-phenyloxazolidin-2-ylidene]-2-oxazoline-2-acetonitrile;(S,S)-(+)-4-PHENYL-ALPHA-(4-PHENYLOXAZOL IDIN-2 -YLIDENE)-2-OXAZOLINE-2-ACETONITR
CBNumber
CB5174902
Molecular Formula
C20H17N3O2
Formula Weight
331.37
MOL File
150639-33-1.mol
More
Less

(+)-(4S)-PHENYL-ALPHA-[(4S)-PHENYLOXAZOLIDIN-2-YLIDENE]-2-OXAZOLINE-2-ACETONITRILE Property

Melting point:
146-148 °C(lit.)
Boiling point:
457.5±45.0 °C(Predicted)
Density 
1.27±0.1 g/cm3(Predicted)
storage temp. 
2-8°C
pka
3.30±0.70(Predicted)
optical activity
[α]20/D +364°, c = 1 in chloroform
More
Less

Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
417068
Product name
(4S)-(+)-Phenyl-α-[(4S)-phenyloxazolidin-2-ylidene]-2-oxazoline-2-acetonitrile
Purity
97%
Packaging
1g
Price
$299.4
Updated
2024/03/01
American Custom Chemicals Corporation
Product number
CCH0004926
Product name
(4S)-(+)-PHENYL-ALPHA-[(4S)-PHENYLOXAZOLIDIN-2-YLIDENE]-2-OXAZOLINE-2-ACETONITRILE
Purity
97.00%
Packaging
1G
Price
$833.76
Updated
2021/12/16
Arctom
Product number
AS713045
Product name
2-((S)-4-Phenyl-4,5-dihydrooxazol-2-yl)-2-((S)-4-phenyloxazolidin-2-ylidene)acetonitrile
Purity
98%
Packaging
1g
Price
$404
Updated
2021/12/16
Ambeed
Product number
A1355479
Product name
2-((S)-4-Phenyl-4,5-dihydrooxazol-2-yl)-2-((S)-4-phenyloxazolidin-2-ylidene)acetonitrile
Purity
98%
Packaging
1g
Price
$455
Updated
2021/12/16
Arctom
Product number
AS713045
Product name
2-((S)-4-Phenyl-4,5-dihydrooxazol-2-yl)-2-((S)-4-phenyloxazolidin-2-ylidene)acetonitrile
Purity
98%
Packaging
100mg
Price
$57
Updated
2021/12/16
More
Less

(+)-(4S)-PHENYL-ALPHA-[(4S)-PHENYLOXAZOLIDIN-2-YLIDENE]-2-OXAZOLINE-2-ACETONITRILE Chemical Properties,Usage,Production

Uses

Ligand for enantioselective catalysis. Easily forms bidentate coordination complexes due to the strong affinity of the oxazoline nitrogen for various metals.

General Description

(4S)-(+)-Phenyl-α-[(4S)-phenyloxazolidin-2-ylidene]-2-oxazoline-2-acetonitrile is a C2-symmetric chiral bisoxazoline (BOX) ligand.

(+)-(4S)-PHENYL-ALPHA-[(4S)-PHENYLOXAZOLIDIN-2-YLIDENE]-2-OXAZOLINE-2-ACETONITRILE Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

(+)-(4S)-PHENYL-ALPHA-[(4S)-PHENYLOXAZOLIDIN-2-YLIDENE]-2-OXAZOLINE-2-ACETONITRILE Suppliers

China 21 South Korea 1 Switzerland 1 United States 3 Global 26
SIGMA-RBI
Tel
--
Fax
--
Country
Switzerland
ProdList
6896
Advantage
91

150639-33-1, (+)-(4S)-PHENYL-ALPHA-[(4S)-PHENYLOXAZOLIDIN-2-YLIDENE]-2-OXAZOLINE-2-ACETONITRILERelated Search:

Oxazoline (S)-(+)-1-AMINO-1-PHENYL-2-METHOXYETHANE MYCOLIDE 2-ISOPROPENYL-2-OXAZOLINE 99+% 2-Ethyl-2-oxazoline (+)-(4S)-PHENYL-ALPHA-[(4S)-PHENYLOXAZOLIDIN-2-YLIDENE]-2-OXAZOLINE-2-ACETONITRILE 3-ETHOXYACRYLONITRILE

  • (s,s)-4-phenyl-α-(4-phenyloxazolidin-2-ylidene)-2-oxazoline-2-acetonitrile
  • (4S)-(+)-Phenyl-alpha-[(4S)-phenyloxazolidin-2-ylidene]-2-oxazoline-2-acetonitrile 97%
  • (+)-(4S)-PHENYL-ALPHA-[(4S)-PHENYLOXAZOLIDIN-2-YLIDENE]-2-OXAZOLINE-2-ACETONITRILE
  • (S,S)-4-PHENYL-ALPHA-(4-PHENYLOXAZOLIDIN-2-YLIDENE)-2-OXAZOLINE-2-ACETONITRILE
  • (S,S)-4-phe-A-(4-phe.oxazolidin-ylidene) -oxazoline-acetonit.
  • (S,S)-(+)-4-PHENYL-ALPHA-(4-PHENYLOXAZOL IDIN-2 -YLIDENE)-2-OXAZOLINE-2-ACETONITR
  • (4s)-(+)-phenyl-α-[(4s)-phenyloxazolidin-2-ylidene]-2-oxazoline-2-acetonitrile
  • (2Z)-2-[(4S)-4-phenyl-4,5-dihydro-1,3-oxazol-2-yl]-2-[(4S)-4-phenyl-1,3-oxazolidin-2-ylidene]acetonitrile
  • 2-Oxazoleacetonitrile, 4,5-dihydro-4-phenyl-α-[(4S)-4-phenyl-2-oxazolidinylidene]-, (4S)-
  • 2-((S)-4-Phenyl-4,5-dihydrooxazol-2-yl)-2-((S)-4-phenyloxazolidin-2-ylidene)acetonitrile
  • (+)-(4S)-PHENYL-ALPHA-[(4S)-PHENYLOXAZOLIDIN-2-YLIDENE]-2-OXAZOLINE-2-ACETONITRILE
  • (4S)-(+)-Phenyl-α-[(4S)-phenyloxazolidin-2-ylidene]-2-oxazoline-2-acetonitrile
  • 2-((S)-4-Phenyl-4,5-dihydrooxazol-2-yl)-2-((S)-4-phenylox
  • (s,s)-4-phenyl-α-(4-phenyloxazolidin-2-ylidene)-2-oxazoline-2-acetonitrile
  • 2-Oxazoleacetonitrile, 4,5-dihydro-4-phenyl-α-[(4S)-4-phenyl-2-oxazolidinylidene]-, (4S)-
  • (4S)-(+)-Phenyl-&#945
  • -[(4S)-phenyloxazolidin-2-ylidene]-2-oxazoline-2-acetonitrile
  • 150639-33-1
  • BOX
  • Asymmetric Synthesis
  • Chiral Catalysts, Ligands, and Reagents
  • Privileged Ligands