CITRACONIC ACID DIMETHYL ESTER

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CITRACONIC ACID DIMETHYL ESTER

Product Name: CITRACONIC ACID DIMETHYL ESTER
CAS No.: 617-54-9
Chemical Name: CITRACONIC ACID DIMETHYL ESTER
Synonyms: C05126;DIMETHYL CITRACONATE;dimethylmethylmaleate;Dimethyl methyl maleate;Citraconate de dimethyle;Dimethyl Citraconate >dimethyl 2-methylmaleate;(2Z)-Dimethyl 2-methylmaleate;methylmaleicacid,dimethylester;CITRACONIC ACID DIMETHYL ESTER
CBNumber: CB5179806
Molecular Formula: C7H10O4
Formula Weight: 158.15
MOL File: 617-54-9.mol

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CITRACONIC ACID DIMETHYL ESTER Property

Boiling point:: 211 °C
Density: 1,11 g/cm³
refractive index: 1.4460-1.4490
storage temp.: Sealed in dry,Room Temperature
solubility: Chloroform (Slightly), Methanol (Slightly)
form: Oil
color: Clear Colourless
LogP: 0.849 (est)
EPA Substance Registry System: 2-Butenedioic acid, 2-methyl-, dimethyl ester, (2Z)- (617-54-9)

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Safety

Risk Statements: 36/37/38
Safety Statements: 26-36
RTECS: GE6700000
HS Code: 2917198090
Toxicity: Both the acute oral LD₅₀ value in rats and the acute dermal LD₅₀ value in rabbits exceeded 5 g/kg (Moreno, 1974).

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H227Combustible liquid

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P403+P235Store in a well-ventilated place. Keep cool.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical

Product number: C0364
Product name: Dimethyl Citraconate
Purity: >99.0%(GC)
Packaging: 5g
Price: $85
Updated: 2024/03/01

TCI Chemical

Product number: C0364
Product name: Dimethyl Citraconate
Purity: >99.0%(GC)
Packaging: 25g
Price: $224
Updated: 2024/03/01

TRC

Product number: D471950
Product name: Dimethyl Citraconate
Packaging: 100mg
Price: $150
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: CHM0237738
Product name: DIMETHYL CITRACONATE
Purity: 99.00%
Packaging: 250G
Price: $5020.79
Updated: 2021/12/16

AK Scientific

Product number: J57352
Product name: Citraconicaciddimethylester
Packaging: 25g
Price: $253
Updated: 2021/12/16

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CITRACONIC ACID DIMETHYL ESTER Chemical Properties,Usage,Production

Occurrence

Has apparently not been reported to occur in nature.

Uses

Dimethyl Citraconate is a useful synthetic intermediate. It has been used in the synthesis of natural products chaetomellic acid A anhydride and 1,7(Z)- nonadecadiene-2,3-dicarboxylic acid. It is also used to prepare acyclic alkanes by reduction using homogeneous catalysts or biocatalysts.

Preparation

By the reaction of methanol with citraconic anhydride in the presence of a catalyst.

Synthesis Reference(s)

Journal of the American Chemical Society, 94, p. 9269, 1972 DOI: 10.1021/ja00781a071

CITRACONIC ACID DIMETHYL ESTER Preparation Products And Raw materials

Raw materials

Preparation Products

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617-54-9, CITRACONIC ACID DIMETHYL ESTERRelated Search:

Dimethyl sulfate CITRACONIC ACID DIMETHYL ESTER Citraconic acid TETRAETHYL ETHYLENETETRACARBOXYLATE 2-HYDROXY-5-OXO-2,5-DIHYDRO-FURAN-3,4-DICARBOXYLIC ACID DIMETHYL ESTER DIETHYL DICYANOFUMARATE, 97 TRIALLYL ACONITATE TRIETHYL ACONITATE TRANS-ACONITIC ACID TRIMETHYL ESTER ETHYL 7-HYDROXYCOUMARIN-4-CARBOXYLATE TETRAMETHYL (1Z,3Z)-1-{[4-(ETHOXYCARBONYL)-1,2,3-THIADIAZOL-5-YL]AMINO}BUTA-1,3-DIENE-1,2,3,4-TETRACARBOXYLATE TRIETHYL 1,1,2-ETHYLENETRICARBOXYLATE RARECHEM AL BI 1458 3-HYDROXY-2-OXO-5,6,7,8-TETRAHYDRO-2H-PYRANO[3,2-B]PYRIDINE-4-CARBOXYLIC ACID ETHYL ESTER RARECHEM AL BF 1458 1-Propene-1,2,3-tricarboxylic acid, trihexyl ester 2-(TERT-BUTYL) 1,1-DIETHYL 1,1,2-ETHYLENETRICARBOXYLATE (1Z,3Z)-TETRAMETHYL 1-(4-CARBAMOYL-1,2,3-THIADIAZOL-5-YLAMINO)BUTA-1,3-DIENE-1,2,3,4-TETRACARBOXYLATE

2-Butenedioic acid, 2-methyl-, dimethyl ester (Z)-

2-methyl-,dimethylester,(z)-2-butenedioicaci

2-Methyl-but-2-enedioic acid dimethyl ester, Z

cis-2-methyl-2-butenedioicacid,dimethylester

cis-2-methyl-but-2-enoicaciddimethylester

Dimethyl (2Z)-2-methyl-2-butenedioate

Dimethyl methyl maleate

dimethylmethylmaleate

Maleic acid, methyl-, dimethyl ester

Methylmaleic acid, dimethyl ester

methylmaleicacid,dimethylester

DIMETHYL CITRACONATE

CITRACONIC ACID DIMETHYL ESTER

2-Butenedioic acid, 2-methyl-, dimethyl ester, (2Z)-

(Z)-2-Methyl-2-butenedioic acid dimethyl ester

Dimethyl cis-1-propene-1,2-dicarboxylate

C05126

Citraconate de dimethyle

Dimethyl Citraconate &gt

Dimethyl Citraconate@1000 μg/mL in Ethanol

2-Butenedioic acid, 2-methyl-, 1,4-dimethyl ester, (2Z)-

dimethyl 2-methylmaleate

(2Z)-Dimethyl 2-methylmaleate

617-54-9　CITRACONIC ACID DIMETHYL ESTER

(Z)-Citraconic acid-dimethyl ester

617-54-9

C7H10O4C7H10O4