ChemicalBook > CAS DataBase List > 1-BROMO-4-FLUORONAPHTHALENE

1-BROMO-4-FLUORONAPHTHALENE

Product Name
1-BROMO-4-FLUORONAPHTHALENE
CAS No.
341-41-3
Chemical Name
1-BROMO-4-FLUORONAPHTHALENE
Synonyms
BUTTPARK 44\09-75;1-Bromo-4-fluonaphthalene;1-FLUORO-4-BROMONAPHTHALENE;1-BROMO-4-FLUORONAPHTHALENE;Naphthalene, 1-bromo-4-fluoro-;1-Bromo-4-fluoronaphthalene>1-Bromo-4-fluoronaphthalene 98%;1-Bromo-4-fluoronaphthalene,98%
CBNumber
CB5197752
Molecular Formula
C10H6BrF
Formula Weight
225.06
MOL File
341-41-3.mol
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1-BROMO-4-FLUORONAPHTHALENE Property

Melting point:
35-38 °C (lit.)
Boiling point:
110-115 °C(Press: 2 Torr)
Density 
1.563±0.06 g/cm3(Predicted)
Flash point:
>230 °F
storage temp. 
Sealed in dry,2-8°C
solubility 
Chloroform (Slightly), DMSO (Slightly)
form 
Solid
color 
White
BRN 
2085804
InChI
InChI=1S/C10H6BrF/c11-9-5-6-10(12)8-4-2-1-3-7(8)9/h1-6H
InChIKey
VAUJZKBFENPOCH-UHFFFAOYSA-N
SMILES
C1(Br)=C2C(C=CC=C2)=C(F)C=C1
CAS DataBase Reference
341-41-3(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
HazardClass 
IRRITANT
HS Code 
29039990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
537195
Product name
1-Bromo-4-fluoronaphthalene
Purity
97%
Packaging
5g
Price
$66
Updated
2024/03/01
TCI Chemical
Product number
B3797
Product name
1-Bromo-4-fluoronaphthalene
Purity
>97.0%(GC)
Packaging
1g
Price
$49
Updated
2025/07/31
TCI Chemical
Product number
B3797
Product name
1-Bromo-4-fluoronaphthalene
Purity
>97.0%(GC)
Packaging
5g
Price
$169
Updated
2025/07/31
TRC
Product number
B689065
Product name
1-Bromo-4-fluoronaphthalene
Packaging
2.5g
Price
$70
Updated
2021/12/16
AK Scientific
Product number
Z2820
Product name
4-Bromo-1-fluoronaphthalene
Packaging
25g
Price
$81
Updated
2021/12/16
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1-BROMO-4-FLUORONAPHTHALENE Chemical Properties,Usage,Production

Chemical Properties

Solid

Uses

1-Bromo-4-fluoronaphthalene is the starting material for the synthesis of Fluorobenzo[c]fluoren (F588435) which is a polycyclic aromatic hydrocarbon used in materials science extensively due to utility in organic electronics, light emitting diodes and solar cells.

Synthesis

321-38-0

341-41-3

General procedure for the synthesis of 1-bromo-4-fluoronaphthalene from 1-fluoronaphthalene: 1-fluoronaphthalene (20.0 g, 0.137 mol) was added to a 500 mL single-necked flask with carbon tetrachloride (120.0 mL), and bromine (10.9 g, 0.068 mol) was added dropwise slowly, followed by heating and refluxing for 2 hours. Upon completion of the reaction, the reaction solution was concentrated under reduced pressure and then the concentrate was poured into methanol (80.0 mL). The solid was allowed to precipitate overnight at room temperature to give 28.2 g of 1-bromo-4-fluoronaphthalene in 91.5% yield.

References

[1] Patent: CN106478376, 2017, A. Location in patent: Paragraph 0009; 0020; 0021; 0029; 0030; 0038; 0039; 0047
[2] Journal of Medicinal Chemistry, 2004, vol. 47, # 6, p. 1575 - 1586
[3] Justus Liebigs Annalen der Chemie, 1931, vol. 487, p. 270,282
[4] Patent: US2001/49379, 2001, A1
[5] Patent: US6211208, 2001, B1

1-BROMO-4-FLUORONAPHTHALENE Preparation Products And Raw materials

Raw materials

Preparation Products

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1-BROMO-4-FLUORONAPHTHALENE Suppliers

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View Lastest Price from 1-BROMO-4-FLUORONAPHTHALENE manufacturers

Shanghai UCHEM Inc.
Product
1-Bromo-4-fluoronaphthalene 341-41-3
Price
US $27.00-388.00/g
Min. Order
25g
Purity
0.97
Supply Ability
25kg
Release date
2023-12-20
Shaanxi Dideu Medichem Co. Ltd
Product
1-BROMO-4-FLUORONAPHTHALENE 341-41-3
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
200KG
Release date
2024-06-04
Career Henan Chemical Co
Product
1-BROMO-4-FLUORONAPHTHALENE 341-41-3
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
200kg
Release date
2019-12-20

341-41-3, 1-BROMO-4-FLUORONAPHTHALENERelated Search:


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  • FC10H6Br
  • C10H6BrF
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