ChemicalBook > CAS DataBase List > 2-Bromo-6-fluoronaphthalene

2-Bromo-6-fluoronaphthalene

Product Name
2-Bromo-6-fluoronaphthalene
CAS No.
324-41-4
Chemical Name
2-Bromo-6-fluoronaphthalene
Synonyms
EOS-60456;2-Bromo-6-fluorophthalene;2-fluoro-6-bromonaphthalene;2-Bromo-6-fluoronaphthalene;Naphthalene, 2-bromo-6-fluoro-;5.2-Bromo-6-fluoro-naphthalene
CBNumber
CB5966521
Molecular Formula
C10H6BrF
Formula Weight
225.06
MOL File
324-41-4.mol
More
Less

2-Bromo-6-fluoronaphthalene Property

Melting point:
64.0 to 68.0 °C
Boiling point:
140°C/9mmHg(lit.)
Density 
1.563
storage temp. 
Sealed in dry,Room Temperature
form 
powder to crystal
color 
White to Light yellow to Light orange
More
Less

Safety

Hazard Codes 
Xi
HazardClass 
IRRITANT
HS Code 
2903998090
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

More
Less

N-Bromosuccinimide Price

TCI Chemical
Product number
B5229
Product name
2-Bromo-6-fluoronaphthalene
Purity
>97.0%(GC)
Packaging
1g
Price
$165
Updated
2025/07/31
TRC
Product number
B692703
Product name
2-Bromo-6-fluoronaphthalene
Packaging
100mg
Price
$45
Updated
2021/12/16
TRC
Product number
B692703
Product name
2-Bromo-6-fluoronaphthalene
Packaging
500mg
Price
$65
Updated
2021/12/16
Oakwood
Product number
067631
Product name
2-Bromo-6-fluoronaphthalene
Purity
97%
Packaging
250mg
Price
$20
Updated
2021/12/16
SynQuest Laboratories
Product number
1600-B-26
Product name
2-Bromo-6-fluoronaphthalene
Purity
96%
Packaging
1g
Price
$40
Updated
2021/12/16
More
Less

2-Bromo-6-fluoronaphthalene Chemical Properties,Usage,Production

Chemical Properties

white solid

Synthesis

87700-58-1

324-41-4

Step 2: In a dry reaction flask, 6-fluoro-2-naphthalenecarbonyl chloride (472 mg, 2.097 mmol) with AIBN (173 mg, 1.052 mmol) was dissolved in CBrCl3 (10 mL). The above solution was slowly added dropwise to a mixture containing 2-mercaptopyridine N-oxide sodium salt (981 mg, 6.58 mmol) and CBrCl3 (10 mL) under nitrogen protection at 100 °C over 30 min. After the dropwise addition, the reaction mixture was continued to be stirred at 100 °C for 15 min and subsequently cooled to room temperature. The reaction solution was quenched with deionized water (H2O) and extracted with ethyl acetate (EtOAc, 2 × 10 mL). The organic phases were combined, dried with anhydrous magnesium sulfate (MgSO4), filtered and concentrated under reduced pressure. The crude product was purified by a Biotage fast chromatography system (elution gradient: 0-5% EtOAc/heptane; column: SNAP25) to afford the target compound 2-bromo-6-fluoronaphthalene (6b, 472 mg, 40% yield) as a white solid.1H NMR (400 MHz, MeOD) δ ppm: 7.34 (td, J = 8.84, 2.59 Hz, 1H), 7.49-7.57 (m, 1H), 7.60 (ddd, J = 8.78, 1.96, 0.69 Hz, 1H), 7.77 (d, J = 8.84 Hz, 1H), 7.87 (dd, J = 9.09, 5.56 Hz, 1H), 8.09 (d, J = 1.58 Hz, 1H).

References

[1] Patent: WO2011/61168, 2011, A1. Location in patent: Page/Page column 53

2-Bromo-6-fluoronaphthalene Preparation Products And Raw materials

Raw materials

Ammonium hydroxide Sodium sulfite Hexafluorophosphoric acid 6-Bromo-2-naphthol

Preparation Products

More
Less

2-Bromo-6-fluoronaphthalene Suppliers

Americas 1 China 128 Europe 1 Germany 1 India 2 Japan 1 United Kingdom 3 United States 10 Global 147
J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Wuhan Chemwish Technology Co., Ltd
Tel
86-027-67849912
Fax
86-027-87531808
Email
sales@chemwish.com
Country
China
ProdList
35896
Advantage
56
Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Country
China
ProdList
18207
Advantage
66
JinYan Chemicals(ShangHai) Co.,Ltd.
Tel
13817811078
Fax
86-021-50426522,50426273
Email
sales@jingyan-chemical.com
Country
China
ProdList
9976
Advantage
60
Nanjing Chemlin Chemical Co., Ltd
Tel
025-83697070
Fax
+86-25-83453306
Email
info@chemlin.com.cn
Country
China
ProdList
15883
Advantage
64
Shandong Xiya Chemical Co., Ltd
Tel
4009903999 13355009207
Fax
0539-6365991
Email
3007715519@qq.com
Country
China
ProdList
18729
Advantage
57
Tianjin Jinyuda Chemical Co., Ltd.
Tel
022-58013646 13011382049
Fax
022-23854368
Email
sales@jinyudachem.com
Country
China
ProdList
1930
Advantage
55
NovoChemy Ltd.
Tel
021-31261262/ 49 (0)17662837245
Fax
(0)21-33250524
Email
sales@novochemy.com
Country
Germany
ProdList
6328
Advantage
58
TOKYO CHEMICAL INDUSTRY CO., LTD.
Tel
03-36680489
Fax
03-3668-0520
Email
Sales-JP@TCIchemicals.com
Country
Japan
ProdList
28387
Advantage
80
More
Less

View Lastest Price from 2-Bromo-6-fluoronaphthalene manufacturers

Career Henan Chemical Co
Product
2-Bromo-6-fluoronaphthalene 324-41-4
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
1000KGS
Release date
2019-12-18

324-41-4, 2-Bromo-6-fluoronaphthaleneRelated Search:

Octafluoronaphthalene 1-Bromonaphthalene 2-Bromonaphthalene 1-Fluoronaphthalene Ethyl bromodifluoroacetate Bromine 4-BROMO-1-FLUORONAPHTHALENE-2-BORONIC ACID 1-BROMO-4-FLUORONAPHTHALENE 1-BROMO-8-FLUORONAPHTHALENE 2-BROMOHEPTAFLUORONAPHTHALENE 2-Bromo-6-fluoronaphthalene

  • 2-Bromo-6-fluoronaphthalene
  • 2-fluoro-6-bromonaphthalene
  • 5.2-Bromo-6-fluoro-naphthalene
  • 2-Bromo-6-fluorophthalene
  • EOS-60456
  • Naphthalene, 2-bromo-6-fluoro-
  • 324-41-4
  • Fluorine series
  • Fused Ring Systems
  • Halides
  • Benzene series