ChemicalBook > CAS DataBase List > (S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS
(S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS
Reactions- Product Name
- (S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS
- CAS No.
- 850444-36-9
- Chemical Name
- (S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS
- Synonyms
- 97% TANIAPHOS;(SP)-1-[(S)-aL;(S,Sp)-Taniaphos;(2R)-1-[(S)-α-(Dimethylamino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene;(SP)-1-[(S)-α-(Dimethylamino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene;(2Sp)-1-[(S)-α-(Dimethylamino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene;(SP)-1-[(S)-alpha-(Dimethylamino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene;(S)-(-)-[(S)-2-Diphenylphosphinoferrocenyl](N,N-diMethylaMino)(2-diphenylphosphinophenyl)Methane;(S)-1-Diphenylphosphino-2-[(S)-(N,N-dimethylamino) [2-(diphenylphosphino)phenyl]methyl]ferrocene;(S)-1-Diphenylphosphino-2-[(S)-a-(N,N-dimethylamino)-o-(diphenylphosphinophenyl)-methyl]ferrocene
- CBNumber
- CB52129553
- Molecular Formula
- C38H34NP2.C5H5.Fe
- Formula Weight
- 687.581
- MOL File
- 850444-36-9.mol
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(S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS Property
- alpha
- -312° ±15° (c 0.5, CHCl3)
- storage temp.
- 2-8°C
- form
- Powder
- color
- orange
- Stability:
- store cold
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Safety
- WGK Germany
- 3
- HS Code
- 29319090
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 73476
- Product name
- (SP)-1-[(S)-α-(Dimethylamino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene
- Purity
- ≥97%, optical purity ee: ≥99%
- Packaging
- 1g
- Price
- $730
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 73476
- Product name
- (SP)-1-[(S)-α-(Dimethylamino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene
- Purity
- ≥97%, optical purity ee: ≥99%
- Packaging
- 5g
- Price
- $3370
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 26-1155
- Product name
- (S)-(-)-[(S)-2-Diphenylphosphinoferrocenyl](N,N-dimethylamino)(2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS
- Packaging
- 100mg
- Price
- $96
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 26-1155
- Product name
- (S)-(-)-[(S)-2-Diphenylphosphinoferrocenyl](N,N-dimethylamino)(2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS
- Packaging
- 500mg
- Price
- $355
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 73476
- Product name
- (SP)-1-[(S)-α-(Dimethylamino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene
- Purity
- ≥97%, optical purity ee: ≥99%
- Packaging
- 100mg
- Price
- $92.8
- Updated
- 2024/03/01
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(S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS Chemical Properties,Usage,Production
Reactions
- Ligand for the Ru-catalyzed hydrogenation of $-ketoesters, enamides and itaconates.
- Ligand for Cu-catalyzed asymmetric conjugate addition of Grignard reagents to cyclic enones.
- AgOAc-catalyzed asymmetric amination of glycine Schiff bases with azodicarboxylates.
Chemical Properties
Orange powder
General Description
sold in collaboration with Solvias AG
(S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS Preparation Products And Raw materials
Raw materials
Preparation Products
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(S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS Suppliers
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