Sunset Yellow FCF Property

Melting point:

390°C (dec.)

Boiling point:

162.4°C

Density 

0.474-0.588[at 20℃]

storage temp. 

Amber Vial, Refrigerator

solubility 

Soluble in water, ethanol

Colour Index 

15985

pka

0[at 20 ℃]

form 

crystals

color 

Orange-red

Odor

Odorless

Water Solubility 

5-10 g/100 mL at 24 ºC

λmax

480 nm

Merck 

14,9001

Stability:

Stable. Combustible. Incompatible with strong oxidizing agents.

Biological Applications

Medical devices; treating bone metabolic diseases,dermatological disorders,mitochondrial diseases,respiratory illness

LogP

-0.244-0.046 at 25-26℃

CAS DataBase Reference

2783-94-0(CAS DataBase Reference)

IARC

3 (Vol. 8, Sup 7) 1987

EPA Substance Registry System

C.I. Food Yellow 3 (2783-94-0)

Safety

Hazard Codes 

Xi

Risk Statements 

36/37/38

Safety Statements 

26-36

WGK Germany 

2

RTECS 

QK2450000

HS Code 

32129000

Hazardous Substances Data

2783-94-0(Hazardous Substances Data)

Toxicity

LD50 in rats, mice (g/kg): >10, >6 orally (Gaunt, 1967)

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

P501Dispose of contents/container to..…

Sunset Yellow FCF Chemical Properties,Usage,Production

Description

FD & C Yellow No. 6 is principally the disodium salt of 6-hydroxy5-[(4-sulfophenyl)azo]-2-napthalenesulfonic acid. The trisodiumsalt of 3-hydroxy-4-[(4-sulfophenyl)azo]-2,7-napthal-enedisul- fonic acid may be added in small amounts.
The colorant is an orange powder that dissolves in water to give a solution yellow-orange at neutrality or in acid and red-brown in base. When dissolved in concentrated sulfuric acid, it yields an orange solution that turns yellow when diluted with water. It is slightly soluble in 95% ethanol.
FD & C Yellow No. 6 is used in various food items including dessert powders, cereals, bakery goods, snack foods, confectionery products, maraschino cherries, sausage, ice cream, sherbet, dairy products, and beverages. It is also used in cosmetics, ingested and externally applied drugs and dietary supplements.1 .

Chemical Properties

orange-red crystals or powder

Uses

Sunset Yellow FCF (FD&C Yellow #6) is a colorant. It has good stability to changes in ph, showing no appreciable change at ph 3–8. It has excellent solubility in water with a solubility of 19 g in 100 ml at 25°c. It has moderate stability to light, fair stability to oxidation, good stability to heat, and shows appreciable change in 10% sugar systems. It has a reddishyellow hue and has good tinctorial strength. It has moderate compatibility with food components and is used in beverages, bakery goods, dessert confections, and ice cream.

Uses

Provisionally listed for use in food, drugs and cosmetics. Sunset Yellow is useful in fermented foods which must be heat treated. It may be found in orange sodas, orange jelly, marzipan, Swiss rolls, apricot jam, citrus marmalade, lemon curd, sweets, hot chocolate mix and packet soups, trifle mix, breadcrumbs, snack chips, shelf fresh noodles, cheese sauce mixes. Sunset Yellow is a sulfonated ver sion of Sudan I, a possible carcinogen. Sunset Yellow itself may be responsible for causing an allergic reaction in people with an aspirin intolerance, resulting in various symptoms, including gastric upset, diarrhea, vomiting, nettle rash (urticaria), swelling of the skin (angioedema) and migraines.

Preparation

4-Aminobenzenesulfonic acid?diazo, and 6-Hydroxynaphthalene-2-sulfonic acid?coupling.

Definition

ChEBI: Sunset Yellow FCF is an organic molecular entity.

General Description

Orange-red crystals or a red powder.

Air & Water Reactions

Azo dyes can be explosive when suspended in air at specific concentrations. Soluble in water.

Reactivity Profile

Food Yellow 3 is an azo compound. Azo, diazo, azido compounds can detonate. This applies in particular to organic azides that have been sensitized by the addition of metal salts or strong acids. Toxic gases are formed by mixing materials of this class with acids, aldehydes, amides, carbamates, cyanides, inorganic fluorides, halogenated organics, isocyanates, ketones, metals, nitrides, peroxides, phenols, epoxides, acyl halides, and strong oxidizing or reducing agents. Flammable gases are formed by mixing materials in this group with alkali metals. Explosive combination can occur with strong oxidizing agents, metal salts, peroxides, and sulfides.

Health Hazard

SYMPTOMS: It can cause enlargement of the caecum and weight loss.

Fire Hazard

Flash point data for Food Yellow 3 are not available; however, Food Yellow 3 is probably combustible.

Flammability and Explosibility

Non flammable

Safety Profile

Low toxicity by ingestion and intraperitoneal routes. Mutation data reported. When heated to decomposition it emits very toxic fumes of NOx and SOx.

Properties and Applications

red light yellow to colourful yellow orange. Soluble in water for yellow light red clarified solution, slightly soluble in ethanol, insoluble in grease. The strong sulfuric acid in red for orange, yellow as diluted. Dye with strong hydrochloric acid solution of color; Add thick sodium hydroxide solution is palm red light. Has the characteristics of acid dyes, can make the animal fiber direct shading.