ChemicalBook > CAS DataBase List > METHYL 2-FLUORO-3-METHYLBENZOATE

METHYL 2-FLUORO-3-METHYLBENZOATE

Product Name: METHYL 2-FLUORO-3-METHYLBENZOATE
CAS No.: 586374-04-1
Chemical Name: METHYL 2-FLUORO-3-METHYLBENZOATE
Synonyms: 2-fluoro-3-methylbenzoate;METHYL 2-FLUORO-3-METHYLBENZOATE;2-Fluoro-3-methyl benzoate methyl;2-Fluoro-3-methylbenzoic acid methyl ester;Benzoic acid, 2-fluoro-3-methyl-, methyl ester;2-fluoro-3-methyl-Benzoic acid methyl ester (9CI ACI);Benzoic acid, 2-fluoro-3-methyl-, methyl ester (9CI, ACI)
CBNumber: CB52454716
Molecular Formula: C9H9FO2
Formula Weight: 168.16
MOL File: 586374-04-1.mol

Less

METHYL 2-FLUORO-3-METHYLBENZOATE Property

Boiling point:: 229.0±28.0℃ (760 Torr)
Density: 1.137±0.06 g/cm3 (20 ºC 760 Torr)
Flash point:: 89.8±18.9℃
storage temp.: Sealed in dry,Room Temperature
Appearance: Colorless to light pink Liquid

Less

Safety

HS Code: 2916399090

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H227Combustible liquid

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Less

N-Bromosuccinimide Price

Oakwood

Product number: 209485
Product name: Methyl 2-fluoro-3-methylbenzoate
Packaging: 250mg
Price: $25
Updated: 2021/12/16

Oakwood

Product number: 209485
Product name: Methyl 2-fluoro-3-methylbenzoate
Packaging: 1g
Price: $48
Updated: 2021/12/16

Oakwood

Product number: 209485
Product name: Methyl 2-fluoro-3-methylbenzoate
Packaging: 5g
Price: $148
Updated: 2021/12/16

Oakwood

Product number: 209485
Product name: Methyl 2-fluoro-3-methylbenzoate
Packaging: 25g
Price: $499
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: HCH0369203
Product name: METHYL-2-FLUORO-3-METHYLBENZOATE
Purity: 95.00%
Packaging: 5MG
Price: $504.85
Updated: 2021/12/16

Less

METHYL 2-FLUORO-3-METHYLBENZOATE Chemical Properties,Usage,Production

Chemical Properties

off-white powder

Synthesis

67-56-1

315-31-1

586374-04-1

Step A: Thionyl chloride (2.8 mL, 39.0 mmol) was added slowly and dropwise to a stirred solution of 2-fluoro-3-methylbenzoic acid (4.0 g, 26.0 mmol) in anhydrous methanol (52 mL) at 0 °C. The reaction mixture was stirred overnight under reflux conditions. Upon completion of the reaction, the mixture was diluted with methanol and the excess thionyl chloride was subsequently removed by concentration under reduced pressure. The residue was dissolved in ethyl acetate, the organic layer was washed with saturated aqueous sodium bicarbonate, dried over anhydrous sodium sulfate, filtered, and concentrated under reduced pressure to afford methyl 2-fluoro-3-methylbenzoate (3.6 g, 83% yield) as a clear oil. The product could be used in subsequent steps without further purification.1H NMR (500 MHz, CDCl3) δ 7.75-7.72 (m, 1H), 7.38-7.35 (m, 1H), 7.26-7.06 (m, 1H), 3.91 (s, 3H), 2.31 (s, 3H).

References

[1] Patent: WO2011/8572, 2011, A2. Location in patent: Page/Page column 62
[2] Patent: WO2005/18557, 2005, A2. Location in patent: Page/Page column 304
[3] Patent: WO2005/18557, 2005, A2. Location in patent: Page/Page column 304

METHYL 2-FLUORO-3-METHYLBENZOATE Preparation Products And Raw materials

Raw materials

Preparation Products

Less

METHYL 2-FLUORO-3-METHYLBENZOATE Suppliers

China 69 India 1 United Kingdom 1 United States 3 Global 74

Shijiazhuang Sdyano Fine Chemical Co., Ltd.

Tel: 0311-89250318 031166536426
Fax: 4000311741
Email: master@sjzsdyn.com
Country: China
ProdList: 2805
Advantage: 65

Nanjing Chemlin Chemical Co., Ltd

Tel: 025-83697070
Fax: +86-25-83453306
Email: info@chemlin.com.cn
Country: China
ProdList: 16075
Advantage: 64

Shanghai Hanhong Scientific Co.,Ltd.

Tel: 021-54306202 13764082696
Email: info@hanhongsci.com
Country: China
ProdList: 42934
Advantage: 64

Beijing Eternalchem Co,. Ltd.

Tel: 010-59484199 18611897322
Email: sales@eternalchem.com
Country: China
ProdList: 4383
Advantage: 60

Shanghai Sphchem Co., Ltd.

Tel: 021-56491756 13512199871
Fax: 021-5649-1756
Email: 2819742715@qq.com
Country: China
ProdList: 4000
Advantage: 55

Shanghai Raise Chemical Technology Co.,Ltd

Tel: 15026594951
Fax: 0556-5030632
Email: rs@raise-chem.com
Country: China
ProdList: 4454
Advantage: 55

Bide Pharmatech Ltd.

Tel: 400-164-7117 13681763483
Fax: +86-21-61629029
Email: product02@bidepharm.com
Country: China
ProdList: 39966
Advantage: 60

Beijing FYF Chemicals Co., Ltd

Tel: 010-57903446 15869909019
Fax: 010-57903446
Email: 168931144@qq.com
Country: China
ProdList: 2875
Advantage: 58

Shanghai ACT chemical Limited

Tel: 021-59904146 18001826933
Fax: +86-21-59904146
Email: sales@actchemical.com
Country: China
ProdList: 476
Advantage: 56

Tianjin Anhao Biological Technology Co., Ltd.

Tel
Email: sales@ahpharmatech.com
Country: China
ProdList: 5734
Advantage: 55

Nanjing Duolong Bio-tech Co.,Ltd.

Tel: 18905173768
Fax: 025-83263139
Email: 52513593@qq.com
Country: China
ProdList: 2331
Advantage: 50

Changzhou Tianrui Pharmaceutical Technology Co., Ltd.

Tel: 0519-85386832 13382812559
Fax: 0519-85386832
Email: sales@cztrchem.com
Country: China
ProdList: 1185
Advantage: 56

Bellen Chemistry Co., Ltd.

Tel: 010-60400365-8001 15910885229
Fax: 010-60400361
Email: service@bellenchem.com
Country: China
ProdList: 4514
Advantage: 60

Changzhou Anxuan Chemical, Co., Ltd.

Tel: 13912302692 13912302692;
Fax: 0519-88064678
Email: sales@anxuanchem.com
Country: China
ProdList: 4828
Advantage: 58

Shanghai Brain Biotechnology Co., Ltd.

Tel: 13564638271
Fax: 021-68948280
Email: shhjiang1977@163.com
Country: China
ProdList: 2987
Advantage: 55

Chengdu DingDang Pharmaceutical Co., Ltd.

Tel: 028-86040038 13980902949;
Fax: 028-85149890
Email: market@dingdangchem.com
Country: China
ProdList: 1853
Advantage: 55

Jinan elephant international trading co., LTD

Tel
Fax: -
Email: 13006575422@163.com
Country: China
ProdList: 6355
Advantage: 58

Amadis Chemical Company Limited

Tel: 571-89925085
Fax: 0086-571-89925065
Email: sales@amadischem.com
Country: China
ProdList: 131957
Advantage: 58

Shijiazhuang Yesheng Chemical Technology Co., Ltd

Tel: 18031147013 18031147013;
Fax: 0311-68030586
Email: yeshengchemical@163.com
Country: China
ProdList: 2607
Advantage: 58

Shanghai CR Corporation Limited

Tel: 13062833949; 4006653949 4006653949
Fax: QQ: 2136646215
Email: fred.wen@crcorporation.cn
Country: China
ProdList: 9756
Advantage: 58

Dalian lichuang Chemical Co., Ltd

Tel: 0411-0411-00000000 13644282108
Fax: -
Email: 3500508746@qq.com
Country: China
ProdList: 2896
Advantage: 55

Wuhan EEChem Technologies Co., Ltd

Tel: 0711-3617768 13308685235
Fax: 0711-3616558
Email: lihongcai4360@sina.com
Country: China
ProdList: 1510
Advantage: 55

Capot Chemical Co.,Ltd.

Tel: +86-（0）57185586718; +8613336195806
Fax: +86-571-85864795
Email: sales@capot.com
Country: China
ProdList: 29735
Advantage: 60

Aikon International Limited

Tel: 025-58851090 15955137747
Fax: (6)02557626880
Email: sales01@aikonchem.com
Country: China
ProdList: 15949
Advantage: 58

Suzhou Nuoouman Biological Technology Co., Ltd.

Tel: 15026866316
Email: 180642609@qq.com
Country: China
ProdList: 4967
Advantage: 58

Rhawn Reagent

Tel: 400-400-1332688 18019345275
Fax: 400-133-2688
Email: amy@rhawn.cn
Country: China
ProdList: 14948
Advantage: 58

Shanghai Haohong Pharmaceutical Co., Ltd.

Tel: 400-8210725 400821072
Fax: 021-58955996
Email: malulu@leyan.com
Country: China
ProdList: 25000
Advantage: 58

Win-Win Chemical CO., Limited

Tel: 0577-64498589 15325081899
Fax: 0577-56994596
Email: sales@win-winchemical.com
Country: China
ProdList: 1085
Advantage: 58

Cool Pharm, Ltd

Tel: 021-58581007 18019463053
Fax: 021-50966098
Email: sales@coolpharm.com
Country: China
ProdList: 12878
Advantage: 58

Fuxin Crest Biotechnology Co. Ltd.

Tel: 13062833949
Fax: QQ: 2073772974
Email: fred.wen@crcorporation.cn
Country: China
ProdList: 853
Advantage: 58

Allfluoro pharmaceutical co. ltd.

Tel: +86-400-0216110 +86-15958047586
Fax: 0086-21-33275002
Email: sales@allfluoro.com
Country: China
ProdList: 11385
Advantage: 58

Zhengzhou Alfa Chemical Co.,Ltd

Tel: +8618530059196
Email: sale04@alfachem.cn
Country: China
ProdList: 11784
Advantage: 58

Hefei TNJ Chemical Industry Co.,Ltd.

Tel: +86-0551-65418684 +8618949823763
Fax: 0086-551-65418684
Email: sales@tnjchem.com
Country: China
ProdList: 25356
Advantage: 58

Labnetwork lnc.

Tel: +86-27-50766799 +8618062016861
Email: contact@labnetwork.com
Country: China
ProdList: 19987
Advantage: 58

CD Chemical Group Limited

Tel: +8615986615575
Fax: 0086-13651442114
Email: info@codchem.com
Country: China
ProdList: 20342
Advantage: 58

Win-Win chemical CO., Limited

Tel: +86-0086-577-64498589 +86-15355981851
Fax: 0086-577-56994596
Email: sales@win-winchemical.com
Country: China
ProdList: 14359
Advantage: 58

Zhengzhou anmousse chemical products co. LTD

Tel: 0371-55289822 18737195735
Fax: QQ:483339295
Email: 483339295@qq.com
Country: China
ProdList: 7587
Advantage: 58

Shanghai Jiegu Biotechnology Co., Ltd.

Tel: 021-51698675
Email: sales@jiejiegroup.com
Country: China
ProdList: 8020
Advantage: 58

Shanghai Kaiwei Chemical Technology Co., Ltd.

Tel: 021-58461859 15821823057
Email: service@aiviche.com
Country: China
ProdList: 49312
Advantage: 58

career henan chemical co

Tel: +86-0371-86658258 +8613203830695
Fax: 0086-371-86658258
Email: factory@coreychem.com
Country: China
ProdList: 29798
Advantage: 58

Yuzhou Enthalpy Carbon Pharmaceutical Technology Co. LTD

Tel: 19963477321; 19963477321
Fax: QQ:2041275825
Email: 2041275825@qq.com
Country: China
ProdList: 1447
Advantage: 58

Shanghai Xiushi Biomedical Co., LTD

Tel: 15002184385 15021598081 15002184385
Email: product001@xiushipharm.com
Country: China
ProdList: 4719
Advantage: 58

Shanghai Sunway Pharmaceutical Technology Co.,Ltd.

Tel: 021-51816796-820 13611835272
Fax: 021-5161 3951
Email: sales2@sunwaypharm.com
Country: China
ProdList: 44119
Advantage: 58

Encyclopedia Source (Chengdu) Technology Co., Ltd.

Tel: 15021461747
Email: 446211270@qq.com
Country: China
ProdList: 1196
Advantage: 58

Bide Pharmatech Ltd.

Tel: 400-6005915
Email: sales@picasso-e.com
Country: China
ProdList: 39653
Advantage: 58

AAB-PHARMA LIMITED

Tel: 02566880956
Email: 3325708371@qq.com
Country: China
ProdList: 7869
Advantage: 58

Shandong Mingde Biotechnology Co., Ltd

Tel: 15553348166
Email: m15553348166@163.com
Country: China
ProdList: 9967
Advantage: 58

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 18621169109
Email: market03@meryer.com
Country: China
ProdList: 27987
Advantage: 58

Hangzhou Yaoruiyicheng Biological Medicine Co., Ltd

Tel: 18072846723 18072846723
Email: 2493446488@qq.com
Country: China
ProdList: 568
Advantage: 58

Shaanxi Didu New Material Co., Ltd

Tel: 029-81145920 17391631969
Email: 1046@dideu.com
Country: China
ProdList: 9996
Advantage: 58

Less

View Lastest Price from METHYL 2-FLUORO-3-METHYLBENZOATE manufacturers

Honest Joy Holdings Limited

Product: Methyl 2-fluoro-3-methylbenzoate 586374-04-1
Price: US $0.00/KG
Min. Order: 1KG
Purity: 97.0%
Supply Ability: 100 tons
Release date: 2022-01-14

Career Henan Chemical Co

Product: METHYL 2-FLUORO-3-METHYLBENZOATE 586374-04-1
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100KG
Release date: 2020-01-08

586374-04-1, METHYL 2-FLUORO-3-METHYLBENZOATERelated Search:

2,5-DIFLUORO-3-METHYLBENZOIC ACID ETHYL ESTER METHYL 2-FLUORO-3-METHYLBENZOATE RARECHEM AL BI 0317 RARECHEM AL BF 0317 RARECHEM AL BF 0492 2,5-DIFLUORO-3-METHYLBENZOIC ACID METHYL ESTER 2,4-DIFLUORO-3-METHYLBENZOICACID METHYL ESTER RARECHEM AL BI 0295 RARECHEM AL BI 0492 RARECHEM AL BF 0295 2,4-DIFLUORO-3-METHYLBENZOIC ACID ETHYL ESTER RARECHEM AL BF 0496 RARECHEM AL BI 0496

METHYL 2-FLUORO-3-METHYLBENZOATE

2-fluoro-3-methylbenzoate

2-Fluoro-3-methyl benzoate methyl

Benzoic acid, 2-fluoro-3-methyl-, methyl ester

2-Fluoro-3-methylbenzoic acid methyl ester

Benzoic acid, 2-fluoro-3-methyl-, methyl ester (9CI, ACI)

2-fluoro-3-methyl-Benzoic acid methyl ester (9CI ACI)

586374-04-1