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2-(Trimethylsilylmethyl)allyl acetate

Product Name
2-(Trimethylsilylmethyl)allyl acetate
CAS No.
72047-94-0
Chemical Name
2-(Trimethylsilylmethyl)allyl acetate
Synonyms
2-[(TRIMETHYLSILYL)METHYL]-2-PROPEN-1-YL ACETATE;DK875;SKL104;DKFELEX0231;2-(Acetoxymethyl)allyltrimethyliane;2-(ACETOXYMETHYL)ALLYTRIMETHYLSILANE;2-(TRIMETHYLSILYLMETHYL)ALLYL ACETATE;(2-(Ethoxymethyl)allyl)trimethylsilane;[2-(ACETOXYMETHYL)ALLYL]TRIMETHYLSILANE;2-((trimethylsilyl)methyl)-2-propen-1-yl
CBNumber
CB5245853
Molecular Formula
C9H18O2Si
Formula Weight
186.32
MOL File
72047-94-0.mol
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2-(Trimethylsilylmethyl)allyl acetate Property

Boiling point:
95 °C7 mm Hg(lit.)
Density 
0.877 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.440(lit.)
Flash point:
160 °F
storage temp. 
Inert atmosphere,2-8°C
solubility 
Solubility most organic solvents.
form 
Liquid
color 
Clear colorless
Water Solubility 
reacts
BRN 
1933657
InChIKey
IKQWABMHZKGCLX-UHFFFAOYSA-N
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38-14
Safety Statements 
26-36/37/39-37/39
WGK Germany 
3
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
339830
Product name
2-[(Acetoxymethyl)allyl]trimethylsilane
Purity
99%
Packaging
1g
Price
$63
Updated
2024/03/01
Sigma-Aldrich
Product number
339830
Product name
2-[(Acetoxymethyl)allyl]trimethylsilane
Purity
99%
Packaging
5g
Price
$314
Updated
2024/03/01
TRC
Product number
T798228
Product name
2-(Trimethylsilylmethyl)allylAcetate
Packaging
500mg
Price
$175
Updated
2021/12/16
Matrix Scientific
Product number
099119
Product name
2-((Trimethylsilyl)methyl)allyl acetate
Purity
95+%
Packaging
1g
Price
$171
Updated
2021/12/16
AK Scientific
Product number
V0008
Product name
2-(Trimethylsilylmethyl)allylacetate
Packaging
1g
Price
$165
Updated
2021/12/16
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2-(Trimethylsilylmethyl)allyl acetate Chemical Properties,Usage,Production

Chemical Properties

Clear colorless liquid

Physical properties

bp 68–70°C/6.5 mmHg;60–61°C/2.5 mmHg.

Uses

2-[(Acetoxymethyl)allyl]trimethylsilane was used in the cyclopentane synthesis via Pd(0)-catalyzed reactions with 2π acceptors.

Uses

precursor for palladium trimethylenemethane cycloaddition reactions.

Preparation

commercially available but expensive. Several preparations of (1) or the precursor alcohol (2) have been reported. The simplest involves the direct silylation of methallyl alcohol (eq 1).

2-(Trimethylsilylmethyl)allyl acetate Preparation Products And Raw materials

Raw materials

Preparation Products

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2-(Trimethylsilylmethyl)allyl acetate Suppliers

Shanghai joygo pharmacetical tech., Co., Ltd.
Tel
13621615409
Fax
QQ:3065286126, 1796903118
Email
sale1@joygooo.com
Country
China
ProdList
109
Advantage
50
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
INTATRADE GmbH
Tel
+49 3493/605464
Fax
+49 3493/605470
Email
sales@intatrade.de
Country
Germany
ProdList
3572
Advantage
66
Ark Pharm, Inc.
Tel
847-367-3680
Fax
847-367-3681
Email
sales@arkpharminc.com
Country
United States
ProdList
1670
Advantage
56
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44688
Advantage
61
Accela ChemBio Co.,Ltd.
Tel
021-50795510 4000665055
Fax
021-50795055
Email
sales@accelachem.com
Country
China
ProdList
11655
Advantage
64
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
Advantage
64
China DongFan Chemical Co.,LTD
Tel
86-0571-85151182
Fax
86-0571-85151182
Country
China
ProdList
5691
Advantage
66
Thermo Fisher Scientific
Tel
800-810-5118
Fax
+86-10-84193589
Email
cnchemical@thermofisher.com
Country
China
ProdList
17770
Advantage
75
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View Lastest Price from 2-(Trimethylsilylmethyl)allyl acetate manufacturers

Jiangsu Nata Opto-electronic Material Co.,Ltd.
Product
2-(Trimethylsilylmethyl)allyl acetate 72047-94-0
Price
US $0.00/KG
Min. Order
0.5KG
Purity
98%
Supply Ability
250KG
Release date
2023-05-24
Career Henan Chemical Co
Product
2-(Trimethylsilylmethyl)allyl acetate 72047-94-0
Price
US $9.80/KG
Min. Order
1g
Purity
≥99%
Supply Ability
100kg
Release date
2020-01-08

72047-94-0, 2-(Trimethylsilylmethyl)allyl acetateRelated Search:


  • 2-(Acetoxymethyl)allyltrimethyliane
  • 2-(Acetoxymethyl)allyltrimethyliane;2-Acetoxymethyl-3-(trimethylsilyl)propene;2-(Trimethylsilylmethyl)allyl acetate;2-(Trimethylsilylmethyl)-2-propen-1-yl acetate
  • 2-(ACETOXYMETHYL)-3-(TRIMETHYLSILYL)PROPENE
  • [2-(ACETOXYMETHYL)ALLYL]TRIMETHYLSILANE
  • 2-(ACETOXYMETHYL)ALLYTRIMETHYLSILANE
  • 2-[(TRIMETHYLSILYL)METHYL]-2-PROPEN-1-VL ACETATE
  • 2-[(TRIMETHYLSILYL)METHYL]-2-PROPEN-1-YL ACETATE
  • 2-(TRIMETHYLSILYLMETHYL)ALLYL ACETATE
  • 3-ACETOXY-2-(TRIMETHYLSILYLMETHYL)-1-PROPENE
  • 2-(Trimethylsilylmethyl)allyl acetate,98%
  • 2-(Trimethylsilylmethyl)allyl acetate2-(Acetoxymethyl)allytrimethylsilane
  • 2-((trimethylsilyl)methyl)-2-propen-1-yl
  • 2-(Trimethylsilylmethyl)-2-propen-1-yl acetate, 2-(Trimethylsilylmethyl)allyl acetate, 2-Acetoxymethyl-3-(trimethylsilyl)propene
  • 2-(trimethylsilylmethyl)prop-2-enyl acetate
  • 2-(Acetoxymethyl)allytrimethylsilane ,97.5%
  • (2-(Ethoxymethyl)allyl)trimethylsilane
  • 2-(TriMethylsilylMethyl)allyl acetate SynonyMs 2-(AcetoxyMethyl)allytriMethylsilane
  • 2-[(AcetoxyMethyl)allyl]triMethylsilane 99%
  • 2-Propen-1-ol, 2-[(trimethylsilyl)methyl]-, 1-acetate
  • SKL104
  • 2-[(trimethylsilyl)methyl]prop-2-en-1-yl acetate
  • DK875
  • DKFELEX0231
  • 72047-94-0
  • 92047-94-0
  • C9H18O2Si
  • CH3CO2CH2CCH2CH2SiCH33
  • Organic Building Blocks
  • Esters
  • Carbonyl Compounds
  • C8 to C9
  • Building Blocks