ChemicalBook > CAS DataBase List > 2-(Trimethylsilylmethyl)allyl acetate

2-(Trimethylsilylmethyl)allyl acetate

Product Name
2-(Trimethylsilylmethyl)allyl acetate
CAS No.
72047-94-0
Chemical Name
2-(Trimethylsilylmethyl)allyl acetate
Synonyms
2-[(TRIMETHYLSILYL)METHYL]-2-PROPEN-1-YL ACETATE;DK875;SKL104;DKFELEX0231;2-(Acetoxymethyl)allyltrimethyliane;2-(ACETOXYMETHYL)ALLYTRIMETHYLSILANE;2-(TRIMETHYLSILYLMETHYL)ALLYL ACETATE;(2-(Ethoxymethyl)allyl)trimethylsilane;[2-(ACETOXYMETHYL)ALLYL]TRIMETHYLSILANE;2-((trimethylsilyl)methyl)-2-propen-1-yl
CBNumber
CB5245853
Molecular Formula
C9H18O2Si
Formula Weight
186.32
MOL File
72047-94-0.mol
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2-(Trimethylsilylmethyl)allyl acetate Property

Boiling point:
95 °C7 mm Hg(lit.)
Density 
0.877 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.440(lit.)
Flash point:
160 °F
storage temp. 
Inert atmosphere,2-8°C
solubility 
Solubility most organic solvents.
form 
Liquid
color 
Clear colorless
Water Solubility 
reacts
BRN 
1933657
InChIKey
IKQWABMHZKGCLX-UHFFFAOYSA-N
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38-14
Safety Statements 
26-36/37/39-37/39
WGK Germany 
3
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
339830
Product name
2-[(Acetoxymethyl)allyl]trimethylsilane
Purity
99%
Packaging
1g
Price
$63
Updated
2024/03/01
Sigma-Aldrich
Product number
339830
Product name
2-[(Acetoxymethyl)allyl]trimethylsilane
Purity
99%
Packaging
5g
Price
$314
Updated
2024/03/01
TRC
Product number
T798228
Product name
2-(Trimethylsilylmethyl)allylAcetate
Packaging
500mg
Price
$175
Updated
2021/12/16
Matrix Scientific
Product number
099119
Product name
2-((Trimethylsilyl)methyl)allyl acetate
Purity
95+%
Packaging
1g
Price
$171
Updated
2021/12/16
AK Scientific
Product number
V0008
Product name
2-(Trimethylsilylmethyl)allylacetate
Packaging
1g
Price
$165
Updated
2021/12/16
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2-(Trimethylsilylmethyl)allyl acetate Chemical Properties,Usage,Production

Chemical Properties

Clear colorless liquid

Physical properties

bp 68–70°C/6.5 mmHg;60–61°C/2.5 mmHg.

Uses

2-[(Acetoxymethyl)allyl]trimethylsilane was used in the cyclopentane synthesis via Pd(0)-catalyzed reactions with 2π acceptors.

Uses

precursor for palladium trimethylenemethane cycloaddition reactions.

Preparation

commercially available but expensive. Several preparations of (1) or the precursor alcohol (2) have been reported. The simplest involves the direct silylation of methallyl alcohol (eq 1).

2-(Trimethylsilylmethyl)allyl acetate Preparation Products And Raw materials

Raw materials

Preparation Products

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2-(Trimethylsilylmethyl)allyl acetate Suppliers

Ark Pharm, Inc.
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View Lastest Price from 2-(Trimethylsilylmethyl)allyl acetate manufacturers

Jiangsu Nata Opto-electronic Material Co.,Ltd.
Product
2-(Trimethylsilylmethyl)allyl acetate 72047-94-0
Price
US $0.00/KG
Min. Order
0.5KG
Purity
98%
Supply Ability
250KG
Release date
2023-05-24
Career Henan Chemical Co
Product
2-(Trimethylsilylmethyl)allyl acetate 72047-94-0
Price
US $9.80/KG
Min. Order
1g
Purity
≥99%
Supply Ability
100kg
Release date
2020-01-08

72047-94-0, 2-(Trimethylsilylmethyl)allyl acetateRelated Search:


  • 2-(Acetoxymethyl)allyltrimethyliane
  • 2-(Acetoxymethyl)allyltrimethyliane;2-Acetoxymethyl-3-(trimethylsilyl)propene;2-(Trimethylsilylmethyl)allyl acetate;2-(Trimethylsilylmethyl)-2-propen-1-yl acetate
  • 2-(ACETOXYMETHYL)-3-(TRIMETHYLSILYL)PROPENE
  • [2-(ACETOXYMETHYL)ALLYL]TRIMETHYLSILANE
  • 2-(ACETOXYMETHYL)ALLYTRIMETHYLSILANE
  • 2-[(TRIMETHYLSILYL)METHYL]-2-PROPEN-1-VL ACETATE
  • 2-[(TRIMETHYLSILYL)METHYL]-2-PROPEN-1-YL ACETATE
  • 2-(TRIMETHYLSILYLMETHYL)ALLYL ACETATE
  • 3-ACETOXY-2-(TRIMETHYLSILYLMETHYL)-1-PROPENE
  • 2-(Trimethylsilylmethyl)allyl acetate,98%
  • 2-(Trimethylsilylmethyl)allyl acetate2-(Acetoxymethyl)allytrimethylsilane
  • 2-((trimethylsilyl)methyl)-2-propen-1-yl
  • 2-(Trimethylsilylmethyl)-2-propen-1-yl acetate, 2-(Trimethylsilylmethyl)allyl acetate, 2-Acetoxymethyl-3-(trimethylsilyl)propene
  • 2-(trimethylsilylmethyl)prop-2-enyl acetate
  • 2-(Acetoxymethyl)allytrimethylsilane ,97.5%
  • (2-(Ethoxymethyl)allyl)trimethylsilane
  • 2-(TriMethylsilylMethyl)allyl acetate SynonyMs 2-(AcetoxyMethyl)allytriMethylsilane
  • 2-[(AcetoxyMethyl)allyl]triMethylsilane 99%
  • 2-Propen-1-ol, 2-[(trimethylsilyl)methyl]-, 1-acetate
  • SKL104
  • 2-[(trimethylsilyl)methyl]prop-2-en-1-yl acetate
  • DK875
  • DKFELEX0231
  • 72047-94-0
  • 92047-94-0
  • C9H18O2Si
  • CH3CO2CH2CCH2CH2SiCH33
  • Organic Building Blocks
  • Esters
  • Carbonyl Compounds
  • C8 to C9
  • Building Blocks