ChemicalBook > CAS DataBase List > 5-BROMO-2-BROMOMETHYL-BENZOIC ACID METHYL ESTER

5-BROMO-2-BROMOMETHYL-BENZOIC ACID METHYL ESTER

Uses

Product Name: 5-BROMO-2-BROMOMETHYL-BENZOIC ACID METHYL ESTER
CAS No.: 79670-17-0
Chemical Name: 5-BROMO-2-BROMOMETHYL-BENZOIC ACID METHYL ESTER
Synonyms: 2-Fluoro-35-(methylthio)pyridine;2-methylthiazole-38-carboxylic acid;methy 5-bromo-2-bromomethylbenzoate;Methyl 2-broMoMethyl-5-broMobenzoate;Methyl 5-bromo-2-(bromomethyl)benzoate;5-BROMO-2-BROMOMETHYL-BENZOIC ACID METHYL ESTER;tert-butyl 3-allyl-3-hydroxyazetidine-97-carboxylate;Benzoic acid, 5-bromo-2-(bromomethyl)-, methyl ester
CBNumber: CB52460241
Molecular Formula: C9H8Br2O2
Formula Weight: 307.97
MOL File: 79670-17-0.mol

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5-BROMO-2-BROMOMETHYL-BENZOIC ACID METHYL ESTER Property

Boiling point:: 349.7±32.0 °C(Predicted)
Density: 1.780±0.06 g/cm3(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2–8 °C
form: liquid
color: Yellow
InChI: InChI=1S/C9H8Br2O2/c1-13-9(12)8-4-7(11)3-2-6(8)5-10/h2-4H,5H2,1H3
InChIKey: UVIJBFVFEGZZLQ-UHFFFAOYSA-N
SMILES: C(OC)(=O)C1=CC(Br)=CC=C1CBr

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Safety

HS Code: 2916310090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

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N-Bromosuccinimide Price

TRC

Product number: M295933
Product name: Methyl5-bromo-2-(bromomethyl)benzoate
Packaging: 25mg
Price: $45
Updated: 2021/12/16

Apolloscientific

Product number: OR400313
Product name: Methyl5-bromo-2-(bromomethyl)benzoate
Packaging: 250mg
Price: $61
Updated: 2021/12/16

AK Scientific

Product number: 2445AC
Product name: Methyl5-bromo-2-(bromomethyl)benzoate
Packaging: 250mg
Price: $61
Updated: 2021/12/16

Matrix Scientific

Product number: 114654
Product name: Methyl 5-bromo-2-(bromomethyl)benzoate
Purity: 97%
Packaging: 250mg
Price: $63
Updated: 2021/12/16

SynQuest Laboratories

Product number: 2723-9-22
Product name: Methyl 5-bromo-2-(bromomethyl)benzoate
Packaging: 250mg
Price: $68
Updated: 2021/12/16

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5-BROMO-2-BROMOMETHYL-BENZOIC ACID METHYL ESTER Chemical Properties,Usage,Production

Uses

Methyl 5-bromo-2-bromotoluate is a carboxylic acid ester derivative and can be used as a pharmaceutical intermediate.

Synthesis

79669-50-4

79670-17-0

Methyl 5-bromo-2-methylbenzoate (1 g, 4.4 mmol) was added to N-bromosuccinimide (0.80 g, 4.4 mmol) and benzoyl peroxide (56 mg, 0.23 mmol) in carbon tetrachloride (20 mL). The reaction mixture was stirred at 85°C for 2 hours. Upon completion of the reaction, the mixture was filtered through a silica gel pad and subsequently concentrated under vacuum to afford the target product methyl 5-bromo-2-bromomethylbenzoate (1.3 g, 97% yield). The structure of the product was confirmed by ESI-MS, m/z: 306.0 [M + H]+.

References

[1] Patent: WO2018/68017, 2018, A1. Location in patent: Page/Page column 144
[2] Organic and Biomolecular Chemistry, 2017, vol. 15, # 48, p. 10172 - 10183
[3] Patent: WO2014/76104, 2014, A1. Location in patent: Page/Page column 63
[4] Patent: CN107474006, 2017, A. Location in patent: Paragraph 0050; 0051; 0053; 0056-0057; 0059; 0062-0063; 0065
[5] Patent: WO2008/23161, 2008, A1. Location in patent: Page/Page column 116-117

5-BROMO-2-BROMOMETHYL-BENZOIC ACID METHYL ESTER Preparation Products And Raw materials

Raw materials

Preparation Products

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5-BROMO-2-BROMOMETHYL-BENZOIC ACID METHYL ESTER Suppliers

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View Lastest Price from 5-BROMO-2-BROMOMETHYL-BENZOIC ACID METHYL ESTER manufacturers

Shaanxi Dideu New Materials Co. Ltd

Product: 2-Fluoro-35-(methylthio)pyridine 79670-17-0
Price: US $0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 1000kg
Release date: 2025-09-29

Shaanxi Dideu New Materials Co. Ltd

Product: 5-BROMO-2-BROMOMETHYL-BENZOIC ACID METHYL ESTER 79670-17-0
Price: US $0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 10000KGS
Release date: 2025-02-23

Career Henan Chemical Co

Product: Methyl 5-bromo-2-(bromomethyl)benzoate 79670-17-0
Price: US $1.00/g
Min. Order: 1g
Purity: 99%
Supply Ability: 10000KGS
Release date: 2020-01-09

79670-17-0, 5-BROMO-2-BROMOMETHYL-BENZOIC ACID METHYL ESTERRelated Search:

5-BROMOPYRIDINE-2-CARBOXYLIC ACID METHYL ESTER Methyl 2,3,5-trifluorobenzoate Methyl 2-chloro-3-iodobenzoate Methyl 2-aMino-4-fluoro-5-Methylbenzoate 2-BROMOMETHYL-4-NITRO-BENZOIC ACID METHYL ESTER ethyl 2-amino-5-cyano-6-fluorobenzoate Methyl 2-broMo-4,6-difluorobenzoate ETHYL 2-CHLORO-6-HYDROXYBENZOATE methyl 2-(bromomethyl)-5-iodobenzoate 2-Bromo-4-fluoro-5-methyl-benzoic acid methyl ester Methyl 2-chloro-4-iodobenzoate ethyl 5-chloro-2-fluoro-4-methoxybenzoate Methyl 2-(bromomethyl)-6-cyanobenzoate Methyl 2-amino-5-chloro-4-methoxybenzoate METHYL 2-BROMOMETHYL-5-FLUORO-BENZOATE 2-broMo-5-iodobenzoic acid Methyl ester ethyl 5-chloro-2-fluoro-4-hydroxybenzoate ethyl 6-chloro-2-fluoro-3-formylbenzoate

5-BROMO-2-BROMOMETHYL-BENZOIC ACID METHYL ESTER

Methyl 5-bromo-2-(bromomethyl)benzoate

Methyl 2-broMoMethyl-5-broMobenzoate

Benzoic acid, 5-bromo-2-(bromomethyl)-, methyl ester

methy 5-bromo-2-bromomethylbenzoate

tert-butyl 3-allyl-3-hydroxyazetidine-97-carboxylate

2-Fluoro-35-(methylthio)pyridine

2-methylthiazole-38-carboxylic acid

79670-17-0