2-BROMOMETHYL-5-METHOXY-BENZOIC ACID METHYL ESTER

Product Name: 2-BROMOMETHYL-5-METHOXY-BENZOIC ACID METHYL ESTER
CAS No.: 788081-99-2
Chemical Name: 2-BROMOMETHYL-5-METHOXY-BENZOIC ACID METHYL ESTER
Synonyms: Methyl 2-(broMoMethyl)-5-Methoxybenzoate;2-BROMOMETHYL-5-METHOXY-BENZOIC ACID METHYL ESTER;Benzoic acid, 2-(bromomethyl)-5-methoxy-, methyl ester
CBNumber: CB52460827
Molecular Formula: C10H11BrO3
Formula Weight: 259.1
MOL File: 788081-99-2.mol

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2-BROMOMETHYL-5-METHOXY-BENZOIC ACID METHYL ESTER Property

Boiling point:: 342.5±32.0 °C(Predicted)
Density: 1.432±0.06 g/cm3(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

AK Scientific

Product number: 2336AC
Product name: Methyl2-(bromomethyl)-5-methoxybenzoate
Packaging: 25g
Price: $691
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: HCH0030254
Product name: BENZOIC ACID, 2-(BROMOMETHYL)-5-METHOXY-, METHYL ESTER
Purity: 95.00%
Packaging: 1G
Price: $1089.05
Updated: 2021/12/16

AK Scientific

Product number: 2336AC
Product name: Methyl2-(bromomethyl)-5-methoxybenzoate
Packaging: 100g
Price: $2051
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: HCH0030254
Product name: BENZOIC ACID, 2-(BROMOMETHYL)-5-METHOXY-, METHYL ESTER
Purity: 95.00%
Packaging: 5G
Price: $2233.89
Updated: 2021/12/16

Ambeed

Product number: A308405
Product name: Methyl2-(bromomethyl)-5-methoxybenzoate
Purity: 98%
Packaging: 250mg
Price: $18
Updated: 2021/12/16

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2-BROMOMETHYL-5-METHOXY-BENZOIC ACID METHYL ESTER Chemical Properties,Usage,Production

Synthesis

73502-03-1

788081-99-2

General procedure for the synthesis of methyl 2-bromomethyl-5-methoxybenzoate from methyl 2-methyl-5-methoxybenzoate: Preparation of intermediate 12: Compound 11 (4.4 g, 24.2 mmol) was dissolved in carbon tetrachloride (80 mL) and N-bromosuccinimide (4.48 g, 24.2 mmol) and benzoyl peroxide (276 mg 1.13 mmol). The reaction mixture was heated to reflux and stirred for 3 hours. After completion of the reaction, the solid insoluble material was removed by filtration and the filter cake was washed with ether. The organic phases were combined, washed with water, dried over anhydrous sodium sulfate and concentrated under reduced pressure to give the target product 12 (6.1 g, 98% yield). Product characterization data: mass spectrum (LCMS) m/z 260 ([M+H]+), 1H NMR (CDCl3) δ 4.50 (2H, s, CH2Br), 3.73 (3H, s, OCH3), 3.88 (3H, s, CO2CH3), 6.86-7.50 (m, 3H, Ar-H).

References

[1] Bioorganic and Medicinal Chemistry Letters, 2010, vol. 20, # 17, p. 5286 - 5289
[2] Patent: WO2009/14637, 2009, A2. Location in patent: Page/Page column 70
[3] Patent: WO2010/54279, 2010, A1. Location in patent: Page/Page column 100
[4] Bioorganic and Medicinal Chemistry Letters, 2010, vol. 20, # 24, p. 7283 - 7287
[5] Patent: WO2006/138549, 2006, A1. Location in patent: Page/Page column 73

2-BROMOMETHYL-5-METHOXY-BENZOIC ACID METHYL ESTER Preparation Products And Raw materials

Raw materials

Preparation Products

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2-BROMOMETHYL-5-METHOXY-BENZOIC ACID METHYL ESTER Suppliers

China 33 India 1 United States 5 Global 39

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788081-99-2, 2-BROMOMETHYL-5-METHOXY-BENZOIC ACID METHYL ESTERRelated Search:

2-BROMOMETHYL-5-METHOXY-BENZOIC ACID METHYL ESTER

Benzoic acid, 2-(bromomethyl)-5-methoxy-, methyl ester

Methyl 2-(broMoMethyl)-5-Methoxybenzoate

788081-99-2