XtalFluor-E
- Product Name
- XtalFluor-E
- CAS No.
- 63517-29-3
- Chemical Name
- XtalFluor-E
- Synonyms
- DiethylaMinodifluorosulfiniuM tetrafluoroborate;1-fluoro-2,4,6-trimethylpyridin-1-ium;(Diethylamino)difluorosulfonium tetrafluoroborate;triethylphosphanium;tetrafluoroboranuide;3,5-dichloro-1-fluoropyridin-1-ium;Xtalfiuor-E;XtalFluor-E;XtalFluor-E(R);1-butylpyridin-1-ium
- CBNumber
- CB52491469
- Molecular Formula
- C4H10BF6NS
- Formula Weight
- 228.9953192
- MOL File
- 63517-29-3.mol
XtalFluor-E Property
- Melting point:
- 84-87℃
- storage temp.
- -20°C
- InChIKey
- YLNKFQWRRIXZPJ-UHFFFAOYSA-N
Safety
- Hazard Codes
- T
- Risk Statements
- 23/24/25-34
- Safety Statements
- 26-36/37/39-45
- RIDADR
- UN 2923 8/PG 3
- WGK Germany
- 3
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P270Do not eat, drink or smoke when using this product.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 719439
- Product name
- XtalFluor-E®
- Packaging
- 5G
- Price
- $52.8
- Updated
- 2024/03/01
- Product number
- 719439
- Product name
- XtalFluor-E®
- Packaging
- 25G
- Price
- $204
- Updated
- 2024/03/01
- Product number
- 719439
- Product name
- XtalFluor-E®
- Packaging
- 250G
- Price
- $1600
- Updated
- 2024/03/01
- Product number
- 719439
- Product name
- XtalFluor-E®
- Packaging
- 1KG
- Price
- $5190
- Updated
- 2024/03/01
- Product number
- X746320
- Product name
- XtalFluor-E
- Packaging
- 10g
- Price
- $220
- Updated
- 2021/12/16
XtalFluor-E Chemical Properties,Usage,Production
Description
XtalFluor-E, [Et2NSF2]BF4, is best known as a useful, versatile and inexpensive commercially available reagent for the deoxyfluorination of carbonyl compounds and alcohols. Although XtalFluor-E is commonly used in combination with an exogenous fluoride source as a deoxofluorinating reagent, it has also been widely employed in other chemical transformations such as dehydration, cyclodehydration, ring expansion, formylation, and proto-functionalization, etc.
Uses
XtalFluor-E can be used as convenient crystalline highly chemoselective deoxofluorination reagent with a broad substrate scopeDeoxofluorination reagent with a better safety profile.
Application
Convenient crystalline highly chemoselective deoxofluorination reagent with a broad substrate scope
Deoxofluorination reagent with a better safety profile, that doesn′t generate corrosive HF which makes it suitable for use in standard borosilicate vessels, and does not react violently with water
Reactant for:
Preparation of fluorodisaccharides
Triisopropylsilanethiol was recently reported by MacMillian and coworkers to be used as an organocatalyst, in tandem with Ir(III) specifically Aldrich product 688096, in photoredox catalysis. This approach directly couples a cyano-containing arene with an allylic sp3 C-H bond.
References
XtalFluor-E: A useful and versatile reagent in organic transformations
(DOI): 10.1016/j.jfluchem.2019.06.006
XtalFluorE effects the C3H sulfenylation of indoles to form di indole sulfides
(DOI): 10.1002/ejoc.202101394
XtalFluor-E Preparation Products And Raw materials
Raw materials
Preparation Products
XtalFluor-E Suppliers
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View Lastest Price from XtalFluor-E manufacturers
- Product
- XtalFluor-E 63517-29-3
- Price
- US $0.00/kg
- Min. Order
- 100g
- Purity
- 97%
- Supply Ability
- 500g,1kg,5kg,10kg,50kg,100kg...
- Release date
- 2019-02-13
- Product
- (Diethylamino)difluorosulfonium Tetrafluoroborate 63517-29-3
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 95%min
- Supply Ability
- 30tons/month
- Release date
- 2023-02-22
- Product
- XtalFluor-E 63517-29-3
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 1Ton
- Release date
- 2022-10-09