XtalFluor-E

Product Name: XtalFluor-E
CAS No.: 63517-29-3
Chemical Name: XtalFluor-E
Synonyms: DiethylaMinodifluorosulfiniuM tetrafluoroborate;1-fluoro-2,4,6-trimethylpyridin-1-ium;(Diethylamino)difluorosulfonium tetrafluoroborate;triethylphosphanium;tetrafluoroboranuide;3,5-dichloro-1-fluoropyridin-1-ium;Xtalfiuor-E;XtalFluor-E;XtalFluor-E(R);1-butylpyridin-1-ium
CBNumber: CB52491469
Molecular Formula: C4H10BF6NS
Formula Weight: 228.9953192
MOL File: 63517-29-3.mol

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XtalFluor-E Property

Melting point:: 84-87℃
storage temp.: -20°C
form: solid
InChIKey: YLNKFQWRRIXZPJ-UHFFFAOYSA-N

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Safety

Hazard Codes: T
Risk Statements: 23/24/25-34
Safety Statements: 26-36/37/39-45
RIDADR: UN 2923 8/PG 3
WGK Germany: 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 719439
Product name: XtalFluor-E®
Packaging: 5G
Price: $52.8
Updated: 2024/03/01

Sigma-Aldrich

Product number: 719439
Product name: XtalFluor-E®
Packaging: 25G
Price: $204
Updated: 2024/03/01

Sigma-Aldrich

Product number: 719439
Product name: XtalFluor-E®
Packaging: 250G
Price: $1600
Updated: 2024/03/01

Sigma-Aldrich

Product number: 719439
Product name: XtalFluor-E®
Packaging: 1KG
Price: $5190
Updated: 2024/03/01

TRC

Product number: X746320
Product name: XtalFluor-E
Packaging: 10g
Price: $220
Updated: 2021/12/16

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XtalFluor-E Chemical Properties,Usage,Production

Description

XtalFluor-E, [Et2NSF2]BF4, is best known as a useful, versatile and inexpensive commercially available reagent for the deoxyfluorination of carbonyl compounds and alcohols. Although XtalFluor-E is commonly used in combination with an exogenous fluoride source as a deoxofluorinating reagent, it has also been widely employed in other chemical transformations such as dehydration, cyclodehydration, ring expansion, formylation, and proto-functionalization, etc.

Uses

XtalFluor-E can be used as convenient crystalline highly chemoselective deoxofluorination reagent with a broad substrate scopeDeoxofluorination reagent with a better safety profile.

Application

Convenient crystalline highly chemoselective deoxofluorination reagent with a broad substrate scope
Deoxofluorination reagent with a better safety profile, that doesn′t generate corrosive HF which makes it suitable for use in standard borosilicate vessels, and does not react violently with water
Reactant for:
Preparation of fluorodisaccharides
Triisopropylsilanethiol was recently reported by MacMillian and coworkers to be used as an organocatalyst, in tandem with Ir(III) specifically Aldrich product 688096, in photoredox catalysis. This approach directly couples a cyano-containing arene with an allylic sp3 C-H bond.

References

XtalFluor-E: A useful and versatile reagent in organic transformations
(DOI): 10.1016/j.jfluchem.2019.06.006
XtalFluorE effects the C3H sulfenylation of indoles to form di indole sulfides
(DOI): 10.1002/ejoc.202101394

XtalFluor-E Preparation Products And Raw materials

Raw materials

Preparation Products

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XtalFluor-E Suppliers

China 106 India 4 United States 6 Global 116

BTC Pharmaceutical CO. Ltd

Tel: 0513-0513-68015397 18862996710
Fax: 0513-68015394
Email: sales12@btcpharm.com
Country: China
ProdList: 694
Advantage: 55

SHANG FLUORO

Tel: 021-65170832 15601903708
Email: qinba_1@163.com
Country: China
ProdList: 374
Advantage: 60

Beijing HwrkChemical Technology Co., Ltd

Tel: 010-89508211 18501085097
Fax: 010-89508210
Email: sales.bj@hwrkchemical.com
Country: China
ProdList: 8418
Advantage: 55

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44689
Advantage: 61

Beijing Mediking Biopharm Co., Ltd

Tel: 010-81769521,89753524,81760121 15901403431
Fax: +86-10-81769652
Email: sales01@mediking.cn
Country: China
ProdList: 614
Advantage: 68

Accela ChemBio Co.,Ltd.

Tel: 021-50795510 4000665055
Fax: 021-50795055
Email: sales@accelachem.com
Country: China
ProdList: 11655
Advantage: 64

Shanghai Sunway Pharmaceutical Technology Co., Ltd

Tel: 021-51613915-820 13611835272
Fax: 021 51613951
Email: mmwang@sunwaypharm.cn
Country: China
ProdList: 9734
Advantage: 57

Shanghai Topbiochem Technology Co., Ltd

Tel: +86-21-60341587
Fax: +86-21-61294319
Email: sales@topbiochem.com
Country: China
ProdList: 6175
Advantage: 58

Shanghai Aladdin Bio-Chem Technology Co.,LTD

Tel: 400-400-6206333 18521732826
Fax: 021-50323701
Email: market@aladdin-e.com
Country: China
ProdList: 25003
Advantage: 65

Shanghai Arbor Chemical Co., Ltd.

Tel: 021-60451682 15021268886
Fax: +86-21-60451682
Email: sales@arborchemical.com
Country: China
ProdList: 855
Advantage: 55

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View Lastest Price from XtalFluor-E manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD

Product: (Diethylamino)difluorosulfonium Tetrafluoroborate 63517-29-3
Price: US $0.00/KG
Min. Order: 1KG
Purity: 95%min
Supply Ability: 30tons/month
Release date: 2023-02-22

Zjartschem

Product: XtalFluor-E 63517-29-3
Price: US $0.00/kg
Min. Order: 100g
Purity: 97%
Supply Ability: 500g,1kg,5kg,10kg,50kg,100kg...
Release date: 2019-02-13

Henan Aochuang Chemical Co.,Ltd.

Product: XtalFluor-E 63517-29-3
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 1Ton
Release date: 2022-10-09

63517-29-3, XtalFluor-ERelated Search:

XtalFluor-M

N,N-Diethyl-S,S-difluorosulfiliminium tetrafluoroborate

XtalFluor-E(R)

DiethylaMinodifluorosulfiniuM tetrafluoroborate

diethylamino(difluoro)sulfanium,tetrafluoroborate

XtalFluor-E

Xtalfiuor-E

(Diethylamino)difluorosulfonium tetrafluoroborate

DAST difluorosulfinium salt

N-(Difluoro-λ4-sulfanylidene)-N-ethyl-ethanaminium tetrafluoroborate

N,N-Diethylamino-S,S-difluorosulfinium tetrafluoroborate

(difluoro-λ-sulfanylidene)diethylazanium

tetrafluoroboranuide

4-acetyl-3-phenylpiperazin-1-ium

iethylamino(difluoro)sulfanium,tetrafluoroborate

1-butylpyridin-1-ium

di-tert-butyl(phenyl)phosphanium

4-(difluoro--sulfanylidene)-4-morpholin-4-ylium

2-(methoxycarbonyl)thiophene-3-diazonium

4-tert-butyl-2,6-dimethyl-1-pyran-1-ylium

2-bromo-1-methylpyridin-1-ium

methyldiphenylsulfanium

1-propyl-2-(1,2,2,2-tetrafluoroethyl)pyridin-1-ium

1-methoxy-4-phenylpyridin-1-ium

1-fluoro-2,4,6-trimethylpyridin-1-ium

2-ethyl-1,3-dimethyl-1H-1,3-benzodiazol-3-ium

1-(dimethyl-2H-1,3-dithiol-2-ylidene)-1-piperidin-1-ylium

1-(cyanomethyl)-2,4,6-trimethylpyridin-1-ium

1,3-dimethyl-2-(trifluoromethyl)-1H-1,3-benzodiazol-3-ium

1,3-bis(propan-2-yl)-4,5-dihydro-1H-imidazol-3-ium

phenyl[2-(trimethylsilyl)ethynyl]iodanium

N,N-dimethylcyclopentaniminium

triethylphosphanium

trimethyldisulfanium

2,4,6-trimethyl-1-phenyl-1-pyridin-1-ylium

2,4,6-trimethyl-1-(prop-2-en-1-yl)pyridin-1-ium

3-(4-bromophenyl)-4-[1,3]thiazolo[3,2-a]pyridin-4-ylium

1-benzyl-2,4,6-trimethylpyridin-1-ium

1-benzyl-2,6-diethyl-4-phenylpyridin-1-ium

1-[chloro(pyrrolidin-1-yl)methylidene]-1-pyrrolidin-1-ylium

1-[(4-methoxyphenyl)methyl]pyridin-1-ium

ethynyl(phenyl)iodanium

ethyldiphenylsulfanium

[(dimethylamino)[(2-oxo-1,2-dihydropyridin-1-yl)oxy]methylidene]dimethylazanium

(dimethylamino)(methyl)oxo(phenyl)--sulfanylium

3,5-dichloro-1-fluoropyridin-1-ium

3,5-bis(trifluoromethyl)benzene-1-diazonium

(4-chlorophenyl)(pentafluoroethyl)iodanium

2-tert-butyl-1,3-dimethyl-1H-1,3-benzodiazol-3-ium

diethylamino(difluoro)sulfanium

TIANFU-CHEM XtalFluor-E

(difluoro-λ?-sulfanylidene)-diethyl-ammonium

DAST difluorosulfinium saltXtalFluor-E

Ethanaminium, N-(difluoro-λ4-sulfanylidene)-N-ethyl-, tetrafluoroborate(1-) (1:1)

(difluoro-lambda4-sulfanylidene)-diethyl-ammonium tetrafluoroborate

63517-29-3

C4H10F2NSBF4

Chemical Synthesis

Fluorination