(S)-1-(2-CHLOROPHENYL)ETHANOL

Product Name: (S)-1-(2-CHLOROPHENYL)ETHANOL
CAS No.: 131864-71-6
Chemical Name: (S)-1-(2-CHLOROPHENYL)ETHANOL
Synonyms: (S)-1-(2-chlorophenyl)ethane;(S)-1-(2-CHLOROPHENYL)ETHANOL;(S)-1-(2-chlorophenyl)ethan-1-ol;(S)-2' chloro-alphaMethylbenzylalcohol;(S)-1-(2-chlorophenyl)ethanol(WXC09851);BenzeneMethanol, 2-chloro-α-Methyl-, (αS)-;(S)-1-(2-Chlorophenyl)ethanol, 98% (colorless) liquid;(S)-1-(2-CHLOROPHENYL)ETHANOL,(S)-1-(2-CHLOROPHENYL)ETHANOL
CBNumber: CB5254091
Molecular Formula: C8H9ClO
Formula Weight: 156.61
MOL File: 131864-71-6.mol

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(S)-1-(2-CHLOROPHENYL)ETHANOL Property

Boiling point:: 231℃
Density: 1.182
Flash point:: 94℃
storage temp.: Sealed in dry,Room Temperature
pka: 14.05±0.20(Predicted)
Appearance: Colorless to light yellow Liquid
Water Solubility: Slightly soluble in water.
InChI: InChI=1/C8H9ClO/c1-6(10)7-4-2-3-5-8(7)9/h2-6,10H,1H3/t6-/s3
InChIKey: DDUBOVLGCYUYFX-ISZMHOAENA-N
SMILES: C1(C=CC=CC=1Cl)[C@H](C)O |&1:7,r|

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Safety

HS Code: 2906290090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

Precautionary statements

P270Do not eat, drink or smoke when using this product.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P330Rinse mouth.

P403Store in a well-ventilated place.

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N-Bromosuccinimide Price

TRC

Product number: C992580
Product name: (S)-1-(2-Chlorophenyl)ethanol
Packaging: 50mg
Price: $45
Updated: 2021/12/16

Ark Pharm

Product number: P000038690
Product name: (S)-1-(2-Chlorophenyl)ethanol
Purity: 98%
Packaging: 1g
Price: $114
Updated: 2021/12/16

ChemScene

Product number: CS-B0639
Product name: Benzenemethanol,2-chloro-α-methyl-,(αS)-
Packaging: 1g
Price: $127
Updated: 2021/12/16

Ark Pharm

Product number: P000038690
Product name: (S)-1-(2-Chlorophenyl)ethanol
Purity: 98%
Packaging: 100mg
Price: $20
Updated: 2021/12/16

Ark Pharm

Product number: P000038690
Product name: (S)-1-(2-Chlorophenyl)ethanol
Purity: 98%
Packaging: 250mg
Price: $38
Updated: 2021/12/16

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(S)-1-(2-CHLOROPHENYL)ETHANOL Chemical Properties,Usage,Production

Uses

It is an intermediate in organic syntheses and used as a pharmaceutical intermediates.

Synthesis

13524-04-4

General procedure for the synthesis of 1-(2-chlorophenyl)ethanol from 1-(2-chlorophenyl)ethanol: Racemic alcohol (1o, 1.0 mmol) was dissolved in 5 mL of dichloromethane at -30 °C, and a compound of formula 2 (where R is I and n=2, and pharmaceutically acceptable salts thereof, 0.01 mol/mol) was added as catalyst. Subsequently, 0.7 equivalents of the methylsilylating agent Formula 5 (where R4 is methyl), 1 equivalent of potassium fluoride, and 80 mg of carboxylic acid-based ion exchange resin were added and the reaction mixture was stirred for 1 hour. Upon completion of the reaction, the mixture was filtered to recover the potassium fluoride and the ion exchange resin, and the filtrate was subsequently concentrated. The residue was purified by fast chromatography (eluent ratio acetone/hexane/triethylamine = 1:5:0.025) to afford the target product chiral alcohol (49% yield, enantiomeric excess value 98% ee, (S)-configuration).

References

[1] Patent: KR2015/114167, 2015, A. Location in patent: Paragraph 0359-0360
[2] Patent: KR2015/114445, 2015, A. Location in patent: Paragraph 0354; 0355; 0356; 0442
[3] Bulletin of the Chemical Society of Japan, 1996, vol. 69, # 4, p. 1079 - 1085
[4] Journal of the Chemical Society - Perkin Transactions 1, 1999, # 16, p. 2397 - 2402
[5] ChemCatChem, 2015, vol. 7, # 24, p. 4016 - 4020

(S)-1-(2-CHLOROPHENYL)ETHANOL Preparation Products And Raw materials

Raw materials

Preparation Products

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(S)-1-(2-CHLOROPHENYL)ETHANOL Suppliers

China 111 Germany 1 India 2 Japan 1 United States 11 Global 126

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View Lastest Price from (S)-1-(2-CHLOROPHENYL)ETHANOL manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

Product: (1S)-1-(2-Chlorophenyl)ethanol 131864-71-6
Price: US $1.10-9.90/kg
Min. Order: 1kg
Purity: 99%min
Supply Ability: 100kg
Release date: 2025-08-18

Career Henan Chemical Co

Product: (S)-1-(2-CHLOROPHENYL)ETHANOL 131864-71-6
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 150KG
Release date: 2019-07-09

131864-71-6, (S)-1-(2-CHLOROPHENYL)ETHANOLRelated Search:

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(S)-1-(2-CHLOROPHENYL)ETHANOL

(S)-2' chloro-alphaMethylbenzylalcohol

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(S)-1-(2-CHLOROPHENYL)ETHANOL,(S)-1-(2-CHLOROPHENYL)ETHANOL

(S)-1-(2-Chlorophenyl)ethanol, 98% (colorless) liquid

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131864-71-6

chiral

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