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2-(tert-Butylamino)ethyl methacrylate

Product Name
2-(tert-Butylamino)ethyl methacrylate
CAS No.
3775-90-4
Chemical Name
2-(tert-Butylamino)ethyl methacrylate
Synonyms
TBAEMA;tert-Butylaminoethyl methacrylate;T-BUTYLAMINOETHYL METHACRYLATE;EM44-T;ageflexfm-4;Ageflex FM-4;butylaminoethylmethacrylate;tert-butylaminoethylmethacrylate;n-tert-butylaminoethylmethacrylate;2-tert.-Butylaminoethylmethacrylat
CBNumber
CB5259142
Molecular Formula
C10H19NO2
Formula Weight
185.26
MOL File
3775-90-4.mol
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2-(tert-Butylamino)ethyl methacrylate Property

Melting point:
100~105℃/12 mm
Boiling point:
82 °C10 mm Hg(lit.)
Density 
0.914 g/mL at 25 °C(lit.)
vapor pressure 
6Pa at 20℃
refractive index 
n20/D 1.442(lit.)
Flash point:
160 °F
solubility 
Slightly soluble in water
form 
clear liquid
pka
8.99±0.10(Predicted)
color 
Colorless to Light yellow
Water Solubility 
18g/L at 25℃
InChIKey
BEWCNXNIQCLWHP-UHFFFAOYSA-N
LogP
2.12 at 20℃
CAS DataBase Reference
3775-90-4(CAS DataBase Reference)
EPA Substance Registry System
2-(tert-Butylamino)ethyl methacrylate (3775-90-4)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/38-43
Safety Statements 
26
RIDADR 
1760
WGK Germany 
1
RTECS 
OZ3500000
TSCA 
TSCA listed
HS Code 
2922.19.9690
HazardClass 
8
PackingGroup 
II
Hazardous Substances Data
3775-90-4(Hazardous Substances Data)
Toxicity
dog,LDLo,intravenous,76uL/kg (0.076mL/kg),Journal of Pharmaceutical Sciences. Vol. 63, Pg. 376, 1974.
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H317May cause an allergic skin reaction

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
444332
Product name
2-(tert-Butylamino)ethyl methacrylate
Purity
97%, contains ~1000 ppm monomethyl ether hydroquinone (MEHQ) as inhibitor
Packaging
100ml
Price
$59.7
Updated
2024/03/01
Sigma-Aldrich
Product number
444332
Product name
2-(tert-Butylamino)ethyl methacrylate
Purity
97%, contains ~1000 ppm monomethyl ether hydroquinone (MEHQ) as inhibitor
Packaging
500ml
Price
$149
Updated
2024/03/01
TCI Chemical
Product number
B6009
Product name
2-(tert-Butylamino)ethyl Methacrylate (stabilized with MEHQ)
Packaging
25ML
Price
$30
Updated
2024/03/01
TCI Chemical
Product number
B6009
Product name
2-(tert-Butylamino)ethyl Methacrylate (stabilized with MEHQ)
Packaging
500ML
Price
$130
Updated
2024/03/01
scipoly
Product number
M-136
Product name
t-Butylaminoethyl methacrylate
Packaging
200g
Price
$36
Updated
2024/07/03
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2-(tert-Butylamino)ethyl methacrylate Chemical Properties,Usage,Production

Uses

Researchers reported the preparation of latex particles from 2-(tert-butylamino)ethyl methacrylate (TBAEMA) using aqueous emulsion polymerization. The preparation of PTBAEMA-functionalized polyolefin fibers via ATRP and an azide-functional initiator has been reported. Poly[2-(tert-butylamino)ethyl methacrylate](PTBAEMA) is a neutral polymer, which is inherently biocidal with potential application in antifouling paints and coatings. The major role of PTBAEMA is to displace Ca2+ and/or Mg2+ ions from the outer membrane of the bacteria, which is accordingly disorganized and finally disrupted. This pendent bulky secondary amine does not need quaternization for antibacterial properties[1-2].

References

[1] Bayramgil, Nursel Pekel. “Synthesis and characterization of new methacrylate-type hydrogels containing 2-tert-butylamino ethyl groups for sorption purposes.” Journal of Applied Polymer Science 109 2 (2008): 1205–1211.
[2] Abdullah M Alswieleh. “Surface modification of pH-responsive poly(2-(tert-butylamino)ethyl methacrylate) brushes grafted on mesoporous silica nanoparticles.” Designed Monomers and Polymers 22 1 (2019): 226–235.

Safety Profile

Poison by intraperitoneal route. See also ESTERS and AMINES. Combustible when exposed to heat or flame. To fight fire, use alcohol foam, water spray or mist, dry chemical. When heated to decomposition it emits toxic fumes of NOx.

2-(tert-Butylamino)ethyl methacrylate Preparation Products And Raw materials

Raw materials

Preparation Products

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2-(tert-Butylamino)ethyl methacrylate Suppliers

TOKYO CHEMICAL INDUSTRY CO., LTD.
Tel
03-36680489
Fax
03-3668-0520
Email
Sales-JP@TCIchemicals.com
Country
Japan
ProdList
28387
Advantage
80
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View Lastest Price from 2-(tert-Butylamino)ethyl methacrylate manufacturers

Qingdao RENAS Polymer Material Co., Ltd.
Product
tert-Butylaminoethyl Methacrylate 3775-90-4
Price
US $0.00/kg
Min. Order
20kg
Purity
99.0%
Supply Ability
10 toms
Release date
2024-04-26
Shaanxi Dideu Medichem Co. Ltd
Product
2-(tert-Butylamino)ethyl methacrylate 3775-90-4
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20t
Release date
2024-07-14
Henan Fengda Chemical Co., Ltd
Product
2-(TERT-BUTYLAMINO)ETHYL METHACRYLATE 3775-90-4
Price
US $100.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-24

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