9-Phenyl-9H,9'H-[3,3']bicarbazolyl
Application- Product Name
- 9-Phenyl-9H,9'H-[3,3']bicarbazolyl
- CAS No.
- 1060735-14-9
- Chemical Name
- 9-Phenyl-9H,9'H-[3,3']bicarbazolyl
- Synonyms
- ]bicarbazolyl;-3,3'-bicarbazoL;9-phenyl-3,3'-bicarbazole;N-Phenyl-3,3'-bicarbazolyl;9-Phenyl-3,3'-bicarbazolyl;9-Phenyl-3,3'-biscarbazole;Phenyl-3,3'-Bi-9H-carbazole;9-Phenyl-3,3'-bi-9H-carbazole;9-Phenyl-3,3’-Bi-9H-carbazole;9-phenyl-9H,9'H-3,3'-dibazole
- CBNumber
- CB52630028
- Molecular Formula
- C30H20N2
- Formula Weight
- 408.49
- MOL File
- 1060735-14-9.mol
9-Phenyl-9H,9'H-[3,3']bicarbazolyl Property
- Boiling point:
- 685.6±37.0 °C(Predicted)
- Density
- 1.23±0.1 g/cm3(Predicted)
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- pka
- 17.10±0.30(Predicted)
- Appearance
- White to off-white Powder
- InChI
- InChI=1S/C30H20N2/c1-2-8-22(9-3-1)32-29-13-7-5-11-24(29)26-19-21(15-17-30(26)32)20-14-16-28-25(18-20)23-10-4-6-12-27(23)31-28/h1-19,31H
- InChIKey
- GKTLHQFSIDFAJH-UHFFFAOYSA-N
- SMILES
- N1(C2=CC=CC=C2)C2=C(C=CC=C2)C2=C1C=CC(C1=CC3C4=C(NC=3C=C1)C=CC=C4)=C2
Safety
- HS Code
- 2933998090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H412Harmful to aquatic life with long lasting effects
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- P336553
- Product name
- 9-Phenyl-9H,9''H-3,3''-bicarbazole
- Packaging
- 500mg
- Price
- $110
- Updated
- 2021/12/16
- Product number
- 3H31-1-H0
- Product name
- 9-Phenyl-3,3'-bicarbazole
- Purity
- 99%
- Packaging
- 1g
- Price
- $80
- Updated
- 2021/12/16
- Product number
- 9597AL
- Product name
- 9-Phenyl-9H,9'H-3,3'-bicarbazole
- Packaging
- 1g
- Price
- $150
- Updated
- 2021/12/16
- Product number
- 3H31-1-H0
- Product name
- 9-Phenyl-3,3'-bicarbazole
- Purity
- 99%
- Packaging
- 5G
- Price
- $232
- Updated
- 2021/12/16
- Product number
- 9597AL
- Product name
- 9-Phenyl-9H,9'H-3,3'-bicarbazole
- Packaging
- 10g
- Price
- $521
- Updated
- 2021/12/16
9-Phenyl-9H,9'H-[3,3']bicarbazolyl Chemical Properties,Usage,Production
Application
9-phenyl-3,3’-bicarbazolyl is the intermediate to synthesis electronic materials, such as OLED.9-phenyl-3,3’-bicarbazolyl is a kind of organic electroluminescent materials to make OLED display screen, and this intermediate can be used in OLED series, such as Thiophene series, Fluorene series, Boronic Acid series and so on.
Synthesis
A mixture of (9-phenyl-9H-carbazol-3-yl)boronic acid (14.2 g,49.5 mmol), 3-bromo-9H-carbazole (11.1 g, 45.0 mmol), Pd(PPh3)4(1.05 g, 0.9 mmol), K2CO3 (2.0 M aqueous solution, 80 mL), toluene(160 mL) and ethanol (80 mL) were stirred under nitrogen at 100 °Cfor 12 h. Until the reaction cooled to room temperature, the grey powder was filtered from the solution and was recrystallized by ethanol to afford 9-Phenyl-3,3'-bicarbazolyl (15.1 g, yield: 82 percent).
References
[1] Patent: CN106631984, 2017, A. Location in patent: Paragraph 0020; 0021
[2] Patent: EP2662368, 2013, A1. Location in patent: Paragraph 0155; 0156
[3] Dyes and Pigments, 2017, vol. 136, p. 54 - 62
[4] Patent: EP1972619, 2008, A1. Location in patent: Page/Page column 262-263
[5] Patent: US2009/247795, 2009, A1. Location in patent: Page/Page column 10
9-Phenyl-9H,9'H-[3,3']bicarbazolyl Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 9-Phenyl-9H,9'H-[3,3']bicarbazolyl manufacturers
- Product
- 3,3'-Bi-9H-carbazole, 9-phenyl- 1060735-14-9
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 98.00%
- Supply Ability
- 150KG /month
- Release date
- 2021-11-17
- Product
- 9-Phenyl-9H,9'H-[3,3']bicarbazolyl 1060735-14-9
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 150KG /month
- Release date
- 2021-12-24
- Product
- 9-phenyl-9H,9'H-3,3'-bicarbazole 1060735-14-9
- Price
- US $200.00-1.00/KG
- Min. Order
- 1KG
- Purity
- 99%, 99.5% Sublimated
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2023-12-30