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(2-NAPHTHYL)METHYLZINC BROMIDE

Product Name
(2-NAPHTHYL)METHYLZINC BROMIDE
CAS No.
152329-44-7
Chemical Name
(2-NAPHTHYL)METHYLZINC BROMIDE
Synonyms
(2-NAPHTHYL)METHYLZINC BROMIDE;(2-naphthylmethyl)zinc bromide solution;(2-Naphthylmethyl)zinc bromide solution 0.5 in THF;(2-Naphthylmethyl)zinc bromide solution 0.5M in THF;(2-Naphthyl)methylzinc bromide 0.5 M in Tetrahydrofuran;(2-NAPHTHYLMETHYL)ZINC BROMIDE, 0.5M SOL UTION IN TETRAHYDROFURAN
CBNumber
CB5266735
Molecular Formula
C11H9BrZn
Formula Weight
286.48
MOL File
152329-44-7.mol
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(2-NAPHTHYL)METHYLZINC BROMIDE Property

Density 
0.978 g/mL at 25 °C
Flash point:
-17 °C
storage temp. 
2-8°C
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Safety

Hazard Codes 
F,Xn
Risk Statements 
14-19-22-36/38-40-36/37-11
Safety Statements 
16-26-33-36-36/37
RIDADR 
UN 2056 3/PG 2
WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H302Harmful if swallowed

H319Causes serious eye irritation

H335May cause respiratory irritation

H351Suspected of causing cancer

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P370+P378In case of fire: Use … for extinction.

P403+P235Store in a well-ventilated place. Keep cool.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
499021
Product name
(2-Naphthylmethyl)zinc bromide solution
Purity
0.5M in THF
Packaging
50ml
Price
$114
Updated
2024/03/01
Rieke Metals
Product number
2099
Product name
(2-Naphthyl)methylzincbromide
Packaging
50mL
Price
$317
Updated
2021/12/16
Rieke Metals
Product number
2099
Product name
(2-Naphthyl)methylzincbromide
Packaging
100mL
Price
$558
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
ING0005767
Product name
(2-NAPHTHYL)METHYLZINC BROMIDE
Purity
95.00%
Packaging
50ML
Price
$2644.95
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
ING0005767
Product name
(2-NAPHTHYL)METHYLZINC BROMIDE
Purity
95.00%
Packaging
100ML
Price
$2899.05
Updated
2021/12/16
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(2-NAPHTHYL)METHYLZINC BROMIDE Chemical Properties,Usage,Production

Uses

(2-Naphthylmethyl)zinc bromide can be used as a reagent for the synthesis of:

  • 4-(5,6-dimethoxy-2-(naphthalen-2-ylmethyl)pyridin-3-yl)benzonitrile from 4-(2-bromo-5,6-dimethoxypyridin-3-yl)benzonitrile using Pd catalyst.
  • (E)-stilbene, (2,2′-[1,4-phenylenedi-(1E)-2,1-ethenediyl]bis[naphthalene]) from 1,4-benzenedicarboxaldehyde in the presence of Pd catalyst and a silylating agent.

General Description

(2-Naphthylmethyl)zinc bromide is an organozinc halide, which is typically used as a reagent in Negishi cross-coupling reactions. In this process, the organozinc halide reacts with organic halides or triflates to form a carbon-carbon bond in the presence of a Pd catalyst.

(2-NAPHTHYL)METHYLZINC BROMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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(2-NAPHTHYL)METHYLZINC BROMIDE Suppliers

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152329-44-7, (2-NAPHTHYL)METHYLZINC BROMIDERelated Search:

4-METHYL-2-PYRIDYLZINC BROMIDE PHENETHYLZINC BROMIDE 4-BROMOBENZYLZINC BROMIDE 1-PHENYLVINYLZINC BROMIDE 2-CHLORO-6-FLUOROBENZYLZINC CHLORIDE 5-ETHOXYCARBONYL-2-METHYLFURANZINC CHLORIDE 2 3 4 5 6-PENTAFLUOROBENZYLZINC CHLORID& 2,6-DICHLOROBENZYLZINC CHLORIDE 2 5-DIFLUOROBENZYLZINC CHLORIDE 5-BROMO-2-METHOXYBENZYLZINC CHLORIDE 4-METHOXYBENZYLZINC CHLORIDE 2-THIAZOLYLZINC BROMIDE 1-PENTYLZINC BROMIDE 3,4-DIMETHOXYBENZYLZINC CHLORIDE 3-BROMOBENZYLZINC BROMIDE Zinc bromide BENZYLZINC BROMIDE (2-NAPHTHYL)METHYLZINC BROMIDE

  • (2-NAPHTHYL)METHYLZINC BROMIDE
  • (2-NAPHTHYLMETHYL)ZINC BROMIDE, 0.5M SOL UTION IN TETRAHYDROFURAN
  • (2-naphthylmethyl)zinc bromide solution
  • (2-Naphthylmethyl)zinc bromide solution 0.5M in THF
  • (2-Naphthyl)methylzinc bromide 0.5 M in Tetrahydrofuran
  • (2-Naphthylmethyl)zinc bromide solution 0.5 in THF
  • 152329-44-7
  • C10H7CH2ZnBr
  • Alkyl
  • Organozinc Halides
  • Organometallic Reagents
  • Reike and Organozinc Reagents
  • Alkyl
  • Organozinc Halides
  • Reike and Organozinc Reagents