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BOC-GLU(OBZL)-OME

Product Name
BOC-GLU(OBZL)-OME
CAS No.
59279-58-2
Chemical Name
BOC-GLU(OBZL)-OME
Synonyms
BOC-GLU(OBZL)-OME;Boc-L-Glu(OBzl)-OMe;(Tert-Butoxy)Carbonyl Glu(OBzl)-OMe;Boc-L-glutamicacid-benzyla-methylester;Boc-L-Glutamic Acid 5-Benzyl 1-Methyl Ester;Boc-L-glutamic acid γ-benzyl α-methyl ester;BOC-L-GLUTAMIC ACID-Y-BENZYL A-METHYL-DIESTER;5-Benzyl 1-Methyl (S)-2-(Boc-amino)pentanedioate;BOC-L-GLUTAMIC ACID-GAMMA-BENZYL ALPHA-METHYL-DIESTER;BOC-L-GLUTAMIC ACID .GAMMA.-BENZYL .ALPHA.-METHYL ESTER
CBNumber
CB5269761
Molecular Formula
C18H25NO6
Formula Weight
351.39
MOL File
59279-58-2.mol
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BOC-GLU(OBZL)-OME Property

Melting point:
38-41 °C
Boiling point:
471.2±40.0 °C(Predicted)
Density 
1.144±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,2-8°C
pka
10.96±0.46(Predicted)
Appearance
White to light yellow Solid
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Activate Scientific
Product number
AS112951
Product name
Boc-Glu(Obzl)-OMe
Purity
95%
Packaging
5G
Price
$149
Updated
2021/12/16
AK Scientific
Product number
8817AB
Product name
Boc-Glu(OBzl)-OMe
Packaging
5g
Price
$182
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
AAA0009071
Product name
(S)-5-BENZYL 1-METHYL-2-(TERT-BUTOXYCARBONYLAMINO)PENTANEDIOATE
Purity
95.00%
Packaging
5MG
Price
$505.26
Updated
2021/12/16
Activate Scientific
Product number
AS112951
Product name
Boc-Glu(Obzl)-OMe
Purity
95%
Packaging
25g
Price
$583
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
AAA0009071
Product name
(S)-5-BENZYL 1-METHYL-2-(TERT-BUTOXYCARBONYLAMINO)PENTANEDIOATE
Purity
95.00%
Packaging
5G
Price
$735
Updated
2021/12/16
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BOC-GLU(OBZL)-OME Chemical Properties,Usage,Production

Synthesis

13574-13-5

74-88-4

59279-58-2

Step 1: Iodomethane (1.01 mL, 16.3 mmol) was slowly added dropwise to a mixed solution of THF (14.82 mmol) and DMF (25 mL) of (2S)-5-(benzyloxy)-2-{[(tert-butoxy)carbonyl]amino}-5-oxopentanoic acid (5.00 g) along with K2CO3 (2.25 g, 16.3 mmol). The reaction mixture was stirred at room temperature for about 3 hours before iodomethane (1.01 mL, 16.3 mmol) was added again. Subsequently, EtOAc was added to the reaction mixture and washed three times with 10% Na2S2O3 solution and then dried with MgSO4. After concentration under reduced pressure to remove the solvent, the crude product was purified by silica gel column chromatography (100:1, followed by 50:1 CHCl3/MeOH) to afford methyl (S)-5-benzyl-2-((tert-butoxycarbonyl)amino)pentanedioate (4.20 g, 12.23 mmol, 82% yield). m/z of C18H25NO6 was detected by ESIMS as 352 (M + H ).

References

[1] Journal of Medicinal Chemistry, 2016, vol. 59, # 5, p. 1899 - 1913
[2] Patent: US2008/318957, 2008, A1. Location in patent: Page/Page column 41-42
[3] Patent: WO2012/109164, 2012, A1. Location in patent: Page/Page column 39
[4] Organic and Biomolecular Chemistry, 2007, vol. 5, # 12, p. 1915 - 1923
[5] Organic Letters, 2016, vol. 18, # 9, p. 1968 - 1971

BOC-GLU(OBZL)-OME Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from BOC-GLU(OBZL)-OME manufacturers

Career Henan Chemical Co
Product
BOC-GLU(OBZL)-OME 59279-58-2
Price
US $1.00/KG
Min. Order
1KG
Purity
99.0%
Supply Ability
100kg
Release date
2020-01-18

59279-58-2, BOC-GLU(OBZL)-OMERelated Search:

L-Glutamic acid Boc-L-Glutamic acid BOC-L-GLUTAMIC ACID DIBENZYL ESTER 4-[T-BUTYLOXYCARBONYL-(GAMMA-BENZYL)-GLUTAMYLOXYMETHYL]-PHENYLACETIC ACID BOC-GLU(OBZL)-ONP Boc-L-glutamic acid γ-benzyl ester N-carboxyanhydride BOC-GLU(OBZL)-OME

  • BOC-GLU(OBZL)-OME
  • BOC-L-GLUTAMIC ACID GAMMA-BENZYL ESTER ALPHA-METHYL ESTER
  • BOC-L-GLUTAMIC ACID-GAMMA-BENZYL ALPHA-METHYL-DIESTER
  • Boc-L-Glutamic Acid 5-Benzyl 1-Methyl Ester
  • Boc-L-Glu(OBzl)-OMe
  • N-ALPHA-T-BUTOXYCARBONYL-L-GLUTAMIC ACID GAMMA-BENZYL ESTER ALPHA-METHYL ESTER
  • Boc-L-glutamic acid γ-benzyl α-methyl ester
  • Boc-L-glutamicacid-benzyla-methylester
  • BOC-L-GLUTAMIC ACID-Y-BENZYL A-METHYL-DIESTER
  • BOC-L-GLUTAMIC ACID .GAMMA.-BENZYL .ALPHA.-METHYL ESTER
  • (S)-5-benzyl 1-methyl 2-(tert-butoxycarbonylamino)pentanedioate
  • Boc-Glu(OBzl)-OMe Boc-L-glutaMic acid γ-benzyl α-Methyl ester
  • (Tert-Butoxy)Carbonyl Glu(OBzl)-OMe
  • 5-benzyl 1-methyl (2S)-2-{[(tert-butoxy)carbonyl]amino}pentanedioate
  • L-Glutamic acid, N-[(1,1-dimethylethoxy)carbonyl]-, 1-methyl 5-(phenylmethyl) ester
  • N-α-(t-Butoxycarbonyl)-L-glutamic acid γ-benzyl ester α-methyl ester
  • 5-Benzyl 1-Methyl (S)-2-(Boc-amino)pentanedioate
  • (S)-Methyl 5-benzyl-2-((tert-butoxycarbonyl)amino)glutarate
  • 59279-58-2
  • C18H25NO6