ChemicalBook > CAS DataBase List > N,N-DIMETHYL-3-FLUOROANILINE

N,N-DIMETHYL-3-FLUOROANILINE

Product Name
N,N-DIMETHYL-3-FLUOROANILINE
CAS No.
2107-43-9
Chemical Name
N,N-DIMETHYL-3-FLUOROANILINE
Synonyms
3-Fluoro-N,N-diMethylaniline;N,N-DIMETHYL-3-FLUOROANILINE;1-(DIMETHYLAMINO)-3-FLUOROBENZENE;1-Fluoro-3-(dimethylamino)benzene;3-Fluoro-N,N-dimethyl-benzenamine;Benzenamine, 3-fluoro-N,N-dimethyl-;Benzenamine, 3-fluoro-2,4-dimethyl-
CBNumber
CB5282218
Molecular Formula
C8H10FN
Formula Weight
139.17
MOL File
2107-43-9.mol
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N,N-DIMETHYL-3-FLUOROANILINE Property

storage temp. 
Sealed in dry,Room Temperature
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Safety

Hazard Codes 
Xi
Risk Statements 
20/21/22-36/37/38
Safety Statements 
26-36/37/39
RIDADR 
1993
Hazard Note 
Irritant
HazardClass 
3
PackingGroup 
HS Code 
2921490090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
F600155
Product name
3-Fluoro-N,N-dimethylaniline
Packaging
100mg
Price
$90
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HCH0000659
Product name
1-(DIMETHYLAMINO)-3-FLUOROBENZENE
Purity
95.00%
Packaging
5MG
Price
$499.65
Updated
2021/12/16
Chemenu
Product number
CM251302
Product name
3-Fluoro-N,N-dimethylaniline
Purity
95+%
Packaging
10g
Price
$677
Updated
2021/12/16
Crysdot
Product number
CD12096731
Product name
3-Fluoro-N,N-dimethylaniline
Purity
97%
Packaging
10g
Price
$717
Updated
2021/12/16
Ambeed
Product number
A199409
Product name
3-Fluoro-N,N-dimethylaniline
Purity
97%
Packaging
250mg
Price
$43
Updated
2021/12/16
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N,N-DIMETHYL-3-FLUOROANILINE Chemical Properties,Usage,Production

Synthesis

124-38-9

1978-37-6

2107-43-9

The general procedure for the synthesis of 3-fluoro-N,N-dimethylaniline from carbon dioxide and 3-fluoro-N-methylaniline was as follows: the methylation of various secondary amines was carried out using the general method Example II. The specific operating conditions were as follows: the substituted aromatic amines (1.0 mmol), [Ru(Triphos)(TMM)] (2.5 mol%), and HNTf2 (5 mol%) were dissolved in THF (2 mL), and reacted at 150 °C under a CO2/H2 (20/60 bar) atmosphere. The reaction time and yield data are detailed in Table II below.The reaction times and corresponding yields for different amine substrates are listed in Table II.

References

[1] Patent: WO2015/753, 2015, A1. Location in patent: Page/Page column 8-9
[2] Chemical Science, 2013, vol. 4, # 5, p. 2127 - 2131
[3] Angewandte Chemie - International Edition, 2013, vol. 52, # 36, p. 9554 - 9557
[4] Angew. Chem., 2013, vol. 125, # 36, p. 9733 - 9736
[5] Patent: EP2821397, 2015, A1. Location in patent: Paragraph 0039; 0041

N,N-DIMETHYL-3-FLUOROANILINE Preparation Products And Raw materials

Raw materials

Preparation Products

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N,N-DIMETHYL-3-FLUOROANILINE Suppliers

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