Raffinose

ChemicalBook > CAS DataBase List > Raffinose

Product Name: Raffinose
CAS No.: 512-69-6
Chemical Name: Raffinose
Synonyms: D-RAFFINOSE;melitriose;Cottonseed oligosaccharides;ffinose;NSC 2025;NSC26414;RAFFINOSE;gossypose;NSC 26414;NSC-26414
CBNumber: CB5290712
Molecular Formula: C18H32O16
Formula Weight: 504.44
MOL File: 512-69-6.mol

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Raffinose Property

Melting point:: 81℃
Boiling point:: 513.84°C (rough estimate)
Density: 1.81
refractive index: 1.6760 (estimate)
storage temp.: 2-8°C
solubility: |DMSO : 100 mg/mL (198.24 mM; Need ultrasonic)
form: Solid
pka: pK1:12.74 (25°C)
color: White to Off-White
Water Solubility: 229.8g/L(25 ºC)
Stability:: Stable. Incompatible with strong oxidizing agents. Combustible.
LogP: -5.104 (est)
CAS DataBase Reference: 512-69-6(CAS DataBase Reference)
EPA Substance Registry System: .alpha.-D-Glucopyranoside, .beta.-D-fructofuranosyl O-.alpha.-D-galactopyranosyl-(1.fwdarw.6)- (512-69-6)

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Safety

Safety Statements: 24/25
HS Code: 29389090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

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N-Bromosuccinimide Price

TRC

Product number: R730105
Product name: D-(+)-Raffinose
Packaging: 5g
Price: $75
Updated: 2021/12/16

Matrix Scientific

Product number: 097922
Product name: D-Raffinose
Purity: 95+%
Packaging: 10g
Price: $255
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: CRB0003054
Product name: RAFFINOSE
Purity: 95.00%
Packaging: 5MG
Price: $499.32
Updated: 2021/12/16

Biorbyt Ltd

Product number: orb105219
Product name: Raffinose
Purity: >98%,Standard References Grade
Packaging: 20mg
Price: $569.5
Updated: 2021/12/16

AK Scientific

Product number: J99531
Product name: D-(+)-Raffinose
Packaging: 5g
Price: $70
Updated: 2021/12/16

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Raffinose Chemical Properties,Usage,Production

Description

Raffinose is also called melitose, melitriose, or gossypose.The term raffinose is derived from the French word raffiner (to refine)，owing to the fact that it was identified first in the products of beet-sugar refining.Raffinose is found in sugar-beets in small quantities and also in cotton seeds.Raffinose is a trisaccharide composed of galactose, fructose, and glucose. It can be found in beans, cabbage, brussels sprouts, broccoli, asparagus, and other plants. In plants, raffinose is generated via binding of galactinol (a sugar alcohol) to sucrose. Raffinose has only 20 % of the sweetening intensity of sucrose.It is much more readily soluble in hot water than sucrose，consequently it remains in syrups and molasses during sugar refining process，especially in those products obtained from the process of extracting sugarfrom molasses.

Chemical Properties

Raffinose is a white crystalline powder. It is odorless and has a sweet taste approximately 10% that of sucrose.

Uses

D-(+)-Raffinose is an oligosaccharide and trisaccharide whose physical structure and chemical properties have been shown to affect the stability and crystallization of amorphous sucrose, helping to increase the shelf-life of sucrose-containing foods.

Definition

ChEBI: Raffinose is a trisaccharide composed of alpha-D-galactopyranose, alpha-D-glucopyranose and beta-D-fructofuranose joined in sequence by 1->6 and 1<->2 glycosidic linkages, respectively. It has a role as a plant metabolite, a Saccharomyces cerevisiae metabolite and a mouse metabolite. It is a raffinose family oligosaccharide and a trisaccharide.

Production Methods

Raffinose occurs naturally in Australian manna, cottonseed meal, and seeds of various food legumes. It can be isolated from beet sugar molasses through sucrose separation, seed-crystallization, and filtration.

Pharmaceutical Applications

Raffinose is a trisaccharide carbohydrate that is used as a bulking agent, blood substitute, stabilizing agent, and water scavenger in freeze-drying where it acts as a stabilizer for freeze-dried formulations. It is also used as a crystallization inhibitor in sucrose solutions.

Safety

Raffinose is a naturally occurring trisaccharide investigated for use in freeze-dried pharmaceutical formulations. It occurs in a number of plants that are consumed widely.

storage

Raffinose is stable under ordinary conditions of use and storage. Excessive heat should be avoided to prevent degradation. Thermal decomposition products are carbon monoxide and carbon dioxide.

Purification Methods

fructo-furanose [17629-30-0 (5H2O), 512-69-6 (anhydrous)] M 594.5, m 8 0o, 80 -82o, +124o (c 10, H2O), [ ] D +105o (c 1 for pentahydrate, H2O), pK 1 12.40, pK 2 13.44, pK 3 13.52. D(+)-Raffinose crystallises from H2O, 90% aqueous EtOH or MeOH as the pentahydrate. The anhydrous sugar has m 132-135o. It has RF 0.8 on TLC (Silica Gel, and 1:3:3 CHCl3/butanone:/MeOH). The undecaacetate has been purified through an alumina column by elution with CHCl3, and recrystallised from EtOH/MeOH/H2O (3:2:5), with m 99-100o, [] D +92.8o (c 5.14, EtOH). [pK : Coccioli & Vicedomini Ann Chim (Rome) 66 269, 275 1976, 1H NMR: Suami et al. Carbohydr Research 26 234 1973, Beilstein 17 III/IV 3801, 17/8 V 403.]

Incompatibilities

Raffinose is incompatible with strong oxidizers.

Regulatory Status

Raffinose is a naturally occurring trisaccharide and is consumed as part of a normal diet.

Raffinose Preparation Products And Raw materials

Raw materials

Preparation Products

SPINOSAD Spinosad D Lactic acid Sucralose

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View Lastest Price from Raffinose manufacturers

Ouhuang Engineering Materials (Hubei) Co., Ltd

Product: Raffinose 512-69-6
Price: US $10.00/kg
Min. Order: 1kg
Purity: 99.7%
Supply Ability: 200000kg
Release date: 2024-04-22

Hebei Yanxi Chemical Co., Ltd.

Product: Raffinose 512-69-6
Price: US $20.00-10.00/kg
Min. Order: 1kg
Purity: 0.99
Supply Ability: 10 tons
Release date: 2023-11-02

WUHAN FORTUNA CHEMICAL CO., LTD

Product: Raffinose 512-69-6
Price: US $0.00/G
Min. Order: 10G
Purity: 98%min
Supply Ability: 30kg/month
Release date: 2023-02-09

512-69-6, RaffinoseRelated Search:

RAFFINOSE UNDECAACETATE,RAFFINOSE UNDECYLACETATE,D-RAFFINOSE UNDECAACETATE,D-(+)-RAFFINOSE UNDECAACETATE D(+)-Raffinose pentahydrate D-GALACTOSE 1-[2-(2-AZIDOETHOXY)ETHOXYETHYL]-2,3,4,6-TETRA-O-ACETATE galactinol -raffinose galactosyltransferase RAFFINOSE, [GALACTOSE-6-3H] RAFFINOSE HYDRATE RAFFINOSE OLEATE RAFFINOSE MYRISTATE YEAST NITROGEN BASE RAFFINOSE W/O DEX, AMM SULFATE, AMINO ACIDS,YNB, RAFFINOSE W/O DEX, AMM SULFATE, AMINO ACIDS DROP OUT BASE AGAR, GALACTOSE, RAFFINOSE DROP OUT BASE RAFFINOSE raffinose permease, E coli SD W/ RAFFINOSE W/O DEXTROSE O-raffinose cross-linked human hemoglobin SD W/ GALACTOSE, RAFFINOSE SDA W/ GALACTOSE, RAFFINOSE YNB w/o Ammonium Sulfate, w/ 2% Raffinose (Powder) PHENOL RED RAFFINOSE BROTH

.beta.-D-fructofuranosylO-.alpha.-D-galactopyranosyl-(1→6)-.alpha.-D-Glucopyranoside

.fwdarw.)-

alpha-d-glucopyranoside,beta-d-fructofuranosylo-alpha-d-galactopyranosyl-(1-6

gossypose

melitriose

raffinose,pure

RAFFINOSE

RAFFINOSE, D-(+)

D-(+)-RAFFINOSE

D-RAFFINOSE

ALPHA-D-GALACTOPYRANOSYL-(1->6)-ALPHA-D-GLUCOPYRANOSYL-(1->2)-BETA-D-FRUCTOFURANOSIDE

ALPHA-D-RAFFINOSE

(3R,4S,5S,6R)-2-[[(2R,3R,4S,5R)-6-[(2S,3S,4R,5R)-3,4-dihydroxy-2,5-bis(hydroxymethyl)oxolan-2-yl]oxy-3,4,5-trihydroxy-oxan-2-yl]methoxy]-6-(hydroxymethyl)oxane-3,4,5-triol

raffinose, pure Raffinose

β-D-Fructofuranosyl 6-O-α-D-galactopyranosyl-α-D-glucopyranoside

RADDEANIN A (RG)

Nittenraffinose

NSC 170228

NSC 2025

Cottonseed oligosaccharides

ffinose

Raffinose D-Raffinose

.alpha.-D-Glucopyranoside, .beta.-D-fructofuranosyl O-.alpha.-D-galactopyranosyl-(1.fwdarw.6)-

RaffinoseSolution,5mg/L,1ml

Raffinose(b)

α-D-Glucopyranoside, β-D-fructofuranosyl O-α-D-galactopyranosyl-(1→6)-

Raffino-oligosaccharide

NSC 26414

NSC26414

NSC-26414

Lumateperone Impurity 17

Raffinose CAS

512-69-6