N'-TERT-BUTYL-N,N-DIMETHYLFORMAMIDINE Property

Boiling point:

137-140 °C(lit.)

Density 

0.815 g/mL at 25 °C(lit.)

refractive index 

n20/D 1.445(lit.)

Flash point:

94 °F

solubility 

Dichloromethane, Ethyl Acetate, Methanol

pka

12.23±0.50(Predicted)

form 

Clear Liquid

Safety

Hazard Codes 

C

Risk Statements 

10-34

Safety Statements 

16-26-27-36/37/39-45

RIDADR 

UN 2920 8/PG 2

WGK Germany 

3

HazardClass 

3.2

PackingGroup 

III

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H226Flammable liquid and vapour

H314Causes severe skin burns and eye damage

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

N'-TERT-BUTYL-N,N-DIMETHYLFORMAMIDINE Chemical Properties,Usage,Production

Chemical Properties

Clear Liquid

Uses

Enamidine intermediates derived from this reagent and carbonyl compounds may be converted into homologated secondary amines, aldehydes or ketones.1 Review of formamidines as precursors to α-amino carbanions.2

General Description

Enamidine intermediates derived from N′-tert-butyl-N,N-dimethylformamidine were converted into homologated secondary amines, aldehydes or ketones. Formamidines were reviewed as precursors to α-amino carbanions.