ChemicalBook > CAS DataBase List > 4-N-HEXYLBENZENEBORONIC ACID

4-N-HEXYLBENZENEBORONIC ACID

Product Name
4-N-HEXYLBENZENEBORONIC ACID
CAS No.
105365-50-2
Chemical Name
4-N-HEXYLBENZENEBORONIC ACID
Synonyms
AKOS BRN-0153;4-Hexylphenylboronicaci;4-hexylphenylboronic acid;4-HEXYLBENZENEBORONIC ACID;4-N-HEXYLPHENYLBORONIC ACID;4-N-HEXYLBENZENEBORONIC ACID;1-Borono-4-(hex-1-yl)benzene;B-(4-Hexylphenyl)boronic acid;4-(Hex-1-yl)benzeneboronic acid;Boronic acid,B-(4-hexylphenyl)-
CBNumber
CB5309126
Molecular Formula
C12H19BO2
Formula Weight
206.09
MOL File
105365-50-2.mol
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4-N-HEXYLBENZENEBORONIC ACID Property

Melting point:
81-84°
Boiling point:
342.6±35.0 °C(Predicted)
Density 
1.00±0.1 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
solubility 
soluble in Methanol
pka
8.73±0.16(Predicted)
form 
Solid
color 
White to Almost white
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Safety

Hazard Codes 
Xi
Hazard Note 
Irritant
HS Code 
2931900090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TCI Chemical
Product number
H1489
Product name
4-Hexylphenylboronic Acid (contains varying amounts of Anhydride)
Packaging
1g
Price
$73
Updated
2025/07/31
TCI Chemical
Product number
H1489
Product name
4-Hexylphenylboronic Acid (contains varying amounts of Anhydride)
Packaging
5g
Price
$241
Updated
2025/07/31
TRC
Product number
H297403
Product name
4-HexylphenylboronicAcid
Packaging
100mg
Price
$45
Updated
2021/12/16
TRC
Product number
H297403
Product name
4-HexylphenylboronicAcid
Packaging
250mg
Price
$50
Updated
2021/12/16
AK Scientific
Product number
X1301
Product name
4-n-Hexylphenylboronicacid
Packaging
1g
Price
$61
Updated
2021/12/16
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4-N-HEXYLBENZENEBORONIC ACID Chemical Properties,Usage,Production

Synthesis

23703-22-2

105365-50-2

A n-hexane solution of n-butyllithium (1.67 M, 131 mL, 218 mmol) was slowly added dropwise to a solution of anhydrous THF (300 mL) of 1-bromo-4-hexylbenzene (50.0 g, 207 mmol) under nitrogen protection, keeping the reaction temperature at -75 °C. After the dropwise addition was completed, stirring of the reaction mixture was continued for 2 hours. Subsequently, trimethoxyborane (64.6 g, 622 mmol) was slowly added dropwise to the reaction system, and after completion of the dropwise addition, stirring was continued for 2 hours. At the end of the reaction, 1N dilute hydrochloric acid (300 mL) was slowly added to the reaction system and stirred for 30 minutes. The reaction mixture was extracted with ethyl acetate, the organic layer was washed with saturated aqueous sodium chloride solution, dried over anhydrous sodium sulfate, and concentrated under reduced pressure to give the intermediate 4-N-hexylphenylboronic acid (42.5 g, 99% yield) as a colorless solid.

References

[1] Patent: EP2695882, 2014, A1. Location in patent: Paragraph 0377
[2] Organic Letters, 2006, vol. 8, # 18, p. 4071 - 4074
[3] Patent: US2011/281822, 2011, A1. Location in patent: Page/Page column 7-8

4-N-HEXYLBENZENEBORONIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

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4-N-HEXYLBENZENEBORONIC ACID Suppliers

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View Lastest Price from 4-N-HEXYLBENZENEBORONIC ACID manufacturers

Career Henan Chemical Co
Product
4-N-HEXYLBENZENEBORONIC ACID 105365-50-2
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100KG
Release date
2019-12-25

105365-50-2, 4-N-HEXYLBENZENEBORONIC ACIDRelated Search:

P-(4-PROPYLCYCLOHEXYL)PHENYLBORONIC ACID 4-N-BUTYLCYCLOHEXYL PHENYLBORIC ACID 4-N-HEPTYLBENZENE BORONIC ACID ACETIC ACID 4,5-DIACETOXY-6-ACETOXYMETHYL-2-[4-(4,4,5,5-TETRAMETHYL-[1,3,2]DIOXABOROLAN-2-YL)-PHENYL]-TETRAHYDRO-PYRAN-3-YL ESTER 3,4,5-TRIS-BENZYLOXY-2-BENZYLOXYMETHYL-6-[4-(4,4,5,5-TETRAMETHYL-[1,3,2]DIOXABOROLAN-2-YL)-PHENYL]-TETRAHYDRO-PYRAN 2,3-DIFLUORO-4-HEPTYLPHENYL BORONIC ACID 4-(N-OCTYL)BENZENEBORONIC ACID 4-Nonylphenylboronic acid 2,3-DIFLUORO-4-HEXYLPHENYL BORONIC ACID 4-N-HEXYLBENZENEBORONIC ACID [4-(TRANS-4-N-PROPYLCYCLOHEXYL)PHENYL]BORONIC ACID 4-(4-PENTYLCYCLOHEXYL)PHENYLBORONIC ACID AKOS BRN-1188 4-Cyclohexylbenzeneboronic acid

  • 4-N-HEXYLBENZENEBORONIC ACID
  • 4-N-HEXYLPHENYLBORONIC ACID
  • AKOS BRN-0153
  • 4-hexylphenylboronic acid
  • 4-(Hex-1-yl)benzeneboronic acid
  • 1-Borono-4-(hex-1-yl)benzene
  • 4-HEXYLBENZENEBORONIC ACID
  • Boronic acid,B-(4-hexylphenyl)-
  • 4-Hexylphenylboronic Acid (contains varying amounts of Anhydride)
  • 4-Hexylphenylboronicaci
  • B-(4-Hexylphenyl)boronic acid
  • 105365-50-2
  • C12H19BO2