(IODOMETHYL)TRIMETHYLSILANE

Product Name: (IODOMETHYL)TRIMETHYLSILANE
CAS No.: 4206-67-1
Chemical Name: (IODOMETHYL)TRIMETHYLSILANE
Synonyms: DK779;DK296;DKFELEX0199;(Lodomethyl)trimethylsilane;(IODOMETHYL)TRIMETHYLSILANE;Trimethyl(iodomethyl)silane;(Trimethylsilyl)iodomethane;(TRIMETHYLSILYL)METHYL IODIDE;(Iodomethyl)trimethylsilane>Silane, (iodomethyl)trimethyl-
CBNumber: CB5340291
Molecular Formula: C4H11ISi
Formula Weight: 214.12
MOL File: 4206-67-1.mol

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(IODOMETHYL)TRIMETHYLSILANE Property

Melting point:: 137-141 °C
Boiling point:: 139-141 °C (lit.)
Density: 1.443 g/mL at 25 °C (lit.)
refractive index: n20/D 1.491(lit.)
Flash point:: 89 °F
storage temp.: Keep in dark place,Inert atmosphere,2-8°C
solubility: Difficult to mix.
form: clear liquid
color: Colorless to Light orange to Yellow
Specific Gravity: 1.441
Hydrolytic Sensitivity: 3: reacts with aqueous base
Sensitive: Light Sensitive
BRN: 1731485
InChIKey: VZNYXGQMDSRJAL-UHFFFAOYSA-N
CAS DataBase Reference: 4206-67-1(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 10-36/37/38
Safety Statements: 26-36-24/25-16
RIDADR: UN 2924 3/PG 3
WGK Germany: 3
F: 8-10-21
TSCA: No
HazardClass: 3.2
PackingGroup: III
HS Code: 29319090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H226Flammable liquid and vapour

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 57903
Product name: (Iodomethyl)trimethylsilane
Purity: ≥99.0% (GC)
Packaging: 5ml
Price: $123
Updated: 2024/03/01

Sigma-Aldrich

Product number: 57903
Product name: (Iodomethyl)trimethylsilane
Purity: ≥99.0% (GC)
Packaging: 25ml
Price: $402
Updated: 2024/03/01

TCI Chemical

Product number: I0449
Product name: (Iodomethyl)trimethylsilane
Purity: >97.0%(GC)
Packaging: 10g
Price: $91
Updated: 2024/03/01

Alfa Aesar

Product number: A15120
Product name: (Iodomethyl)trimethylsilane, 99%
Packaging: 10g
Price: $103
Updated: 2024/03/01

Alfa Aesar

Product number: A15120
Product name: (Iodomethyl)trimethylsilane, 99%
Packaging: 50g
Price: $308.65
Updated: 2024/03/01

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(IODOMETHYL)TRIMETHYLSILANE Chemical Properties,Usage,Production

Chemical Properties

CLEAR YELLOW TO BROWN LIQUID

Physical properties

bp 140–142 °C; d 1.442 g cm?3.

Uses

(Iodomethyl)trimethylsilane is used for the N-alkylation of amides, in a reaction sequence to prepare unstabilized ylides for [2+3]-cycloadditions. It can react with acetoacetic acid ethyl ester to get 3-trimethylsilanyl-proπonic acid ethyl ester.

Uses

(Iodomethyl)trimethylsilane can be used as electrophile for the preparation of allylsilanes and propargylsilanes; forms carbon alkylation adducts useful for alkene synthesis; alkylation adducts are frequently a source of fluorideinduced reactive intermediates, forming nitrogen and sulfur alkylation adducts that function as ylide precursors; readily undergoes metal–halogen exchange to generate a reagent for Peterson methylenation.

Purification Methods

If slightly violet in colour, wash it with aqueous 1% sodium metabisulfite, H2O, dry (Na2SO4) it and fractionally distil it at 760mm. [Whitmore & Sommer J Am Chem Soc 68 481 1946, Beilstein 4 IV 3878.]

(IODOMETHYL)TRIMETHYLSILANE Preparation Products And Raw materials

Raw materials

Preparation Products

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(IODOMETHYL)TRIMETHYLSILANE Suppliers

Americas 1 Belgium 1 China 122 Europe 2 Germany 3 India 2 Japan 2 Singapore 1 Switzerland 1 United Kingdom 4 United States 13 Global 152

Acros Organics

Tel: --
Fax: --
Email: info@acros.com
Country: Belgium
ProdList: 6772
Advantage: 81

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View Lastest Price from (IODOMETHYL)TRIMETHYLSILANE manufacturers

Shaanxi Dideu Medichem Co. Ltd

Product: (Iodomethyl)trimethylsilane 4206-67-1
Price: US $1.00-35.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 15000KG
Release date: 2024-08-08

Zhuozhou Wenxi import and Export Co., Ltd

Product: (Iodomethyl)trimethylsilane 4206-67-1
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-07-10

Zhuozhou Wenxi import and Export Co., Ltd

Product: (Iodomethyl)trimethylsilane 4206-67-1
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-07-09

4206-67-1, (IODOMETHYL)TRIMETHYLSILANERelated Search:

Clotrimazole BIS(TRIMETHYLSILYL) SULFIDE Iodomethane (IODOMETHYL)TRIMETHYLSILANE TRIMETHYLSILANE IODOMETHYLTRIMETHYLSILANE = (IODOMETHYL)-TRIMETHYLSILANE Tetramethylsilane 3-IODO-3-TRIMETHYLSILANYL-PROP-2-EN-1-OL

(IODOMETHYL)TRIMETHYLSILANE

Silane, (iodomethyl)trimethyl-

(IODOMETHYL)TRIMETHYLSILANE 99%

(TRIMETHYLSILYL)METHYL IODIDE

(Trimethylsilyl)iodomethane

Trimethyl(iodomethyl)silane

(Iodomethyl)trimethylsilane,99%

(IodoMethyl)triMethylsilane, 99% 5ML

(Iodomethyl)trimethylsilane >=99.0% (GC)

(Lodomethyl)trimethylsilane

(Iodomethyl)trimethylsilane&gt

DK779

DK296

DKFELEX0199

4206-67-1

C4H11ISi

CH33SICH2I

Silicon Compounds (for Synthesis)

Si-(C)4 Compounds

Si (Classes of Silicon Compounds)

Others

Organosilicon

Organometallic Reagents

Synthetic Organic Chemistry

Chemical Synthesis

Organometallic Reagents

Organosilicon

Others

Si (Classes of Silicon Compounds)

Si-(C)4 Compounds

Silicon Compounds (for Synthesis)