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(S)-2-HYDROXYBUTYRIC ACID

Product Name
(S)-2-HYDROXYBUTYRIC ACID
CAS No.
3347-90-8
Chemical Name
(S)-2-HYDROXYBUTYRIC ACID
Synonyms
(S)-2-HYDROXYBUTYRIC;(S)-2-Hydroxybutyrate;Pemafibrate Impurity 4;L-2-HYDROXYBUTYRIC ACID;Lactic acid impurity 72;(S)-2-HYDROXYBUTYRIC ACID;(2S)-2-Hydroxybutyric acid;(S)-2-Hydroxybutanoic acid;(2S)-2-hydroxybutanoic acid;(S)-2-hydroxybutanoatic acid
CBNumber
CB5341672
Molecular Formula
C4H8O3
Formula Weight
104.1
MOL File
3347-90-8.mol
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(S)-2-HYDROXYBUTYRIC ACID Property

Melting point:
50-54 °C
Boiling point:
238℃
Density 
1.195
Flash point:
112℃
storage temp. 
2-8°C
pka
3.83±0.10(Predicted)
form 
solid
color 
Pale yellow
BRN 
1720940
InChI
InChI=1S/C4H8O3/c1-2-3(5)4(6)7/h3,5H,2H2,1H3,(H,6,7)/t3-/m0/s1
InChIKey
AFENDNXGAFYKQO-VKHMYHEASA-N
SMILES
C(O)(=O)[C@@H](O)CC
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Safety

Hazard Codes 
Xi
Risk Statements 
37/38-41
Safety Statements 
26-37/39
WGK Germany 
2
3-10
HS Code 
2918199890
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H315Causes skin irritation

H318Causes serious eye damage

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
54918
Product name
(S)-2-Hydroxybutyric acid
Purity
for chiral derivatization, ≥97.0%
Packaging
1G
Price
$358.15
Updated
2025/07/31
TRC
Product number
H956328
Product name
(S)-2-HydroxybutanoicAcid
Packaging
5g
Price
$550
Updated
2021/12/16
AK Scientific
Product number
E769
Product name
S-2-Hydroxybutyricacid
Packaging
25g
Price
$901
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0005109
Product name
(S)-2-HYDROXYBUTYRATE
Purity
95.00%
Packaging
1KG
Price
$9944.55
Updated
2021/12/16
ACHEMBLOCK
Product number
P38746
Product name
(S)-2-Hydroxy-butanoicacid
Purity
95%
Packaging
500MG
Price
$95
Updated
2021/12/16
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(S)-2-HYDROXYBUTYRIC ACID Chemical Properties,Usage,Production

Chemical Properties

Off-white crystals or pale liquid

Uses

(S)-2-Hydroxybutanoic acid is used in method for preparing Cationic Electrodeposition coating compounds.

Definition

ChEBI: An optically active form of 2-hydroxybutyric acid having (S)-configuration.

Synthesis

1492-24-6

3347-90-8

The general procedure for the synthesis of (S)-2-hydroxybutyric acid from L-2-aminobutyric acid was as follows: (S)-2-aminobutyric acid (20.0 g, 194 mmol) was dissolved in 1N sulfuric acid solution (228 mL). Aqueous sodium nitrite solution (26.8 g, 338 mmol, 68 mL) was slowly added dropwise at -5 °C, and stirring of the reaction mixture was continued for 0.5 h after completion of the dropwise addition. Subsequently, the reaction mixture was warmed to room temperature and stirred continuously for 2 hours. Upon completion of the reaction, the mixture was cooled to 0 °C and sulfuric acid was added to adjust the pH to 1. After adjusting the pH, the mixture was stirred for 12 hours at room temperature. Next, sodium chloride (120 g) and methyl tert-butyl ether (MTBE, 120 mL) were added to the reaction mixture and stirred for 30 min before MTBE extraction. The organic layer was washed with saturated brine, dried over anhydrous sodium sulfate, and concentrated under reduced pressure to afford (S)-2-hydroxybutyric acid (13.8 g, 69% yield) as a pale yellow solid. The product was characterized by 1H NMR (400 MHz, CDCl3), δ 1.00 (t, J=7.6 Hz, 3H), 1.68-1.79 (m, 1H), 1.84-1.93 (m, 1H), 4.24 (dd, J=6.8,4.4 Hz, 1H).

IC 50

Human Endogenous Metabolite

References

[1] Patent: US2016/60203, 2016, A1. Location in patent: Paragraph 0082; 0083
[2] Journal of Organic Chemistry, 1993, vol. 58, # 18, p. 4805 - 4808
[3] Journal of the American Chemical Society, 1951, vol. 73, p. 1336
[4] Journal of Biological Chemistry, 1941, vol. 141, p. 404
[5] Biochemische Zeitschrift, 1937, vol. 293, p. 410,412

(S)-2-HYDROXYBUTYRIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

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(S)-2-HYDROXYBUTYRIC ACID Suppliers

Tianjin Zhangxin Pharmaceutical Technology Co., Ltd
Tel
022-28219283 18522293726
Email
linda_zxyy@163.com
Country
China
ProdList
41
Advantage
58
Taizhou Changyuan Chemical Technology Co., Ltd.
Tel
15005869072
Email
tzcyhxkj@163.com
Country
China
ProdList
507
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58
Henan Aosman Biotechnology Co., LTD
Tel
0371-0371-61318675 17719817155
Fax
0371-61318675
Email
sales@xlinebio.com
Country
China
ProdList
2857
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58
Beijing HwrkChemical Technology Co., Ltd
Tel
18515581800 18501085097
Fax
010-89508210
Email
sales.bj@hwrkchemical.com
Country
China
ProdList
9400
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55
Energy Chemical
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021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44801
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Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Country
China
ProdList
18207
Advantage
66
Jia Xing Isenchem Co.,Ltd
Tel
0573-85285100 18627885956
Fax
0573-85285100
Email
isenchem@163.com
Country
China
ProdList
9310
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66
Nanjing Chemlin Chemical Co., Ltd
Tel
025-83697070
Fax
+86-25-83453306
Email
info@chemlin.com.cn
Country
China
ProdList
15883
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64
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42934
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64
Shandong Xiya Chemical Co., Ltd
Tel
4009903999 13355009207
Fax
0539-6365991
Email
3007715519@qq.com
Country
China
ProdList
18729
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57
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View Lastest Price from (S)-2-HYDROXYBUTYRIC ACID manufacturers

Shenzhen Nexcon Pharmatechs Ltd.
Product
(S)-2-HYDROXYBUTYRIC ACID 3347-90-8
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
95%
Supply Ability
2000
Release date
2025-09-25
Shaanxi Dideu New Materials Co. Ltd
Product
(S)-2-HYDROXYBUTYRIC ACID 3347-90-8
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
10000KGS
Release date
2025-03-15
Shaanxi Dideu Medichem Co. Ltd
Product
(S)-2-HYDROXYBUTYRIC ACID 3347-90-8
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20T
Release date
2024-07-18

3347-90-8, (S)-2-HYDROXYBUTYRIC ACIDRelated Search:


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  • (S)-2-HYDROXYBUTYRIC ACID
  • (S)-ALPHA-HYDROXYBUTYRIC ACID
  • (S)-2-Hydroxybutyrate
  • (S)-2-HYDROXYBUTYRIC ACID, 98+%
  • (2S)-2-Hydroxybutyric acid
  • (S)-2-Hydroxybutanoic acid
  • (S)-2-HYDROXYBUTYRIC
  • (2S)-2-hydroxybutanoic acid
  • (S)-(+)-α-hydroxybutyric acid
  • (S)-2-hydroxybutanoatic acid
  • Butanoic acid,2-hydroxy-, (2S)-
  • (S)-2-Hydroxybutyric acid≥ 96% (Titration)
  • Nucleosil(R) C18 HPLC Column
  • (S)-2-hydroxybutyric acid, L-2-Hydroxybutyric acid
  • Lactic acid impurity 72
  • Pemafibrate Impurity 4
  • (<i>S</i>)-2-Hydroxybutyric acid
  • 3347-90-8