1,10-Phenanthrolin-5-amine
- Product Name
- 1,10-Phenanthrolin-5-amine
- CAS No.
- 54258-41-2
- Chemical Name
- 1,10-Phenanthrolin-5-amine
- Synonyms
- 5-AMinophenanthroline;5-AMino-o-phenanthroline;10-Phenanthrolin-5-amine;1,1-Phenanthrolin-5-amine;5-amino-1,10-phenanroline;Amine-1,10-Phenanthrolin;1,10-phenanthrolin-5-amine;Amino-1,1,0-phenanthroline;5-Amine-1,1-phenanthroline;5-AMine-1,10-phenanthroline
- CBNumber
- CB5363511
- Molecular Formula
- C12H9N3
- Formula Weight
- 195.22
- MOL File
- 54258-41-2.mol
1,10-Phenanthrolin-5-amine Property
- Melting point:
- 254-258 °C (lit.)
- Boiling point:
- 197-198 °C
- Density
- 1.333±0.06 g/cm3(Predicted)
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- solubility
- DMSO (Sparingly), Methanol (Sparingly)
- form
- Solid
- pka
- 5.20±0.10(Predicted)
- color
- Yellow to Orange
- InChIKey
- DKPSSMOJHLISJI-UHFFFAOYSA-N
Safety
- Hazard Codes
- Xn
- Risk Statements
- 22-41-43
- Safety Statements
- 26-36/37/39
- WGK Germany
- 3
- HS Code
- 29339900
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H302Harmful if swallowed
H317May cause an allergic skin reaction
H318Causes serious eye damage
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
N-Bromosuccinimide Price
- Product number
- 631507
- Product name
- 1,10-Phenanthrolin-5-amine
- Purity
- 97%
- Packaging
- 1g
- Price
- $187
- Updated
- 2025/07/31
- Product number
- 631507
- Product name
- 1,10-Phenanthrolin-5-amine
- Purity
- 97%
- Packaging
- 5g
- Price
- $590
- Updated
- 2025/07/31
- Product number
- A2977
- Product name
- 5-Amino-1,10-phenanthroline
- Purity
- >98.0%(GC)
- Packaging
- 1g
- Price
- $90
- Updated
- 2025/07/31
- Product number
- P295030
- Product name
- 1,10-Phenanthrolin-5-amine
- Packaging
- 5g
- Price
- $150
- Updated
- 2021/12/16
- Product number
- 019356
- Product name
- 1,10-Phenanthrolin-5-amine
- Packaging
- 5g
- Price
- $460
- Updated
- 2021/12/16
1,10-Phenanthrolin-5-amine Chemical Properties,Usage,Production
Chemical Properties
Brown to Orange Solid
Uses
1,10-Phenanthrolin-5-amine can be used in the synthesis of bis-[1,10]phenanthrolin-5-yl-pyromellitic diimide (Bphen-PMD), which can find applications in organic light-emitting devices.
Uses
1,10-Phenanthrolin-5-amine is a potential fluorescent label for DNA detection. 1,10-Phenanthrolin-5-amine is used as a mediator for glucose oxidase for development of biosensors and biofuel cells
Synthesis
4199-88-6
54258-41-2
4) Add 0.64 g (6.0 mmol) of 10% palladium-carbon catalyst, 4.85 g of 80% (mass fraction) hydrazine hydrate, and 20.0 mL of anhydrous ethanol to a 250 mL three-neck flask. A reflux condenser was installed and the two remaining ports were sealed with glass stoppers. The device was placed on a DF-101S heated thermostatic magnetic stirrer with the oil bath temperature set to 72 °C and stirring was initiated. Subsequently, 2.03 g (9 mmol) of 5-nitro-1,10-phenanthroline was added to the flask, followed by 40 mL of anhydrous ethanol to ensure complete dissolution (total ethanol volume of 60 mL). The dissolved 5-nitro-1,10-phenanthroline solution was quickly poured into a three-necked flask after the oil bath temperature reached 72 °C. After the reaction lasted for 10 hours, the heating was stopped and left for about 1 hour to ensure complete dissolution of 5-nitro-1,10-phenanthroline. The oil bath was again heated to 60°C. If any precipitate redissolved in the system, the three-necked flask was immediately removed, the solution was poured into a thermal filter, and the residue was washed with anhydrous ethanol about five times. The filtrate was collected and concentrated using a rotary evaporator to remove the solvent, yielding a yellow solid. The solid was dried in a vacuum oven at 60 °C for 12 hours. Finally, the product was recrystallized with anhydrous ethanol, filtered and dried under vacuum at 60 °C for 12 h to give 1.28 g of yellow-brown solid powder, 5-amino-1,10-phenanthroline (Phen-NH2), in 72.9% yield.
References
[1] Chemical Communications, 2006, # 43, p. 4539 - 4541
[2] European Journal of Inorganic Chemistry, 2008, # 10, p. 1559 - 1564
[3] Tetrahedron Letters, 2007, vol. 48, # 18, p. 3135 - 3139
[4] Journal of the American Chemical Society, 2003, vol. 125, # 40, p. 12062 - 12063
[5] Patent: US2007/276104, 2007, A1
1,10-Phenanthrolin-5-amine Preparation Products And Raw materials
Raw materials
Preparation Products
1,10-Phenanthrolin-5-amine Suppliers
- Tel
- 800-4238616
- Fax
- +1-888-520-1075 / +1-503-283-1987
- sales@tciamerica.com
- Country
- Americas
- ProdList
- 23653
- Advantage
- 75
View Lastest Price from 1,10-Phenanthrolin-5-amine manufacturers
- Product
- 5-Amino-1,10-phenanthroline 54258-41-2
- Price
- US $37.00-577.00/g
- Min. Order
- 1g
- Purity
- 0.98
- Supply Ability
- 10kg
- Release date
- 2023-10-17
- Product
- 1,10-Phenanthrolin-5-amine 97% 54258-41-2
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-06-27
- Product
- 10-Phenanthrolin-5-amine 54258-41-2
- Price
- US $1.00/g
- Min. Order
- 1g
- Purity
- 99%
- Supply Ability
- 1000KGS
- Release date
- 2019-12-20