4'-CHLOROPIVALOANILIDE

Product Name: 4'-CHLOROPIVALOANILIDE
CAS No.: 65854-91-3
Chemical Name: 4'-CHLOROPIVALOANILIDE
Synonyms: 4-Chloropivalamide;4-Chloropivalanilide;4'-CHLOROPIVALOANILIDE;N-Pivaloyl-p-chlorophenyl;4'-Chloropivaloanilide>4-CHLORO-N-PIVALOYLANILINE;N-PIVALOYL-P-CHLOROANILINE;N-(4-chlorophenyl)pivalaMide;N-(4-CHLOROPHENYL)PIVALOYLAMIDE;4''-CHLOROPIVALOANILIDE,98.0%+(GC)
CBNumber: CB5365717
Molecular Formula: C11H14ClNO
Formula Weight: 211.69
MOL File: 65854-91-3.mol

More

Less

4'-CHLOROPIVALOANILIDE Property

Melting point:: 152 °C
Boiling point:: 352.1±25.0 °C(Predicted)
Density: 1.150±0.06 g/cm3(Predicted)
storage temp.: 2-8°C
pka: 14.25±0.70(Predicted)

More

Less

Safety

HS Code: 2921420090

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P501Dispose of contents/container to..…

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: S902640
Product name: 4'-CHLORO-2,2-DIMETHYLPROPIONANILIDE
Purity: Aldrich<sup>CPR</sup>
Packaging: 1 unit
Price: $30.7
Updated: 2025/07/31

Sigma-Aldrich

Product number: S902640
Product name: 4'-CHLORO-2,2-DIMETHYLPROPIONANILIDE
Purity: Aldrich
Packaging: 50mg
Price: $29.8
Updated: 2024/03/01

TCI Chemical

Product number: C2099
Product name: 4'-Chloropivaloanilide
Purity: >98.0%(GC)
Packaging: 25g
Price: $31
Updated: 2025/07/31

TCI Chemical

Product number: C2099
Product name: 4'-Chloropivaloanilide
Purity: >98.0%(GC)
Packaging: 250g
Price: $312
Updated: 2025/07/31

AK Scientific

Product number: J56537
Product name: 4'-Chloropivaloanilide
Packaging: 5g
Price: $49
Updated: 2021/12/16

More

Less

4'-CHLOROPIVALOANILIDE Chemical Properties,Usage,Production

Synthesis

3282-30-2

106-47-8

65854-91-3

The general procedure for synthesizing N-pivaloyl-p-chloroaniline from pivaloyl chloride and 4-chloroaniline was as follows: referring to Example 2, 4-chloroaniline (113 kg, 886 mol), deionized water (565 L), and sodium bicarbonate (89.3 kg, 1.2 eq.) were added to ethyl acetate (1695 L). Pivaloyl chloride (112 kg, 1.05 eq.) was slowly added dropwise at 15°C or lower. After the dropwise addition was completed, the reaction solution was stirred at about 25°C for 2 hours. Upon completion of the reaction, the organic and aqueous layers were separated. The organic layer was washed twice with deionized water (848 L x 2) and then concentrated under reduced pressure to about 600 L. To the concentrate was added ethylcyclohexane (848 L) and again concentrated under reduced pressure to about 600 L. The residue was cooled to about 5 °C and stirred for 1 h to promote crystallization. The precipitated crystals were collected by filtration and dried under reduced pressure to afford N-pivaloyl-p-chloroaniline (187 kg, 99.7% yield).

References

[1] Patent: WO2005/121133, 2005, A1. Location in patent: Page/Page column 30-31
[2] Patent: US2009/247766, 2009, A1. Location in patent: Page/Page column 27
[3] Patent: WO2015/118515, 2015, A1. Location in patent: Page/Page column 9
[4] Journal of Organic Chemistry, 1998, vol. 63, # 23, p. 8536 - 8543
[5] Patent: CN105801442, 2016, A. Location in patent: Paragraph 0006; 0018; 0022; 0026; 0030

4'-CHLOROPIVALOANILIDE Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

4'-CHLOROPIVALOANILIDE Suppliers

Americas 1 China 54 Czech Republic 2 Europe 1 Germany 4 India 4 Japan 3 Spain 1 Sweden 1 United Kingdom 6 United States 23 Global 100

J & K SCIENTIFIC LTD.

Tel: 18210857532; 18210857532
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 4006356688 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

ZHIWE CHEMTECH CO LTD

Tel: 021-20221225 13917446399
Fax: QQ:115820162
Email: zwchem@163.com
Country: China
ProdList: 616
Advantage: 61

TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
Fax: 021-67121385
Email: Sales-CN@TCIchemicals.com
Country: China
ProdList: 24529
Advantage: 81

Ark Pharm, Inc.

Tel: 847-367-3680
Fax: 847-367-3681
Email: sales@arkpharminc.com
Country: United States
ProdList: 1670
Advantage: 56

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44801
Advantage: 61

Shandong Xiya Chemical Co., Ltd

Tel: 4009903999 13355009207
Fax: 0539-6365991
Email: 3007715519@qq.com
Country: China
ProdList: 18729
Advantage: 57

Maya High Purity Chemicals

Tel: +86 (573) 82222445 (0)18006601000 452520369
Fax: +86 (573) 82222643
Email: sales@maya-r.com
Country: China
ProdList: 11707
Advantage: 57

Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.

Tel: 025-66113011 17798518460
Fax: (1)02557626880
Email: cfzhang@aikonchem.com
Country: China
ProdList: 19913
Advantage: 55

TOKYO CHEMICAL INDUSTRY CO., LTD.

Tel: 03-36680489
Fax: 03-3668-0520
Email: Sales-JP@TCIchemicals.com
Country: Japan
ProdList: 28387
Advantage: 80

More

Less

View Lastest Price from 4'-CHLOROPIVALOANILIDE manufacturers

Career Henan Chemical Co

Product: 4'-CHLOROPIVALOANILIDE 65854-91-3
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100KG
Release date: 2020-01-11

65854-91-3, 4'-CHLOROPIVALOANILIDERelated Search:

MONALIDE 4'-CHLOROPIVALOANILIDE CYCLANILIDE 3',4'-DICHLOROPIVALANILIDE N-(4-CHLORO-6-METHOXYPHENYL)-2,2-DIMETHYLPROPANAMIDE 3-CHLORO-N-(2,4-DICHLOROPHENYL)-2,2-DIMETHYLPROPANAMIDE SALOR-INT L135151-1EA N-(2,4-DICHLOROPHENYL)(PHENYLCYCLOPENTYL)FORMAMIDE N-(4-CHLOROPHENYL)(PHENYLCYCLOPENTYL)FORMAMIDE N1,N3-BIS(2,4-DICHLOROPHENYL)-2-[(METHOXYIMINO)METHYL]-2-METHYLMALONAMIDE N-(4-CHLORO-3-NITROPHENYL)(PHENYLCYCLOPENTYL)FORMAMIDE N-(3,4-DICHLOROPHENYL)(PHENYLCYCLOPENTYL)FORMAMIDE AURORA 3316 5-chloro-2-[(2,2-dimethylpropanoyl)amino]benzoic acid 1-(2-BENZOYL-4-CHLOROPHENYL)-3,3-DIMETHYL-2-AZETANONE AURORA 10613 N-(4-CHLORO-2-NITROPHENYL)(PHENYLCYCLOPENTYL)FORMAMIDE N-(2-BENZOYL-4-CHLOROPHENYL)-3-CHLORO-2,2-DIMETHYLPROPANAMIDE

N-PIVALOYL-P-CHLOROANILINE

N-(4-CHLOROPHENYL)-2,2-DIMETHYLPROPIONAMIDE

N-(4-CHLOROPHENYL)PIVALOYLAMIDE

4-Chloropivalanilide

4''-CHLOROPIVALOANILIDE,98.0%+(GC)

N-Pivaloyl-p-chlorophenyl

4-CHLORO-N-PIVALOYLANILINE

4'-CHLOROPIVALOANILIDE

N-(4-Chlorophenyl)-2,2-dimethylpropanamide

4-Chloro-N-pivaloylaniline N-(4-Chlorophenyl)pivaloylamide N-(4-Chlorophenyl)-2,2-dimethylpropionamide

N-(4-chlorophenyl)pivalaMide

4'-CHLORO-2,2-DIMETHYLPROPIONANILIDE

4-Chloropivalamide

4'-Chloropivaloanilide&gt

Propanamide, N-(4-chlorophenyl)-2,2-dimethyl-

4'-CHLORO-2,2-DIMETHYLPROPIONANILIDE

4′-Chloropivaloanilide, CAS 65854-91-3

65854-91-3