(ALPHAS,ALPHAS)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(R,R)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE

Reactions

Product Name: (ALPHAS,ALPHAS)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(R,R)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE
CAS No.: 847997-73-3
Chemical Name: (ALPHAS,ALPHAS)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(R,R)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE
Synonyms: SL-M009-2;MANDYPHOS SL-M009-2;-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE;(aS,aS)-1,1#-Bis[-(dimethylamino)benzyl]-(R,R)-2,2#-bis[di(3,5-xylyl)phos;(RP,RμP)-1,1μ-Bis[(S)-α-(dimethylamino)benzyl]-2,2μ-bis[di(3,5-xylyl)phosphino]ferrocene;(RP,R′P)-1,1′-Bis[(S)-α-(dimethylamino)benzyl]-2,2′-bis[di(3,5-xylyl)phosphino]ferrocene;(αs,αs)-1,1'-bis[α-(dimethylamino)benzyl]-(r,r)-2,2'-bis[di(3,5-xylyl)phosphino]ferrocene;(RP,R'P)-1,1'-Bis[(S)-alpha-(dimethylamino)benzyl]-2,2'-bis[di(3,5-xylyl)phosphino]ferrocene;(S,S)-1,1'-BIS[(S)-ALPHA-(DIMETHYLAMINO)-PHENYLMETHYL]-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE;(RP,R'P)-1,1'-Bis[(S)-alpha-(dimethylamino)benzyl]-2,2'-bis[di(3,5-xylyl)phosphino]ferrocene >=97%
CBNumber: CB5366800
Molecular Formula: C60H64FeN2P2
Formula Weight: 930.98
MOL File: 847997-73-3.mol

More

Less

(ALPHAS,ALPHAS)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(R,R)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE Property

alpha: +164°
form: Powder
color: orange
Stability:: store cold

More

Less

Safety

WGK Germany: 3
HS Code: 29319090

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More

Less

N-Bromosuccinimide Price

Strem Chemicals

Product number: 26-0245
Product name: (R,R)-(+)-2,2'-Bis[(S)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(di(3,5-dimethylphenyl)phosphino)ferrocene, min. 97%
Packaging: 100mg
Price: $96
Updated: 2024/03/01

Strem Chemicals

Product number: 26-0245
Product name: (R,R)-(+)-2,2'-Bis[(S)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(di(3,5-dimethylphenyl)phosphino)ferrocene, min. 97%
Packaging: 500mg
Price: $355
Updated: 2024/03/01

Strem Chemicals

Product number: 26-0245
Product name: (R,R)-(+)-2,2'-Bis[(S)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(di(3,5-dimethylphenyl)phosphino)ferrocene, min. 97%
Packaging: 2g
Price: $1207
Updated: 2024/03/01

Strem Chemicals

Product number: 26-0245
Product name: (R,R)-(+)-2,2'-Bis[(S)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(di(3,5-dimethylphenyl)phosphino)ferrocene, min. 97%
Packaging: 10g
Price: $4824
Updated: 2024/03/01

AK Scientific

Product number: 7474AJ
Product name: (R,R)-(+)-2,2'-Bis[(S)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(di(3,5-Dimethylphenyl)phosphino)ferrocene
Packaging: 500mg
Price: $421
Updated: 2021/12/16

More

Less

(ALPHAS,ALPHAS)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(R,R)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE Chemical Properties,Usage,Production

Reactions

Ligand for Rh-catalyzed asymmetric hydrogenation of α-acetamidoacrylates.
Ligand for Rh-catalyzed hydrogenation of α- and β-enamides, acrylic acid derivatives, itaconates, β-ketoesters and 1,3-diketones.
Ligand for Rh-catalyzed asymmetric hydrogenation of furyl-substituted (Z)-dehydroamino acid derivatives.
Ligand for Ir-catalyzed asymmetric transfer hydrogenation of ketones.
Ligand for Cu-catalyzed enantioselective hydroboration of α- and β-unsaturated esters and nitriles.

Chemical Properties

Orange powder

General Description

sold in collaboration with Solvias AG

(ALPHAS,ALPHAS)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(R,R)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

(ALPHAS,ALPHAS)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(R,R)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE Suppliers

China 17 Switzerland 1 United States 2 Global 20

SIGMA-RBI

Tel: --
Fax: --
Country: Switzerland
ProdList: 6896
Advantage: 91

847997-73-3, (ALPHAS,ALPHAS)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(R,R)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENERelated Search:

Ferrocene (+/-)-N,N-DIMETHYL-1-FERROCENYLETHYLAMINE (ALPHAS,ALPHAS)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(R,R)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE (S)-(-)-N,N-DIMETHYL-1-FERROCENYLETHYLAMINE (S)-N,N-DIMETHYL-1-[(R)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE (ALPHAS,ALPHAS)-1,1'-BIS-[ALPHA-(DIMETHYLAMINO)BENZYL]-(R,R)-2,2'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENE 1,1'-DIMETHYLFERROCENE (ALPHAS,ALPHAS)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(R,R)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE N,N-Dimethylaminomethylferrocene (S)-N,N-DIMETHYL-1-[(R)-1',2-BIS(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE 1,1'-DIETHYLFERROCENE 1,1'-Bis(diphenylphosphino)ferrocene

(S,S)-1,1'-BIS[(S)-ALPHA-(DIMETHYLAMINO)-PHENYLMETHYL]-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE

(R,R)-(+)-2,2'-BIS[(S)-(N,N-DIMETHYLAMINO)(PHENYL)METHYL]-1,1'-BIS(DI(3,5-DIMETHYLPHENYL)PHOSPHINO)FERROCENE

MANDYPHOS SL-M009-2

(ALPHAS,ALPHAS)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(R,R)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE

(aS,aS)-1,1#-Bis[<alpha>-(dimethylamino)benzyl]-(R,R)-2,2#-bis[di(3,5-xylyl)phos

(R,R)-(+)-2,2'-Bis[(S)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(di(3,5-dimethylphenyl)phosphino)ferrocene,min.97%

(s,s)-1,1'-bis[(s)-α-(dimethylamino)-phenylmethyl]-2,2'-bis[di(3,5-xylyl)phosphino]ferrocene (acc to cas)

(αs,αs)-1,1'-bis[α-(dimethylamino)benzyl]-(r,r)-2,2'-bis[di(3,5-xylyl)phosphino]ferrocene

(RP,RμP)-1,1μ-Bis[(S)-α-(dimethylamino)benzyl]-2,2μ-bis[di(3,5-xylyl)phosphino]ferrocene

Mandyphos SL-M009-2, (1S,1μS)- 1,1μ-Bis[bis(3,5-dimethylphenyl)phosphino]-2,2μ-bis[(S)-(dimethylamino)phenylmethyl]ferrocene (acc to CAS)

(R,R)-(+)-2,2'-Bis[(S)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(di(3,5-dimethylphenyl)phosphino)ferrocene, min. 97%

-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE

(R,R)-(+)-2,2'-Bis[(S)-(N,N-dimethylamino(phenyl)methyl]-1,1'-bis(di(3,5-dimethylphenyl)phosphino)ferrocene

(aS,aS)-2,2'-Bis(α-N,N-dimethylaminophenylmethyl)-(R,R)-1,1'-bis[di-(3,5-dimethylphenyl)phosphino]ferrocene

(aS,aS)-2,2'-Bis(a-N,N-dimethylaminophenylmethyl)-(R,R)-1,1'-bis[di-(3,5-dimethylphenyl)phosphino]-ferrocene

(1S,1'S)-1,1'-Bis[bis(3,5-dimethylphenyl)phosphino]-2,2'-bis[(S)-(dimethylamino)phenylmethyl]ferrocene

SL-M009-2

(RP,R'P)-1,1'-Bis[(S)-alpha-(dimethylamino)benzyl]-2,2'-bis[di(3,5-xylyl)phosphino]ferrocene >=97%

(RP,R'P)-1,1'-Bis[(S)-alpha-(dimethylamino)benzyl]-2,2'-bis[di(3,5-xylyl)phosphino]ferrocene

(R,R)Fc-1,1’-Bis[bis(3,5-dimethylphenyl)phosphino]-2,2'- bis[(S,S)C-(N,N-dimethylamino)phenylmethyl]ferrocene

(ALPHAS,ALPHAS)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(R,R)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE ISO 9001：2015 REACH

(RP,R′P)-1,1′-Bis[(S)-α-(dimethylamino)benzyl]-2,2′-bis[di(3,5-xylyl)phosphino]ferrocene

(R,R)-(+)-2,2'-Bis[(S)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(di(3,5-dimethylphenyl)phosphino)ferrocene,97%

847997-73-3

C60H66FeN2P2

Chiral Catalysts, Ligands, and Reagents

Asymmetric Synthesis

Privileged Ligands

Solvias Ligands

Chiral Phosphine

Ferrocene Series

Mandyphos Series