NICKEL(II) CHLORIDE
- Product Name
- NICKEL(II) CHLORIDE
- CAS No.
- 69098-15-3
- Chemical Name
- NICKEL(II) CHLORIDE
- Synonyms
- NICKEL(II) CHLORIDE HYDRATE;Puratronic99.995%(metalsbasis);NICKEL(II) CHLORIDE HYDRATE, 99.95%;nickel(ii) chloride hydrate, puratronic;Nickel(II) chloride hydrate 99.95% trace metals basis;Nickel(II) chloride hydrate, Puratronic, 99.995% (metals basis);Nickel(II) chloride hydrate, Puratronic(R), 99.995% (metals basis)
- CBNumber
- CB5370083
- Molecular Formula
- Cl2H2NiO
- Formula Weight
- 147.61
- MOL File
- 69098-15-3.mol
NICKEL(II) CHLORIDE Property
- Melting point:
- 1001 °C
- vapor pressure
- 1 mm Hg ( 671 °C)
- form
- Crystalline Aggregates
- color
- Green
- Water Solubility
- Freely soluble in water. Soluble in ethylene glycol, ethanol, and ammonium hydroxide.
- Sensitive
- Hygroscopic
- Merck
- 14,6505
- Exposure limits
- NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
Safety
- Hazard Codes
- T,N
- Risk Statements
- 45-23/24/25-36/37/38-42/43-68-50/53-48/23-38-23/25-61-49
- Safety Statements
- 53-26-27-28-36/37/39-45-61-60
- RIDADR
- UN 3288 6.1/PG 3
- WGK Germany
- 3
- RTECS
- QR6480000
- TSCA
- Yes
- HazardClass
- 6.1
- PackingGroup
- III
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H315Causes skin irritation
H317May cause an allergic skin reaction
H334May cause allergy or asthma symptoms or breathing difficulties if inhaled
H372Causes damage to organs through prolonged or repeated exposure
H410Very toxic to aquatic life with long lasting effects
- Precautionary statements
-
P202Do not handle until all safety precautions have been read and understood.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302+P352IF ON SKIN: wash with plenty of soap and water.
N-Bromosuccinimide Price
- Product number
- 364304
- Product name
- Nickel(II) chloride hydrate
- Purity
- 99.95% trace metals basis
- Packaging
- 100g
- Price
- $75.2
- Updated
- 2024/03/01
- Product number
- 364304
- Product name
- Nickel(II) chloride hydrate
- Purity
- 99.95% trace metals basis
- Packaging
- 500g
- Price
- $220
- Updated
- 2024/03/01
- Product number
- 010815
- Product name
- Nickel(II) chloride hydrate, Puratronic?, 99.995% (metals basis)
- Packaging
- 5g
- Price
- $54.6
- Updated
- 2024/03/01
- Product number
- 010815
- Product name
- Nickel(II) chloride hydrate, Puratronic?, 99.995% (metals basis)
- Packaging
- 25g
- Price
- $135.45
- Updated
- 2023/01/06
- Product number
- 010815
- Product name
- Nickel(II) chloride hydrate, Puratronic?, 99.995% (metals basis)
- Packaging
- 100g
- Price
- $462
- Updated
- 2023/01/06
NICKEL(II) CHLORIDE Chemical Properties,Usage,Production
Uses
It is used in electroplating and as a catalyst for organic conversions, for example in chemo-selective thioacetalization of aldehydes. In combination with lithium aluminum hydride, it serves as a reducing agent for alkenes, alkynes, and organic halides; it can cleave N-O bond and open epoxides. It is a precursor to several nickel-phosphine complexes, such as bis(triphenylphosphine)nickel(II) chloride, which are used in alkyne trimerizations, carbonylations, and as catalysts in organic reactions such as Suzuki-Miyaura cross coupling reactions as an alternative to palladium(0) catalysts. It is the precursor to acetylacetonate complex of Ni, used for producing 1,5-cyclooctadiene complex, an important reagent in organonickel chemistry. It can be used to prepare the sandwich compound nickelocene through dimethoxyethane complex of nickel chloride.
Purification Methods
It crystallises from dilute HCl to form the green hexahydrate. At 70o this dehydrates to the tetrahydrate, and at higher temperatures it forms the anhydrous salt. It sublimes in yellow hexagonal scales in a stream of HCl. Store it in a desiccator as it is deliquescent. [Hart & Partington J Chem Soc 104 1943.]
NICKEL(II) CHLORIDE Preparation Products And Raw materials
Raw materials
Preparation Products
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