NICKEL(II) CHLORIDE

Product Name: NICKEL(II) CHLORIDE
CAS No.: 69098-15-3
Chemical Name: NICKEL(II) CHLORIDE
Synonyms: NICKEL(II) CHLORIDE HYDRATE;Puratronic99.995%(metalsbasis);NICKEL(II) CHLORIDE HYDRATE, 99.95%;nickel(ii) chloride hydrate, puratronic;Nickel(II) chloride hydrate 99.95% trace metals basis;Nickel(II) chloride hydrate, Puratronic, 99.995% (metals basis);Nickel(II) chloride hydrate, Puratronic(R), 99.995% (metals basis)
CBNumber: CB5370083
Molecular Formula: Cl2H2NiO
Formula Weight: 147.61
MOL File: 69098-15-3.mol

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NICKEL(II) CHLORIDE Property

Melting point:: 1001 °C
vapor pressure: 1 mm Hg ( 671 °C)
form: Crystalline Aggregates
color: Green
Water Solubility: Freely soluble in water. Soluble in ethylene glycol, ethanol, and ammonium hydroxide.
Sensitive: Hygroscopic
Merck: 14,6505
Exposure limits: NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3

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Safety

Hazard Codes: T,N
Risk Statements: 45-23/24/25-36/37/38-42/43-68-50/53-48/23-38-23/25-61-49
Safety Statements: 53-26-27-28-36/37/39-45-61-60
RIDADR: UN 3288 6.1/PG 3
WGK Germany: 3
RTECS: QR6480000
TSCA: Yes
HazardClass: 6.1
PackingGroup: III

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H315Causes skin irritation

H317May cause an allergic skin reaction

H334May cause allergy or asthma symptoms or breathing difficulties if inhaled

H372Causes damage to organs through prolonged or repeated exposure

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P202Do not handle until all safety precautions have been read and understood.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P302+P352IF ON SKIN: wash with plenty of soap and water.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 364304
Product name: Nickel(II) chloride hydrate
Purity: 99.95% trace metals basis
Packaging: 100g
Price: $75.2
Updated: 2024/03/01

Sigma-Aldrich

Product number: 364304
Product name: Nickel(II) chloride hydrate
Purity: 99.95% trace metals basis
Packaging: 500g
Price: $220
Updated: 2024/03/01

Alfa Aesar

Product number: 010815
Product name: Nickel(II) chloride hydrate, Puratronic?, 99.995% (metals basis)
Packaging: 5g
Price: $54.6
Updated: 2024/03/01

Alfa Aesar

Product number: 010815
Product name: Nickel(II) chloride hydrate, Puratronic?, 99.995% (metals basis)
Packaging: 25g
Price: $135.45
Updated: 2023/01/06

Alfa Aesar

Product number: 010815
Product name: Nickel(II) chloride hydrate, Puratronic?, 99.995% (metals basis)
Packaging: 100g
Price: $462
Updated: 2023/01/06

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NICKEL(II) CHLORIDE Chemical Properties,Usage,Production

Uses

It is used in electroplating and as a catalyst for organic conversions, for example in chemo-selective thioacetalization of aldehydes. In combination with lithium aluminum hydride, it serves as a reducing agent for alkenes, alkynes, and organic halides; it can cleave N-O bond and open epoxides. It is a precursor to several nickel-phosphine complexes, such as bis(triphenylphosphine)nickel(II) chloride, which are used in alkyne trimerizations, carbonylations, and as catalysts in organic reactions such as Suzuki-Miyaura cross coupling reactions as an alternative to palladium(0) catalysts. It is the precursor to acetylacetonate complex of Ni, used for producing 1,5-cyclooctadiene complex, an important reagent in organonickel chemistry. It can be used to prepare the sandwich compound nickelocene through dimethoxyethane complex of nickel chloride.

Purification Methods

It crystallises from dilute HCl to form the green hexahydrate. At 70o this dehydrates to the tetrahydrate, and at higher temperatures it forms the anhydrous salt. It sublimes in yellow hexagonal scales in a stream of HCl. Store it in a desiccator as it is deliquescent. [Hart & Partington J Chem Soc 104 1943.]

NICKEL(II) CHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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NICKEL(II) CHLORIDE Suppliers

China 23 Germany 1 India 3 Switzerland 1 United Kingdom 2 United States 8 Global 38

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69098-15-3, NICKEL(II) CHLORIDERelated Search:

Nickel chloride 'LGC' (2011) NICKELCHLORIDETRIHYDRATE TRIS(ETHYLENEDIAMINE)NICKEL(II)CHLORIDE HYDRATE NICKEL CHLOROPALLADATE NICKEL(II) CHLORIDE BIS(ETHYLENEDIAMINE)NICKEL(II) CHLORIDE HYDRATE NICKEL CHLORIDE, DIMETHOXYETHANE ADDUCT

NICKEL(II) CHLORIDE HYDRATE

NICKEL(II) CHLORIDE HYDRATE, 99.95%

Puratronic99.995%(metalsbasis)

nickel(ii) chloride hydrate, puratronic

Nickel(II) chloride hydrate, Puratronic(R), 99.995% (metals basis)

Nickel(II) chloride hydrate, Puratronic, 99.995% (metals basis)

Nickel(II) chloride hydrate 99.95% trace metals basis

69098-15-3

NiCl2xH2O

Cl2NiH2O

Catalysis and Inorganic Chemistry

Chemical Synthesis

Nickel Salts

NickelMetal and Ceramic Science

Salts