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3-NITRO-2-PYRIDINESULFENYL CHLORIDE

Product Name
3-NITRO-2-PYRIDINESULFENYL CHLORIDE
CAS No.
68206-45-1
Chemical Name
3-NITRO-2-PYRIDINESULFENYL CHLORIDE
Synonyms
NPYS-CL;OxytocinImpurity16;3-nitro-2-pyridinesulfenyl;2-(chlorosulfanyl)-3-nitropyridine;3-NITRO-2-PYRIDINESULFENYL CHLORIDE;2-Pyridinesulfenyl chloride, 3-nitro-;3-Nitropyridin-2-yl hypochlorothioite;(3-nitropyridin-2-yl)sulfanyl]chlorane;(3-nitropyridin-2-yl) thiohypochlorite;3-Nitro-2-pyridinesulfenyl chloride 95%
CBNumber
CB5384130
Molecular Formula
C5H3ClN2O2S
Formula Weight
190.61
MOL File
68206-45-1.mol
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3-NITRO-2-PYRIDINESULFENYL CHLORIDE Property

Melting point:
205 °C (dec.) (lit.)
Boiling point:
376.8±27.0 °C(Predicted)
Density 
1.58±0.1 g/cm3(Predicted)
storage temp. 
2-8°C
solubility 
dichloromethane: soluble(lit.)
pka
-3.72±0.29(Predicted)
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Safety

Hazard Codes 
C
Risk Statements 
34
Safety Statements 
26-27-36/37/39-45
RIDADR 
UN 3261 8/PG 2
WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
303232
Product name
3-Nitro-2-pyridinesulfenyl chloride
Purity
95%
Packaging
1g
Price
$230
Updated
2024/03/01
TRC
Product number
B506343
Product name
[(3-nitropyridin-2-yl)sulfanyl]chlorane
Packaging
50mg
Price
$45
Updated
2021/12/16
AK Scientific
Product number
0378AQ
Product name
3-Nitro-2-pyridinesulfenyl chloride
Packaging
1g
Price
$289
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0115401
Product name
3-NITRO-2-PYRIDINESULFENYL CHLORIDE
Purity
95.00%
Packaging
1G
Price
$795.56
Updated
2021/12/16
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3-NITRO-2-PYRIDINESULFENYL CHLORIDE Chemical Properties,Usage,Production

Uses

3-Nitro-2-pyridinesulfenyl chloride (NpysCl) was employed as the starting material for the synthesis of N-, O- and S-Npys-protected amino acid.

General Description

The 3-nitro-2-pyridinesulphenyl (Npys) moiety is useful as a protecting-activating group for cysteine, particularly in the synthesis of cyclic and unsymmetrical disulfides. The stability of NpysCl was studied in various solvents.

Purification Methods

The chloride crystallises as yellow needles from CH2Cl2. When pure, it is stable for several weeks at room temperature, and no decomposition was observed after 6 months at <0o. It is moisture sensitive. UV (MeCN) has at 231nm max ( 12,988), 264nm ( 5,784) and 372nm ( 3,117). [NMR and UV: Matsuda & Aiba Chem Lett 951 1978, Wagner et al. Chem Ber 75 935 1942.]

3-NITRO-2-PYRIDINESULFENYL CHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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3-NITRO-2-PYRIDINESULFENYL CHLORIDE Suppliers

SIGMA-RBI
Tel
--
Fax
--
Country
Switzerland
ProdList
6896
Advantage
91
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View Lastest Price from 3-NITRO-2-PYRIDINESULFENYL CHLORIDE manufacturers

Career Henan Chemical Co
Product
3-NITRO-2-PYRIDINESULFENYL CHLORIDE 68206-45-1
Price
US $2.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
customise
Release date
2018-08-09

68206-45-1, 3-NITRO-2-PYRIDINESULFENYL CHLORIDERelated Search:


  • 3-NITRO-2-PYRIDINESULFENYL CHLORIDE
  • NPYS-CL
  • 3-nitro-2-pyridinesulfenyl
  • 2-(chlorosulfanyl)-3-nitropyridine
  • 3-Nitro-2-pyridinesulfenyl chloride 95%
  • (3-nitropyridin-2-yl) thiohypochlorite
  • thiohypochlorous acid (3-nitro-2-pyridinyl) ester
  • 2-Pyridinesulfenyl chloride, 3-nitro-
  • (3-nitropyridin-2-yl)sulfanyl]chlorane
  • OxytocinImpurity16
  • 3-Nitropyridin-2-yl hypochlorothioite
  • 68206-45-1
  • C5H3ClN2O2S
  • Heterocyclic Building Blocks
  • Pyridines
  • Building Blocks
  • C5
  • C5
  • Heterocyclic Building Blocks
  • Pyridines
  • Heterocyclic Compounds