Sodium tetraphenylboron
- Product Name
- Sodium tetraphenylboron
- CAS No.
- 143-66-8
- Chemical Name
- Sodium tetraphenylboron
- Synonyms
- SODIUM TETRAPHENYLBORATE;NATPB;KALIGNOST;KALIBOR;NaTBP ;99.5%(W);kariporuk;KalignostGr;For Analysis;Kalignost(R)
- CBNumber
- CB5393075
- Molecular Formula
- C24H20BNa
- Formula Weight
- 342.22
- MOL File
- 143-66-8.mol
Sodium tetraphenylboron Property
- Melting point:
- 300 °C
- storage temp.
- 2-8°C
- solubility
- relatively well soluble in water. A 0.1 M aqueous solution is generally used as reagent.
- form
- Solid
- color
- White
- PH
- 8 (50g/l, H2O, 20℃)
- Water Solubility
- SOLUBLE
- Sensitive
- Light Sensitive
- Merck
- 14,8690
- BRN
- 3599783
- Stability:
- Stable. Incompatible with strong acids, strong oxidizing agents. Light sensitive.
- InChI
- InChI=1S/C24H20B.Na/c1-5-13-21(14-6-1)25(22-15-7-2-8-16-22,23-17-9-3-10-18-23)24-19-11-4-12-20-24;/h1-20H;/q-1;+1
- InChIKey
- HFSRCEJMTLMDLI-UHFFFAOYSA-N
- SMILES
- [B-](C1=CC=CC=C1)(C1=CC=CC=C1)(C1=CC=CC=C1)C1C=CC=CC=1.[Na+]
- CAS DataBase Reference
- 143-66-8(CAS DataBase Reference)
- EPA Substance Registry System
- Borate(1-), tetraphenyl-, sodium (143-66-8)
Safety
- Hazard Codes
- Xn,Xi
- Risk Statements
- 22-36/37/38
- Safety Statements
- 26-36/37-36-24/25
- RIDADR
- UN 2811 6.1/PG 3
- WGK Germany
- 3
- RTECS
- ED3362500
- F
- 8
- TSCA
- Yes
- HazardClass
- 6.1
- PackingGroup
- III
- HS Code
- 29310095
- Toxicity
- LD50 orally in Rabbit: 288 mg/kg
N-Bromosuccinimide Price
- Product number
- 1.06669
- Product name
- Sodium tetraphenyl borate
- Purity
- GR for analysis ACS,Reag. Ph Eur
- Packaging
- 10g
- Price
- $220
- Updated
- 2024/03/01
- Product number
- 1.06669
- Product name
- Sodium tetraphenyl borate
- Purity
- GR for analysis ACS,Reag. Ph Eur
- Packaging
- 25g
- Price
- $507
- Updated
- 2024/03/01
- Product number
- 1.06669
- Product name
- Sodium tetraphenyl borate
- Purity
- GR for analysis ACS,Reag. Ph Eur
- Packaging
- 100g
- Price
- $1330
- Updated
- 2024/03/01
- Product number
- 72018
- Product name
- Sodium tetraphenylborate
- Purity
- Selectophore , ≥99.5%
- Packaging
- 1g
- Price
- $121
- Updated
- 2022/05/15
- Product number
- A5130
- Product name
- Sodium Tetraphenylborate [Precipitation reagent for K]
- Purity
- >99.5%(W)
- Packaging
- 1g
- Price
- $32
- Updated
- 2024/03/01
Sodium tetraphenylboron Chemical Properties,Usage,Production
Chemical Properties
white powder
Uses
Determination of potassium, ammonium, rubidium, and cesium.
Uses
Sodium Tetraphenylboroate is a salt that is commonly used in inorganic and organometallic chemistry as a precipitating agent. Sodium Tetraphenylboroate is also utilized for the preparation of N-acylam monium salts and in coordination chemistry due to their favourable solubility in nonpolar sovlents and their crystallinity.
Uses
As reagent for determination of potassium, ammonium, rubidium and cesium ions: Barnard, Buechl, Chemist-Analyst 48, 44, 49 (1959); Montequi, Serrano, An. R. Acad. Farm. 26, 107 (1960).
General Description
Sodium tetraphenylborate (Ph4BNa) undergoes rhodium-catalyzed addition reactions with N-phenylsulfonyl aldimines to afford R(Ph)CHNHSO2Ph.
Purification Methods
Dissolve the borate in dry MeOH and add dry Et2O. Collect the solid and dry it in a vacuum at 80o/2mm for 4hours. It can also be extracted (Soxhlet) using CHCl3, and it crystallises from CHCl3 as snow-white needles. It is freely soluble in H2O, Me2CO but insoluble in pet ether and Et2O. An aqueous solution has pH 5 and can be stored for days at 25 or lower, and for 5 days at 45o without deterioration. Its solubility in polar solvents increases with decrease in temperature [Wittig & Raff Justus Liebigs Ann Chem 573 204 1950]. The salt can also be recrystallised from acetone/hexane or CHCl3, or from Et2O/cyclohexane (3:2) by warming the solution to precipitate the compound. Dry it in a vacuum at 80o. It dissolves in Me2CO at 50-60o to give a clear solution. After standing at this temperature for 10minutes the mixture is filtered rapidly through a pre-heated Büchner funnel, cooled and the crystals are collected and dried in a vacuum desiccator at room temperature for 3days [Abraham et al. J Chem Soc, Faraday Trans 1 80 489 1984]. If the product gives a turbid aqueous solution, the turbidity can be removed by treating with freshly prepared alumina gel and filtering. [Beilstein 16 IV 1624.]
Sodium tetraphenylboron Preparation Products And Raw materials
Raw materials
Preparation Products
Sodium tetraphenylboron Suppliers
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- Belgium
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View Lastest Price from Sodium tetraphenylboron manufacturers
- Product
- Sodium tetraphenylboron 143-66-8
- Price
- US $6.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20TONS
- Release date
- 2024-05-28
- Product
- Sodium tetraphenylboron 143-66-8
- Price
- US $6.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 2000KG/Month
- Release date
- 2024-08-06
- Product
- sodium tetraphenylborate 143-66-8
- Price
- US $0.00/Kg/Drum
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100MT
- Release date
- 2020-05-19